We report on inkjet-printed, wearable electrochromic displays with certified biodegradability according to the international standard 14855 for short-lifecycle applications.

We report on inkjet-printed dual-mode devices based on the synchronous electrochromic and electrofluorochromic effect of the polyindenofluoren-8-tryarylamine polymer (PIF8-TAA). Reference devices show switching times under 4 s, a coloration efficiency of 542 ± 10 cm² C⁻¹ at 395 nm, an electrochromic contrast of 50 ± 4% in the visible spectra and a fluorescence contrast ratio of 4.1 ± 0.3. The material is highly transparent in its neutral state and changes to a deep red color by oxidation. Utilizing PEDOT:PSS as electrode material, inkjet printing enabled the fabrication of freely, digitally designed device layouts providing a cost-efficient method for low-level display applications. The results highlight the applicability of digitally printed dual-mode EFCD for signage or advertisements.

Microlens arrays (MLAs) have a variety of applications in, e.g., display systems, projection optics, and sensors. They can be manufactured by various fabrication methods. Among all, inkjet printing stands out because it offers a straightforward, versatile, and low‐cost fabrication route. However, extra manufacturing steps such as photolithography are so far involved to pre‐structure the substrate in order to improve the uniformity of the printed MLAs and achieve a high fill factor (FF). In this study, the fabrication of MLAs is reported on unstructured substrates by inkjet printing using an optimized UV‐curable ink on top of self‐assembled monolayers (SAMs). The latter allows for tuning the surface free energy and thus the aspect ratio of the microlenses. The high uniformity of the printed MLAs is demonstrated by the automatic quantitative evaluations, where the standard deviations of the radii are below 2.5% and of the sag heights are less than 3.9%. An unprecedented FF of 88% amongst all inkjet‐printed MLAs on unstructured substrates is achieved. Digitally controlled large area fabrication is demonstrated, both, on rigid as well as on flexible substrates, opening a pathway for customized microoptics by additive manufacturing.

In this study, multilayer organic light-emitting diodes (OLEDs) consisting of three solution-processed layers are fabricated using slot die coating, gravure printing, and inkjet printing, techniques that are commonly used in the industry. Different technique combinations are investigated to successively deposit a hole injection layer (poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS)), a cross-linkable hole transport layer (N,N′-bis(4-(6-((3-ethyloxetan-3-yl)methoxy)-hexyloxy)phenyl)-N,N′-bis(4-methoxyphenyl)biphenyl-4,4′-diamin (QUPD)), and a green emissive layer (TSG-M) on top of each other. In order to compare the application techniques, the ink formulations have to be adapted to the respective process requirements. First, the influence of the application technique on the layer homogeneity of the different materials is investigated. Large area thickness measurements of the layers based on imaging color reflectometry (ICR) are used to compare the application techniques regarding the layer homogeneity and reproducible film thickness. The total stack thickness of all solution-processed layers of 32 OLEDs could be reproduced homogeneously in a process window of 30 nm for the technique combination of slot die coating and inkjet printing. The best efficiency of 13.3 cd A⁻¹ is reached for a process combination of slot die coating and gravure printing. In order to enable a statistically significant evaluation, in total, 96 OLEDs were analyzed and the corresponding 288 layers were measured successively to determine the influence of layer homogeneity on device performance.