We explore the optical birefringence of the nematic binary mixtures () embedded into parallel-aligned nanochannels of mesoporous alumina and silica membranes for channel radii of nm. The results are compared with the bulk behavior and analyzed with a Landau–de Gennes model. Depending on the channel radius the nematic ordering in the cylindrical nanochannels evolves either discontinuously (subcritical regime, nematic ordering field ) or continuously (overcritical regime, ), but in both cases with a characteristic paranematic precursor behavior. The strength of the ordering field, imposed by the channel walls, and the magnitude of quenched disorder varies linearly with the mole fraction and scales inversely proportionally with for channel radii larger than 4 nm. The critical pore radius, , separating a continuous from a discontinuous paranematic-to-nematic evolution varies linearly with and differs negligibly between the silica and alumina membranes. We find no hints of preferred adsorption of one species at the channels walls. By contrast, a linear variation of the nematic-to-paranematic transition point and of the nematic ordering field versus suggests that the binary mixtures of cyanobiphenyls 6CB and 7CB keep their homogeneous bulk stoichiometry also in nanoconfinement, at least for channel diameters larger than 7 nm.
Waste incineration is one of the paths of implementation of the European Union’s strategy aimed at reducing the amount of waste deposited in landfills. Along with the development of methods for processing and recycling various wastes, new waste is generated. One example is waste from polyethylene terephthalate (PET) bottles washed during their recycling. In this paper, physical and chemical properties of such wastes are analyzed in terms of their use in the power industry. This research is part of the search for new sources and new technologies for energy production. The study has taken into account the energy properties of waste intended for combustion (calorific value, water content, chemical composition, volatile substances, combustible and non-flammable content). Thermogravimetric analysis of the material tested indicated that the waste is a good source of energy. It was found that the elemental composition (C, H, N, S, O) of the waste investigated is similar to that for biomass materials, and the calorific value of 13.2 MJ/kg qualifies the waste for combustion, provided that its initial moisture is reduced, for example, for co-combustion in the cement industry. Another possibility is mixing the waste with other kinds of waste to obtain a new fuel with more satisfactory parameters.