Carbon capture, utilization and storage (CCUS) represents a vital technological strategy for mitigating greenhouse gas emissions and facilitating sustainable development. Supercritical CO₂ (SC-CO₂) pipeline transportation serves as an essential intermediary step towards attaining the “Dual Carbon Goals” and CCUS, representing the optimal and most cost-effective solution for ultra-long distance transport. In the CO₂ capture process, trace amounts of impurities, such as H₂O, O₂, H₂S, NO_x and SO_x, are inevitable. These gases react to form acidic compounds, thereby accelerating pipeline corrosion. With the progression of CCUS initiatives, corrosion within supercritical CO₂ pipeline transportation has become a critical challenge that significantly affects the safety and integrity of pipeline infrastructure. This review paper provides an in-depth analysis of the corrosion behavior of pipeline materials in a supercritical CO₂ environment, with particular attention to the effects of impurity, temperature, and pressure on corrosion rates, corrosion products, and corrosion morphology. Furthermore, an analysis of the corrosive behavior of welded joints in supercritical CO₂ transport pipelines is performed to provide valuable reference data for research and construction projects related to these pipelines.

A profound overview of the recent development for on-time, on-demand hydrogen production from light metal-based hydrolysis is presented. Hydrogen energy is one of the clean and renewable energy sources which has been recognized as an alternative to fossil fuels. In addition, aluminum is the most suitable light activity metal for hydrolysis materials attributed to its safety, environmental friendliness, high-energy density, inexpensive, and low density with high strength ratio. In general, dense oxide films formed act as a barrier on aluminum surfaces. Accordingly, effective removal of the oxide film is a key measure in solving the Al–water reaction. In this review, recent advances in addressing the main drawbacks including high-purity aluminum with acid–alkali solutions, nano-powders of aluminum or composite with acid–base solutions, ball-milled nano-powders, alloying blocks, and gas atomization powders are summarized. The characteristics of these three technologies and the current research progress are summarized in depth. Moreover, it is essential to promote low-cost aluminum-based materials based on effective hydrogen production efficiency and explore ways for practical large-scale applications.

Micro-arc Oxidation (MAO) is a technology for non-ferrous metal surface treatment through growth ceramic coating in situ. To determine the influence of the power supply mode and the loading parameters on the film forming of magnesium alloy micro-arc oxidation processing, the different power supply modes of pulsed direct current DC, pulsed bipolar current (BC) and the pulsed with a discharge loop current (DLC) was used with MAO technology on the AZ91D magnesium alloy. The power load parameters were optimized. The average energy consumption was calculated. Results showed that the role of the negative voltage in the bipolar pulse power supply is to restrain the large arc tendency. Under the pulse power supply with a discharge loop, the current and energy consumption decreases with the increase of the discharge resistance at the same pulse parameters. The big arc phenomenon can be effectively avoided and the impact of load capacitance could be effectively avoided by using the pulse power supply with a discharge loop. Moreover, the processing of the micro-arc oxidation is stable, the arc point is uniform, the surface of the film is smooth, the hole is uniform and the coating is dense, and the film efficiency is improved effectively.

The nucleation site plays a critical role in achieving the full coverage of perovskite film at both the macroscopic and microscopic scales, and it is systematically investigated for the first time in this study. The results show that under natural conditions, the incomplete coverage of perovskite film is due to both heterogeneous nucleation and homogeneous nucleation. The established concentration field and temperature field in the precursor solution show that there are two preferential nucleation sites, i.e., the upper surface of the precursor solution (homogeneous nucleation) and the surface of the substrate (heterogeneous nucleation). The nucleation sites are tuned by decreasing the drying pressure from the atmosphere to 3000 Pa, and then to 100 Pa, and then the microstructures of the perovskite films change from an incomplete coverage state to a monolayer full coverage state, and then to a bilayer full coverage state. At last, when the full coverage perovskite films are assembled into perovskite solar cells, the photovoltaic performance of the monolayer perovskite solar cells is slightly greater than that of the bilayer perovskite solar cells. The electrochemical characterization shows that there is more restrained internal recombination of the monolayer perovskite solar cells compared with bilayer perovskite solar cells.

A Finite-Element Model (FEM) for thermal-barrier coatings was employed to elaborate the temperature distribution on yttria-stabilized zirconia (YSZ) free surface during cracks coalescing, then the influence of sintering of YSZ induced by heat-transfer overlapping on energy release rate was quantificationally evaluated. A three-dimensional model including three layers was fabricated. Two types of cracks, with and without depth variations in YSZ coating, were introduced into the model, respectively. The temperature rise of YSZ coating over the crack is independent of each other at the beginning of crack propagation. As crack distance shortens, the independent temperature-rise regions begin to overlap, while maximum temperature is still located at the crack center before crack coalescence. The critical distance that the regions of temperature rise, just overlapping, is the sum of half lengths of two coalescing cracks (i.e., a₁ + a₂), which is independent of cracking path. The maximum temperature in YSZ sharply increases once cracks coalesce. Compared with one delamination crack, the effective energy-release rate induced by heat-transfer overlapping increases in the range of 0.2%–15%, depending on crack length and crack distance, which is on some level comparable to that of deterioration of thermal expansion misfit induced by temperature jump between crack faces.

The durability of atmospheric plasma-sprayed thermal barrier coatings (APS TBCs) with a double-layer bond coat was evaluated via isothermal cycling tests under 1120 °C. The bond coat consisted of a porosity layer deposited on the substrate and an oxidation layer deposited on the porosity layer. Two types of double-layer bond coats with different thickness ratios of the porosity layer to the oxidation layer (type A: 1:2 and type B: 2:1, respectively) were prepared. The results show that the porosity layer was oxidation free, the oxidation layer included a fraction of well-distributed α-Al₂O₃. The coefficient of thermal expansion of the oxidation layer was about 11.2 × 10⁻⁶ K⁻¹, which was rather lower than that of the porosity layer. Thus, the oxidation layer can be regards as a secondary bond coat between ceramic topcoat and traditional bond coat. The thermal cyclic lifetime of type A TBCs was about 60 cycles, which exceeded 1.2 times the durability of type B TBCs. The delamination cracks in both TBCs all propagated in the ceramic topcoat, which were all identical to those in traditional TBCs. Therefore, the design of the double-layer bond coat affected the stress level rather than the stress distribution in TBCs.