In the last few years, extensive research efforts have been made to develop novel bio-char-based electrodes using different strategies starting from a variety of biomass precursors as well as applying different thermochemical conversion paths. In this regard, hydrothermal carbonization method is becoming a more prevalent option among conversion procedures even if pyrolysis remains crucial in converting biomass into carbonaceous materials. The main aim of this study is to develop an innovative supercapacitor electrode from spruce bark waste through a unique low-temperature technique approach, which proved to effectively eliminate the pyrolysis step. Consequently, a hybrid spruce-bark-graphene oxide compound (HySB) was obtained as electrode material for supercapacitors. When compared to a regularly used commercial electrode material, SLC1512P graphite (reference) with 150.3 µF cm⁻² capacitance, the HySB has a substantially higher capacitive performance of 530.5 µF cm⁻². In contrast to the reference, the HySB polarization resistance increases by two orders of magnitude at the stationary potential and by three orders of magnitude at the optimum potential, underlying that the superior performances of HySB extend beyond static conditions. The synthesis strategy provides an appropriate energy-efficient option for converting biomass into carbonaceous materials with meaningful properties suitable for energy storage applications.

The main goal of wastewater treatment is to significantly reduce organic compounds, micronutrients (nitrogen and phosphorus) and heavy metals and other contaminants (pathogens, pharmaceuticals and industrial chemicals). In this work, the efficiency of removing different contaminants (COD, NO₃⁻, NO₂⁻, NH₄⁺, PO₄³⁻, SO₄²⁻, Pb²⁺, Cd²⁺) from synthetic wastewater was tested using five different yeast strains: Kluyveromyces marxianus CMGBP16 (P1), Saccharomyces cerevisiae S228C (P2), Saccharomyces cerevisiae CM6B70 (P3), Saccharomyces cerevisiae CMGB234 (P4) and Pichia anomala CMGB88 (P5). The results showed a removal efficiency of up to 70% of COD, 97% of nitrate, 80% of nitrite, 93% of phosphate and 70% of sulfate ions for synthetic wastewater contaminated with Pb²⁺ (43 mg/L) and Cd²⁺ ions (39 mg/L). In contrast, the results showed an increase in ammonium ions, especially in the presence of Pb²⁺ ions. The yeast strains showed a high capacity to reduce Pb²⁺ (up to 96%) and Cd²⁺ (up to 40%) ions compared to the initial concentrations. In presence of a crude biosurfactant, the removal efficiency increased up to 99% for Pb²⁺ and 56% for Cd²⁺ simultaneously with an increase in yeast biomass of up to 11 times. The results, which were obtained in the absence of aeration and in neutral pH conditions, proved a high potential for practical applications in the biotreatment of the wastewater and the recovery of Pb and Cd ions, with a high benefit–cost ratio.

This paper is concerned with space charge accumulation and electric field distribution at XLPE/EPDM interfaces after thermal aging. XLPE, EPDM and multilayer XLPE/EPDM/XLPE flat samples have been manufactured and aged thermally during 240 and 480 h at 105 °C. Material degradation by oxidation during aging has been assessed by FTIR spectroscopy. The conductivities and permittivities of the samples have been measured before and during ageing. Using the values of conductivity and permittivity values obtained experimentally, the charge density values at the XLPE/EPDM interfaces and the electric field distribution across a multilayer XLPE/EPDM HVDC cable joint model has been calculated for different thermal aging times. The results show that the surface charge density values vary with the ageing time (decrease at aging beginning and then increase) and determine important enhancements of the electric field, in the vicinity of the inner but also of the outer semiconductor. The simultaneous presence of the volume and interfacial charges determines a less increase of the electric field for homocharges and more important for heterocharges, both for unaged and aged samples.

Persistent organic pollutants (POPs), including organochlorine pesticides, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins, and polychlorinated dibenzo-p-furans, pose significant hazards to the environment and living organisms. This concise review aims to consolidate knowledge on the biological processes involved in removing POPs from wastewater, an area less explored compared to conventional physico-chemical methods. The focus is on the potential of various aerobic and anaerobic microorganisms, fungi, and bacteria for efficient bioremediation, mitigating or eradicating the deleterious effects of these chemicals. The review scrutinizes individual bacterial strains and mixed cultures engaged in breaking down persistent organic pollutants in water, highlighting promising results from laboratory investigations that could be scaled for practical applications. The review concludes by underscoring the opportunities for exploring and advancing more sophisticated bioremediation techniques and optimized bioreactors. The ultimate goal is to enhance the efficiency of microbial-based strategies, implicitly reducing the environmental impact of persistent chemicals.