Nanotechnology has enabled tremendous breakthroughs in the development of materials and, nowadays, is well established in various economic fields. Among the various nanomaterials, TiO₂ nanoparticles (NPs) occupy a special position, as they are distinguished by their high availability, high photocatalytic activity, and favorable price, which make them useful in the production of paints, plastics, paper, cosmetics, food, furniture, etc. In textiles, TiO₂ NPs are widely used in chemical finishing processes to impart various protective functional properties to the fibers for the production of high-tech textile products with high added value. Such applications contribute to the overall consumption of TiO₂ NPs, which gives rise to reasonable considerations about the impact of TiO₂ NPs on human health and the environment, and debates regarding whether the extent of the benefits gained from the use of TiO₂ NPs justifies the potential risks. In this study, different TiO₂ NPs exposure modes are discussed, and their toxicity mechanisms—evaluated in various in vitro and in vivo studies—are briefly described, considering the molecular interactions with human health and the environment. In addition, in the conclusion of this study, the toxicity and biocompatibility of TiO₂ NPs are discussed, along with relevant risk management strategies.

This research aimed to study the influence of lyocell with incorporated ZnO (CLY) for antibacterial activity and biodegradation of fiber blends composed of viscose (CV), flax (LI), and CLY. Fiber blended samples with an increased weight fraction of CLY fibers were composed, and single CLY, CV and LI fibers were also used for comparison. Antibacterial activity was determined for the Gram-negative Escherichia coli and the Gram-positive Staphylococcus aureus bacteria. The biodegradation of fiber blends was investigated by the soil burial test. The results show that the single CLY fibers exhibited high antimicrobial activity against both E. coli and S. aureus bacteria and that the presence of LI fibers in the blended samples did not significantly affect antibacterial activity against E. coli, but drastically decreased the antibacterial activity against S. aureus. LI fibers strongly promoted the growth of S. aureus and, consequently, impaired the antimicrobial performance of ZnO against this bacterium. The presence of CLY fibers slowed down, but did not prevent, the biodegradation process of the fiber blends, even at the highest ZnO concentration. The soil that was in contact with the fiber blended samples during their burial was not contaminated to such an extent as to affect the growth of sprouts, confirming the sustainability of the fiber blends.

Polymer-based textiles have a major impact on human well-being, as they provide the desired functional protection and aesthetic comfort when worn. However, natural and synthetic polymer-based textiles can also pose serious health risks, as they are surfaces that allow the adhesion of various bacteria, including pathogenic bacteria. To minimise these problems, antibacterial chemical treatments are generally applicable in the case of polymer-based textiles. However, to avoid the use of potentially toxic chemicals, sustainable approaches require the customised design of non-adhesive polymer-based textiles, considering their chemical, physicochemical, constructional, and textural properties. Before designing, several articles are required to gain sufficient knowledge of the described object. Despite the urgent need to combat bacteria (on polymer-based textiles), which pose a serious global health risk, only a few review articles have been published that address bacterial adhesion in the context of superhydrophobic and antibacterial textile materials, while only one review article holistically addresses the textile factors and their influence on this phenomenon. The aim of this review article is to expand the insufficient knowledge about bacterial adhesion to polymer-based textiles on the basis of theoretical findings and real examples through a high degree of structuring, simplification, holistic consideration, and visualization. Therefore, this review provides an insight into the mechanisms involved in bacterial adhesion and a comprehensive overview of the influence of different textile factors, such as chemical composition, hydrophilicity/hydrophobicity, surface charge, surface free energy, roughness, and porosity, on bacterial adhesion. To emphasise the importance of the synergistic effect of the combined textile factors, examples of the influence of hydrophilicity/hydrophobicity in combination with surface charge, surface roughness, and porosity are discussed. From the review, it can be concluded that the combination of hydrophilicity/hydrophobicity and the surface charge of textile fibres and bacteria is crucial for bacterial adhesion, with roughness and porosity being the most important factors among the constructive and textural properties of polymer-based textiles.

The development of durable multifunctional properties is crucial for the production of high-performance technical textiles. In this work, a novel, environmentally friendly and facile method was developed for the chemical modification of cotton fabric by in situ biosynthesis of Ag NPs in the presence of sumac leaf extract as a reducing agent on TiO₂, ZnO and TiO₂ + ZnO previously applied to cotton fibres. The results showed that the presence of TiO₂, ZnO and TiO₂ + ZnO significantly increased the concentrations of the synthesised Ag NPs on the cotton fibres compared to the one-component Ag coating. This resulted in excellent antimicrobial properties of the TiO₂/Ag, ZnO/Ag and TiO₂ + ZnO/Ag composites even after 25 washes. While the TiO₂ and ZnO particles in the composite were incompatible, the synergistic effect among Ag, TiO₂ and ZnO in the composites resulted in excellent UV blocking properties of the coatings before and after 25 washes. Since the biosynthesis of Ag NPs was accompanied by a yellow–brown colouration of the samples, the photocatalytic self-cleaning of the composite coating could not be determined from the photodegradation rate of the coffee stains. This research provides a new environmentally friendly approach to producing durable antimicrobial and UV blocking coatings on cotton fibres.