Agriculture affects both the quantity and the quality of water available for other purposes, which becomes problematic, especially during increasingly frequent severe droughts. This requires tapping into the resources that are typically neglected. One such resource is a by-product of anaerobic digestion, in which moisture content typically exceeds 90%. Application of hydrothermal carbonization process (HTC) to this residue could partially remove organic and inorganic material, improve dewatering, decrease the overall solid mass, sanitize the digestate, change its properties, and eliminate problems related with emissions of odors from the installation. However, a significant gap still exists in terms of the dewatering of the hydrochars and the composition of the effluents. This work presents results of experimental investigation focused on the removal of organic compounds from the HTC effluent. Results of qualitative and quantitative analysis of liquid by-products of HTC of the agricultural digestate showed that acetic acid, 3-pyridinol, 1-hydroxyacetone, and 1,3-propanediol were the main liquid organic products of the process. Application of ultrafiltration process with the use of 10 kDa membrane for liquid HTC by-product treatment allows for the reduction of chemical oxygen demand up to 30%, biological oxygen demand up to 10%, and dissolved organic carbon up to 21%.
To make a beer there are four essential ingredients needed: water, malt, hops, and yeast. After brewing process, the main wastes are spent grains. These are often used as additions to fodders in animal husbandry. This study presents preliminary results of an investigation aiming to determine the feasibility of an alternative use of spent grains as a potential source of solid fuel. This source of energy could make breweries partly sustainable in terms of their energy supply. Such an approach may be feasible especially in large scale industrial breweries. This preliminary study presents encouraging results, showing improvements in terms of the fuel properties of the spent grain after its valorization through hydrothermal carbonization. Moreover, qualitative GC-MS analysis also indicates potential feasibility of the liquid byproduct of the hydrothermal carbonization of spent grain for biogas production. Results of proximate, ultimate, and DTG analyses show that hydrothermal carbonization of spent grain could improve its fuel properties and make it an especially suitable feedstock for fast pyrolysis and gasification. Improvement of HHV is also an improvement in terms of combustion.
19 April 2018 in Journal of Energy Resources Technology
The gasification and torrefaction of sewage sludge have the potential to make the thermal utilization of sewage sludge fully sustainable, thus limiting the use of expensive fossil fuels in the process. This includes sustainability in terms of electricity consumption. Although a great deal of work has been performed so far regarding the gasification of sewage sludge and some investigations have been performed in the area of its torrefaction, there is still a gap in terms of the influence of the torrefaction of the sewage sludge on its subsequent gasification. This study presents the results from the torrefaction tests, performed on a pilot scale reactor, as well as two consecutive steam gasification tests, performed in an allothermal fixed bed gasifier, in order to determine if torrefaction can be deemed as a primary method of the reduction of tar content for the producer gas, from the aforementioned gasification process. A comparative analysis is performed based on the results obtained during both tests, with special emphasis on the concentrations of condensable compounds (tars). The obtained results show that the torrefaction of sewage sludge, performed prior to gasification, can indeed have a positive influence on the gas quality. This is beneficial especially in terms of the content of heavy tars with melting points above 40 °C.
Sewage sludge is a residue of wastewater processing that is biologically active and consists of water, organic matter, including dead and living pathogens, polycyclic aromatic hydrocarbons, and heavy metals, as well as organic and inorganic pollutants. Landfilling is on the decline, giving way to more environmentally friendly utilisation routes. This paper presents the results of a two-stage gasification–vitrification system, using a prototype-entrained flow plasma-assisted gasification reactor along with ex situ plasma vitrification. The results show that the use of plasma has a considerable influence on the quality of gas, with a higher heating value of dry gas exceeding 7.5 MJ/mN3, excluding nitrogen dilution. However, dilution from plasma gases becomes the main problem, giving a lower heating value of dry gas with the highest value being 5.36 MJ/mN3 when dilution by nitrogen from plasma torches is taken into account. An analysis of the residues showed a very low leaching inclination of ex-situ vitrified residues. This suggests that such a system could be used to avoid the problem of landfilling significant amounts of ash from sewage sludge incineration by turning inorganic residues into a by-product that has potential use as a construction aggregate.
This study proposes an innovative installation concept for the sustainable utilization of sewage sludge. The aim of the study is to prove that existing devices and technologies allow construction of such an installation by integration of a dryer, torrefaction reactor and gasifier with engine, thus maximizing recovery of the waste heat by the installation. This study also presents the results of drying tests, performed at a commercial scale paddle dryer as well as detailed analysis of the torrefaction process of dried sewage sludge. Both tests aim to identify potential problems that could occur during the operation. The scarce literature studies published so far on the torrefaction of sewage sludge presents results from batch reactors, thus giving very limited data of the composition of the torgas. This study aims to cover that gap by presenting results from the torrefaction of sewage sludge in a continuously working, laboratory scale, isothermal rotary reactor. The study confirmed the feasibility of a self-sustaining installation of thermal utilization of sewage sludge using low quality heat. Performed study pointed out the most favorable way to use limited amounts of high temperature heat. Plasma gasification of the torrefied sewage sludge has been identified that requires further studies.