The interaction between matter and microwaves assumes critical significance due to the ubiquity of wireless communication technology. The selective shielding of microwaves represents the only way to achieve the control on crucial technological sectors. The implementation of microwave shielding ensures the proper functioning of electronic devices. By preventing electromagnetic pollution, shielding safeguards the integrity and optimal performances of devices, contributing to the reliability and efficiency of technological systems in various sectors and allowing the further step forwards in a safe and secure society. Nevertheless, the microwave shielding research is vast and can be quite hard to approach due to the large number and variety of studies regarding both theory and experiments. In this review, we focused our attention on the comprehensive discussion of the current state of the art of materials used for the production of electromagnetic interference shielding composites, with the aim of providing a solid reference point to explore this research field.

In recent years, low-cost carbons derived from recycled materials have been gaining attention for their potentials as filler in composites and in other applications. The electrical and mechanical properties of polymer composites can be tuned using different percentages and different kind of fillers: either low-cost (e.g., carbon black), ecofriendly (e.g., biochar), or sophisticated (e.g., carbon nanotubes). In this work, the mechanical and electrical behavior of composites with biochar and multiwall carbon nanotubes dispersed in epoxy resin are compared. Superior mechanical properties (ultimate tensile strength, strain at break) were noticed at low heat-treated biochar (concentrations 2–4 wt %). Furthermore, dielectric properties in the microwave range comparable to low carbon nanotubes loadings can be achieved by employing larger but manageable amounts of biochar (20 wt %), rending the production of composites for structural and functional application cost-effective.

Production of versatile composites is a very attractive field. Carbon containing epoxy resins are one of the most relevant reinforced plastics used for a wide number of applications. In this research, we studied the influence of five different commercial biochar samples for the selective enhancement of brittleness and ductility of an epoxy based composite. We proved the relationship between biochar morphology and composites mechanical properties with the aid of FT-IR and FE-SEM analysis. We were able to improve the neat resin mechanical properties by doubling its Young’s modulus and ultimate tensile strength using a wheat straw derived material, and to increase its elongation by 40%, we used a Miscanthus derived biochar.

Olive pruning is waste from olive cultivation and is generally disposed of through incineration. Olive pruning can, however, be salvaged by pyrolysis, which also produces an interesting carbon-based material known as biochar. Biochar has been proved as a suitable filler which improves the mechanical properties of epoxy composites. Despite this, literature has few studied focused on the relationship between biochar thermal history and the properties it induces in related biochar containing composites. In this work, we report a morphological analysis of biochar produced at different pyrolytic high treatment temperatures (400℃, 600℃, 800℃, and 1000℃) using different heating rates (5℃/min, 15℃/min, and 50℃/min). We investigate the effect of different biochar morphology on the biochar epoxy-related composites, proving the tuneability of the mechanical properties of composites according to the thermal history of the biochar employed.