A lithium-ion battery cell’s electrochemical performance can be obtained through a series of standardized experiments, and the optimal operation and monitoring is performed when a model of the Li-ions is generated and adopted. With discrete-time parameter identification processes, the electrical circuit models (ECM) of the cells are derived. Over their wide range, the dual-polarization (DP) ECM is proposed to characterize two prismatic cells with different anode electrodes. In most of the studies on battery modeling, attention is paid to the accuracy comparison of the various ECMs, usually for a certain Li-ion, whereas the parameter identification methods of the ECMs are rarely compared. Hence in this work, three different approaches are performed for a certain temperature throughout the whole SoC range of the cells for two different load profiles, suitable for light- and heavy-duty electromotive applications. Analytical equations, least-square-based methods, and heuristic algorithms used for model parameterization are compared in terms of voltage accuracy, robustness, and computational time. The influence of the ECMs’ parameter variation on the voltage root mean square error (RMSE) is assessed as well with impedance spectroscopy in terms of Ohmic, internal, and total resistance comparisons. Li-ion cells are thoroughly electrically characterized and the following conclusions are drawn: (1) All methods are suitable for the modeling, giving a good agreement with the experimental data with less than 3% max voltage relative error and 30 mV RMSE in most cases. (2) Particle swarm optimization (PSO) method is the best trade-off in terms of computational time, accuracy, and robustness. (3) Genetic algorithm (GA) lack of computational time compared to PSO and LS (4) The internal resistance behavior, investigated for the PSO, showed a positive correlation to the voltage error, depending on the chemistry and loading profile.

In electrified vehicle applications, understanding the battery characteristics is of great importance as it is the state-of-art principal energy source. The key battery parameters can be identified by one of the robust and nondestructive characterization techniques, such as electrochemical impedance spectroscopy (EIS). However, relaxing the battery cell before performing the EIS method is crucial for the characterization results to be standardized. In this study, the three most common and commercially available lithium-ion technologies (NMC/graphite, LFP/graphite, NCA/LTO) are investigated at 15–45 °C temperature, in the range of 20–80% state of charge (SoC) and in fresh and aged state of health (SoH) conditions. The analysis shows that the duration of the relaxation time before impedance measurement has an impact on the battery’s nonlinear behavior. A rest time of 2 h can be proposed, irrespective of battery health condition, considering neutral technology-based impedance measurement. An impedance growth in ohmic and charge transfer characteristics was found, due to aging, and the effect of rest periods was also analyzed from an electrochemical standpoint. This experimental data was fitted to develop an empirical model, which can predict the nonlinear dynamics of lithium technologies with a 4–8% relative error for longer rest time.

The global electric vehicle (EV) is expanding enormously, foreseeing a 17.4% increase in compound annual growth rate (CAGR) by the end of 2027. The lithium-ion battery is considered as the most widely used battery technology in EV. The accurate and reliable diagnostic and prognostic of battery state guarantees the safe operation of EV and is crucial for durable electric vehicles. Research focusing on lithium-ion battery life degradation has grown more important in recent years. In this study, a model built for state of health (SoH) estimation for the LTO anode-based lithium-ion battery is presented. First, electrochemical impedance spectroscopy (EIS) is used to study the deterioration in battery performance, measurements such as charge transfer resistance and ohmic resistance are analyzed for different operational conditions and selected as key characteristic parameters for the model. Then, the model based on a backpropagation neural network (BPNN) along with the characteristic parameters is trained and validated with a real-life driving profile. The model shows a relatively accurate estimation of SoH with a mean-squared-error (MSE) of 0.002.

Incremental Capacity Analysis (ICA) is a method used to investigate the capacity state of health of batteries by tracking the electrochemical properties of the cell. It is based on the differentiation of the battery capacity over the battery voltage, for a full or a partial cycle regarding the experimental conditions. Several ICA research studies have been performed on various Li-ion chemistries and several mathematical approaches have been employed to obtain the differential curves, with most studies however to be focused on a cell level analysis. In the present work, we have performed an in-depth investigation of two battery packs composed of 14 Lithium-ion cells each; for the purpose of evaluating the applicability and the challenges of the ICA on a battery pack level by means of different charging current rates. Also, at a certain charging current, the influence of the temperature on the ICA curves is also analyzed.

This paper presents the concept of a hybrid thermal management system (TMS) including natural convection, heat pipe, and air cooling assisted heat pipe (ACAH) for electric vehicles. Experimental and numerical tests are described to predict the thermal behavior of a lithium titanate oxide (LTO) battery cell in a fast discharging process (8C rate). Specifications of different cooling techniques are deliberated and compared. The mathematical models are solved by COMSOL Multiphysics^® (Stockholm, Sweden), the commercial computational fluid dynamics (CFD) software. The simulation results are validated against experimental data with an acceptable error range. The results specify that the maximum cell temperatures for the cooling systems of natural convection, heat pipe, and ACAH reach 56, 46.3, and 38.3 °C, respectively. We found that the maximum cell temperature experiences a 17.3% and 31% reduction with the heat pipe and ACAH, respectively, compared with natural convection.