This paper summarizes a series of the authors’ research in the field of assessing the operational degradation of oil and gas transit pipeline steels. Both mechanical and electrochemical properties of steels are deteriorated after operation, as is their resistance to environmentally-assisted cracking. The characteristics of resistance to brittle fracture and stress corrosion cracking decrease most intensively, which is associated with a development of in-bulk dissipated microdamages of the material. The most sensitive indicators of changes in the material’s state caused by degradation are impact toughness and fracture toughness by the J-integral method. The degradation degree of pipeline steels can also be evaluated nondestructively based on in-service changes in their polarization resistance and potential of the fracture surface. Attention is drawn to hydrogenation of a pipe wall from inside as a result of the electrochemical interaction of pipe metal with condensed moisture, which facilitates operational degradation of steel due to the combined action of operating stresses and hydrogen. The development of microdamages along steel texture was evidenced metallographically as a trend to the selective etching of boundaries between adjacent bands of ferrite and pearlite and fractographically by revealing brittle fracture elements on the fracture surfaces, namely delamination and cleavage, indicating the sites of cohesion weakening between ferrite and pearlite bands. The state of the X52 steel in its initial state and after use for 30 years was assessed based on the numerical simulation method.

The article presents the application of the acoustic emission (AE) technique for detecting crack initiation and examining the crack growth process in steel used in engineering structures. The tests were carried out on 40CrMo steel specimens with a single edge notch in bending (SENB). In the tests crack opening displacement, force parameter, and potential drop signal were measured. The fracture mechanism under loading was classified as brittle. Accurate AE investigations of the cracking process and SEM observations of the fracture surfaces helped to determine that the cracking process is a more complex phenomenon than the commonly understood brittle fracture. The AE signals showed that the frequency range in the initial stage of crack development and in the further crack growth stages vary. Based on the analysis of parameters and frequencies of AE signals, it was found that the process of apparently brittle fracture begins and ends according to the mechanisms characteristic of ductile crack growth. The work focuses on the comparison of selected parameters of AE signals recorded in the pre-initiation phase and during the growth of brittle fracture cracking.