A smart meta-superconductor Bi(Pb)SrCaCuO (B(P)SCCO) may increase the critical transition temperature (T_C) of B(P)SCCO by electroluminescence (EL) energy injection of inhomogeneous phases. However, the increase amplitude ΔT_C ($\mathsf{\Delta }{T}_C=T_C-T_{C,pure}$) of T_C is relatively small. In this study, a smart meta-superconductor B(P)SCCO with different matrix sizes was designed. Three kinds of raw materials with different particle sizes were used, and different series of Y₂O₃:Sm³⁺, Y₂O₃, Y₂O₃:Eu³⁺, and Y₂O₃:Eu³⁺+Ag-doped samples and pure B(P)SCCO were prepared. Results indicated that the T_C of the Y₂O₃ or Y₂O₃:Sm³⁺ non-luminescent dopant doping sample is lower than that of pure B(P)SCCO. However, the T_C of the Y₂O₃:Eu³⁺+Ag or Y₂O₃:Eu³⁺ luminescent inhomogeneous phase doping sample is higher than that of pure B(P)SCCO. With the decrease of the raw material particle size from 30 to 5 μm, the particle size of the B(P)SCCO superconducting matrix in the prepared samples decreases, and the doping content of the Y₂O₃:Eu³⁺+Ag or Y₂O₃:Eu³⁺ increases from 0.2% to 0.4%. Meanwhile, the increase of the inhomogeneous phase content enhances the ΔT_C. When the particle size of raw material is 5 μm, the doping concentration of the luminescent inhomogeneous phase can be increased to 0.4%. At this time, the zero-resistance temperature and onset transition temperature of the Y₂O₃:Eu³⁺+Ag doped sample are 4 and 6.3 K higher than those of pure B(P)SCCO, respectively.

Incorporating with inhomogeneous phases with high electroluminescence (EL) intensity to prepare smart meta-superconductors (SMSCs) is an effective method for increasing the superconducting transition temperature (T_c) and has been confirmed in both MgB₂ and Bi(Pb)SrCaCuO systems. However, the increase of ΔT_c (ΔT_c = T_c ‒ T_cpure) has been quite small because of the low optimal concentrations of inhomogeneous phases. In this work, three kinds of MgB₂ raw materials, namely, ^aMgB₂, ^bMgB₂, and ^cMgB₂, were prepared with particle sizes decreasing in order. Inhomogeneous phases, Y₂O₃:Eu³⁺ and Y₂O₃:Eu³⁺/Ag, were also prepared and doped into MgB₂ to study the influence of doping concentration on the ΔT_c of MgB₂ with different particle sizes. Results show that reducing the MgB₂ particle size increases the optimal doping concentration of inhomogeneous phases, thereby increasing ΔT_c. The optimal doping concentrations for ^aMgB₂, ^bMgB₂, and ^cMgB₂ are 0.5%, 0.8%, and 1.2%, respectively. The corresponding ΔT_c values are 0.4, 0.9, and 1.2 K, respectively. This work open a new approach to reinforcing increase of ΔT_c in MgB₂ SMSCs.

We prepared poly(ethylaniline)-coated graphene oxide nanoflakes and then treated them with different concentrations of hydrazine solution to form dielectric composite nanoflakes having different reduction degrees of reduced graphene oxide core and insulating polyethylaniline shell (PEANI/rGO). The morphology of PEANI/rGO was observed by scanning electron microscopy, while the chemical structure was confirmed by Fourier transform infrared spectroscopy and X-ray photoelectron spectrometer. The influence of reduction degrees on the conductivity, dielectric polarization and electrorheological effect of PEANI/rGO in suspensions was investigated by dielectric spectroscopy and rheological test under electric fields. It shows that the PEANI/rGO has two interfacial polarization processes respectively due to rGO core and PEANI shell. As the number of hydrazine increases, the conductivity and polarization rate of rGO core increase. As a result, the difference between the polarization rate of rGO core and that of the PEANI shell gradually becomes large. This increased difference does not significantly decrease the yield stress but causes the flow instability of PEANI/GO suspensions under the simultaneous action of electric and shear fields.

The smart meta-superconductor MgB₂ and Bi(Pb)SrCaCuO increase the superconducting transition temperature (T_C), but the changes in the transport critical current density (J_C) and Meissner effect are still unknown. Here, we investigated the J_C and Meissner effect of smart meta-superconductor MgB₂ and Bi(Pb)SrCaCuO. The use of the standard four-probe method shows that Y₂O₃:Eu³⁺ and Y₂O₃:Eu³⁺+Ag inhomogeneous phase significantly increase the J_C, and J_C decreases to a minimum value at a higher temperature. The Meissner effect was measured by direct current magnetization. The doping of Y₂O₃:Eu³⁺ and Y₂O₃:Eu³⁺+Ag luminescent inhomogeneous phase causes a Meissner effect of MgB₂ and Bi(Pb)SrCaCuO at a higher temperature, while the non-luminescent dopant reduces the temperature at which samples have Meissner effect. The introduction of luminescent inhomogeneous phase in conventional MgB₂ and copper oxide high-temperature Bi(Pb)SrCaCuO superconductor increases the T_C and J_C, and Meissner effect is exerted at higher temperature. Therefore, smart meta-superconductivity is suitable for conventional and copper oxide high-temperature superconductors.

Increasing and improving the critical transition temperature (T_C), current density (J_C) and the Meissner effect (H_C) of conventional superconductors are the most important problems in superconductivity research, but progress has been slow for many years. In this study, by introducing the p-n junction nanostructured electroluminescent inhomogeneous phase with a red wavelength to realize energy injection, we found the improved property of smart meta-superconductors MgB₂, the critical transition temperature T_C increases by 0.8 K, the current density J_C increases by 37%, and the diamagnetism of the Meissner effect H_C also significantly improved, compared with pure MgB₂. Compared with the previous yttrium oxide inhomogeneous phase, the p-n junction has a higher luminescence intensity, a longer stable life and simpler external field requirements. The coupling between superconducting electrons and surface plasmon polaritons may be explained by this phenomenon. The realization of smart meta-superconductor by the electroluminescent inhomogeneous phase provides a new way to improve the performance of superconductors.

Superconducting materials exhibit unique physical properties and have great scientific value and vast industrial application prospects. However, due to limitations, such as the critical temperature (T_C) and critical current density (J_C), the large-scale application of superconducting materials remains challenging. Chemical doping has been a commonly used method to enhance the superconductivity of B(P)SCCO. However, satisfactory enhancement results have been difficult to achieve. In this study, we introduce green-light GaN p-n junction particles as inhomogeneous phases into B(P)SCCO polycrystalline particles to form a smart meta-superconductor (SMSC) structure. Based on the electroluminescence properties of the p-n junction, the Cooper pairs were stimulated and strengthened to enhance the superconductivity of B(P)SCCO. The experimental results demonstrate that the introduction of inhomogeneous phases can indeed enhance the critical temperature T_C, critical current density J_C, and complete diamagnetism (Meissner effect) of B(P)SCCO superconductors. Moreover, when the particle size of the raw material of B(P)SCCO is reduced from 30 to 5 μm, the grain size of the sintered samples also decreases, and the optimal doping concentration of the inhomogeneous phases increases from 0.15 wt.% to 0.2 wt.%, further improving the superconductivity.