A global transition towards more sustainable, affordable and reliable energy systems is being stimulated by the Paris Agreement and the United Nation's 2030 Agenda for Sustainable Development. This poses a challenge for the corrosion industry, as building climate‐resilient energy systems and infrastructures brings with it a long‐term direction, so as a result the long‐term behaviour of structural materials (mainly metals and alloys) becomes a major prospect. With this in mind “Corrosion Challenges Towards a Sustainable Society” presents a series of cases showing the importance of corrosion protection of metals and alloys in the development of energy production to further understand the science of corrosion, and bring the need for research and the consequences of corrosion into public and political focus. This includes emphasis on the limitation of greenhouse gas emissions, on the lifetime of infrastructures, implants, cultural heritage artefacts, and a variety of other topics.

The steel–concrete interface (SCI) is a complex, multi-phase and multi-scale system. It is widely known to influence the performance and long-term durability of concrete structures. However, a fundamental understanding of its properties and effects on corrosion initiation of embedded reinforcing steel remains elusive. This is attributed to its complicated heterogeneity and time-dependent nature, exacerbated by the lack of suitable techniques for systematic and detailed characterisation. This paper, prepared by members of the RILEM Technical Committee 262-SCI, critically reviews available information regarding current methods (laboratory or field-based) for characterising local properties of the SCI that have been identified as governing factors affecting corrosion initiation. These properties include characteristics of the steel such as mill scale and rust layers, and characteristics of the concrete such as interfacial voids, microstructure and moisture content. We evaluated over twenty methods and summarised their advantages, applications and limitations. The findings show a severe lack of well established, non-destructive techniques that are suitable for direct monitoring of the SCI at a representative scale with sufficiently high resolution (spatial, temporal), particularly for moisture related aspects. Several promising novel techniques with significant potential for further development and application were identified and discussed. Finally, we provide several recommendations for future research needs that are required to advance this critically important topic.

This paper presents a systematic study of the electrical resistivity of different steel fibre-reinforced concretes with fibre contents from 0 kg/m³ to 80 kg/m³ in order to identify possible effects of interactions among concrete composition and fibre type and content regarding electrical resistivity. Based on a literature review, four parameters, w/c ratio, binder content, ground granulated blast-furnace slag (GGBS) and fineness of cement, which show a significant influence on the electrical resistivity of plain concrete, were identified, and their influence on the electrical resistivity as well as interaction effects were investigated. The results of the experiments highlight that the addition of fibres leads to a significant decrease in electrical resistivity, independent of all additional parameters of the concrete composition. Additionally, it was shown that a higher porosity of the concrete, e.g., due to a higher w/c ratio, also results in a lower electrical resistivity. These results are in agreement with the literature review on plain concrete, while the influence of the concrete composition on the electrical resistivity is weaker with the increase in fibre content. The influence of fibre reinforcement is thus not affected by changes in the concrete composition. In general, a higher fibre dosage leads to a decrease in electrical resistivity, but the impact on the electrical resistivity varies slightly with different types of steel fibres. Based on this study, the potential of determining the fibre content using electrical resistivity measurements could be clearly presented.

Alkali‐activated materials (AAMs) are binders that can complement and partially substitute the current use of conventional cement. However, the present knowledge about how AAMs protect steel reinforcement in concrete elements is incomplete, and uncertainties exist regarding the application of electrochemical methods to investigate this issue. The present review by EFC WP11‐Task Force ‘Corrosion of steel in alkali‐activated materials’ demonstrates that important differences exist between AAMs and Portland cement, and between different classes of AAMs, which are mainly caused by differing pore solution compositions, and which affect the outcomes of electrochemical measurements. The high sulfide concentrations in blast furnace slag‐based AAMs lead to distinct anodic polarisation curves, unusually low open circuit potentials, and low polarisation resistances, which might be incorrectly interpreted as indicating active corrosion of steel reinforcement. No systematic study of the influence of the steel–concrete interface on the susceptibility of steel to corrosion in AAMs is available. Less common electrochemical methods present an opportunity for future progress in the field.