On the basis of the idea that the injecting energy will improve the conditions for the formation of Cooper pairs, a smart meta-superconductor (SMSC) was prepared by doping inhomogeneous phase of luminescent nanocomposite Y2O3:Eu3+/Ag, which has the strong luminescence characteristic, in MgB2 to improve the superconducting transition temperature (TC) of the MgB2-based superconductor. Two types of Y2O3:Eu3+/Ag with different sizes were prepared and marked as m-Y2O3:Eu3+/Ag and nY2O3:Eu3+/Ag. MgB2 SMSC was prepared through an ex situ process. Results show that when the inhomogeneous phase content was fixed at 2.0 wt.%, the TC of MgB2 SMSC increased initially then decreased with the increase in the Ag content in the dopant. When the Ag content accounted for 5 wt.% of the inhomogeneous phase weight, the TC of MgB2 SMSC was 37.2-38.0 K, which was similar to that of pure MgB2. Meanwhile, the TC of MgB2 SMSC doped with n-Y2O3:Eu3+/Ag increased initially then decreased basically with the increase in the content of n-Y2O3:Eu3+/Ag, in which Ag accounted for 5 wt.% of the inhomogeneous phase. The TC of MgB2 SMSC doped with 0.5 wt.% n-Y2O3:Eu3+/Ag was 37.6-38.4 K, which was 0.4 K higher than that of pure MgB2. It is thought that the doping inhomogeneous phase of luminescent nanocomposite into the superconductor is a new means to improve the TC of SMSC.

Improving the critical transition temperature (TC) of Bi(Pb)SrCaCuO (B(P)SCCO) high-temperature superconductors is important, however, considerable challenges exist. In this study, on the basis of the metamaterial structure and the idea that the injecting energy will promote the formation of Cooper pairs, a smart meta-superconductor B(P)SCCO consisting of B(P)SCCO microparticles and Y2O3:Eu3++Ag or Y2O3:Eu3+ luminophor was designed. In the applied electric field, the Y2O3:Eu3++Ag or Y2O3:Eu3+ luminophor generates an electroluminescence (EL), thereby promoting the TC via EL energy injection. A series of Y2O3:Eu3++Ag topological luminophor-doped B(P)SCCO samples was prepared. Results showed that Y2O3:Eu3++Ag was dispersed around B(P)SCCO particles, forming a metastructure. Accordingly, the onset transition temperature (T_(C,on)) and zero resistance transition temperature (T_(C,0)) of B(P)SCCO increased. Meanwhile, the B(P)SCCO sample doped with 0.2 wt% Y2O3 or Y2O3:Sm3+ nonluminous inhomogeneous phase was also prepared to further prove the influence of EL on the T_C rather than the rare earth effect. Results indicated that the TC of the Y2O3 or Y2O3:Sm3+ doping sample decreased. However, the TC of the 0.2 wt% Y2O3:Eu3++Ag or Y2O3:Eu3+ luminophor-doped sample improved. This outcome further demonstrated that the smart metastructure method can improve the TC of B(P)SCCO.