Biogas is a renewable gas with low heat energy, which makes it extremely difficult to use as fuel in conventional natural gas equipment. Nonetheless, the use of hydrogen as a biogas additive has proven to have a beneficial effect on flame stability and combustion behavior. This study evaluates the biogas–hydrogen combustion in a conventional natural gas burner able to work up to 100 kW. Tests were performed for three different compositions of biogas: BG70 (30% CO2), BG60 (40% CO2), and BG50 (50% CO2). To achieve better flame stability, each biogas was enriched with hydrogen from 5% to 25%. The difficulty of burning biogas in conventional systems was proven, as the burner does not ignite when the biogas composition contains more than 40% of CO2. The best improvements were obtained at 5% hydrogen composition since the exhaust gas temperature and, thus, the enthalpy, rises by 80% for BG70 and 65% for BG60. The stability map reveals that pure biogas combustion is unstable in BG70 and BG60; when the CO2 content is 50%, ignition is inhibited. The properties change slightly when the hydrogen concentrations are more than 20% in the fuel gas and do not necessarily improve.
Environmental problems are frequently related to energy use, estimated to grow at 1.6% per year until 2035. The transport sector accounts for 30% of energy demand and aviation is growing around 2.6% per year. Thus, low-emissions policies promote the use of sustainable aviation fuels. This work simulates a gasification and Fischer-Tropsch process to obtain biojet fuel from biomass and plastic waste. Syngas obtained through cogasification is purified by amine scrubbing and subjected to a Fischer-Tropsch process to produce hydrocarbons, which are upgraded for optimal fuel properties. Pinch analysis is applied to minimize energy usage, while Rankine cycles and a cooling tower are designed to cover the demand of electricity and cooling water. Results show that mass yields of the process towards biofuels are 13.06%, with an output of 1697.45 kg/h of biojet fuel. Density, kinematic viscosity, pour and flammability points and the lower calorific value of the biojet fuel comply with the ASTM D7566 standard. Pinch analysis allows to reduce 41.58% and 100% of cooling and heating demands, respectively, using biomass as renewable energy for heating. Moreover, steam generation covers 38.73% of the required electricity. The produced biojet fuel emits 20.14 gCO2eq/MJ and has a minimum selling price of 1.37 EUR/L.
The influence of particle size on the flammability and explosion severity has been widely demonstrated for coals along the years: the thinner the particle size, the more flammable is the dust and more severe are the explosions. Later, the increase on the use of biomass led to using the same resources and techniques for both groups of materials, considering them similar enough. However, there are basic differences between biomass and coal dust particles that leads to different behaviours when focusing on industrial fire safety. This difference is the starting point of this review, where a study on the existing knowledge in relation to the size and shape of biomass dust is presented. The methodologies and parameters used to determine particle size are described and discussed, showing the inconvenience of using only one parameter (d50) to describe dust, as well as the need of a standardized methodology to homogenise the results. The biomass data gathered from scientific literature and the following analysis carried out has also highlighted the importance of identifying samples in an accurate way and the strong necessity of further research on these materials and on the interdependence between particle size and the experimental procedures for flammability and explosibility properties.