This paper summarizes a series of the authors’ research in the field of assessing the operational degradation of oil and gas transit pipeline steels. Both mechanical and electrochemical properties of steels are deteriorated after operation, as is their resistance to environmentally-assisted cracking. The characteristics of resistance to brittle fracture and stress corrosion cracking decrease most intensively, which is associated with a development of in-bulk dissipated microdamages of the material. The most sensitive indicators of changes in the material’s state caused by degradation are impact toughness and fracture toughness by the J-integral method. The degradation degree of pipeline steels can also be evaluated nondestructively based on in-service changes in their polarization resistance and potential of the fracture surface. Attention is drawn to hydrogenation of a pipe wall from inside as a result of the electrochemical interaction of pipe metal with condensed moisture, which facilitates operational degradation of steel due to the combined action of operating stresses and hydrogen. The development of microdamages along steel texture was evidenced metallographically as a trend to the selective etching of boundaries between adjacent bands of ferrite and pearlite and fractographically by revealing brittle fracture elements on the fracture surfaces, namely delamination and cleavage, indicating the sites of cohesion weakening between ferrite and pearlite bands. The state of the X52 steel in its initial state and after use for 30 years was assessed based on the numerical simulation method.

The paper presents an analysis of mixed-mode fatigue crack growth in bridge steel after 100-years operating time. Experiments were carried out under mode I + II configuration on Compact Tension Shear (CTS) specimens and mode I + III on rectangular specimens with lateral stress concentrator under bending and torsion loading type. Due to the lack of accurate Stress Intensity Factor (SIF) solutions, the crack path was modelled with the finite element method according to its experimental observation. As a result, the Kinetic Fatigue Fracture Diagrams (KFFD) were constructed. Due to the change in the tendency of higher fatigue crack growth rates from K_I towards K_III dominance for the samples subjected to bending and torsion, it was decided to analyze this phenomenon in detail using electron-scanning microscopy. The fractographic analysis was carried out for specimens subjected to I + III crack loading mode. The mechanism of crack growth in old bridge steel at complex loads was determined and analyzed.