The influence of nanoparticle morphology and filler content on the mechanical and electrical properties of carbon nanoparticle modified epoxy is investigated regarding small volumes. Three types of particles, representing spherical, tubular and layered morphologies are used. A clear size effect of increasing true failure strength with decreasing volume is found for neat and carbon black modified epoxy. Carbon nanotube (CNT) modified epoxy exhibits high potential for strength increase, but dispersion and purity are critical. In few layer graphene modified epoxy, particles are larger than statistically distributed defects and initiate cracks, counteracting any size effect. Different toughness increasing mechanisms on the nano- and micro-scale depending on particle morphology are discussed based on scanning electron microscopy images. Electrical percolation thresholds in the small volume fibres are significantly higher compared to bulk volume, with CNT being found to be the most suitable morphology to form electrical conductive paths. Good correlation between electrical resistance change and stress strain behaviour under tensile loads is observed. The results show the possibility to detect internal damage in small volumes by measuring electrical resistance and therefore indicate to the high potential for using CNT modified polymers in fibre reinforced plastics as a multifunctional, self-monitoring material with improved mechanical properties.

Lightweight structures which consist to a large extent of carbon fiber reinforced plastics (CFRP), often lack sufficient damping behavior. This also applies to hybrid laminates such as fiber metal laminates made of CFRP and aluminum. Since they are usually prone to vibrations due to their high stiffness and low mass, additional damping material is required to meet noise, vibration and harshness comfort demands in automotive or aviation industry. In the present study, hybrid carbon fiber elastomer metal laminates (HyCEML) are investigated which are intended to influence the damping behavior of the laminates by an elastomer interlayer between the CFRP ply and the aluminum sheets. The damping behavior is based on the principle of constrained layer damping. To characterize the damping behavior, dynamic mechanical analyses (DMA) are performed under tension on the elastomer and the CFRP, and under three point bending on the hybrid laminate. Different laminate lay-ups, with and without elastomer, and two different elastomer types are examined. The temperature and frequency dependent damping behavior is related to the bending stiffness and master curves are generated by using the time temperature superposition to analyze the damping behavior at higher frequencies. A numerical model is built up on the basis of DMA experiments on the constituents and micro mechanical studies. Subsequently, three point bending DMA experiments on hybrids are simulated and the results are compared with the experimental investigations. In addition, a parameter study on different lay-ups is done numerically. Increasing vibration damping is correlated to increasing elastomer content and decreasing elastomer modulus in the laminate. A rule of mixture is used to estimate the laminate loss factor for varying elastomer content.