Modern civilization is heavily reliant on petroleum-based fuels to meet the energy demand of the transportation sector. However, burning fossil fuels in engines emits greenhouse gas emissions that harm the environment. Biofuels are commonly regarded as an alternative for sustainable transportation and economic development. Algal-based fuels, solar fuels, e-fuels, and CO₂-to-fuels are marketed as next-generation sources that address the shortcomings of first-generation and second-generation biofuels. This article investigates the benefits, limitations, and trends in different generations of biofuels through a review of the literature. The study also addresses the newer generation of biofuels highlighting the social, economic, and environmental aspects, providing the reader with information on long-term sustainability. The use of nanoparticles in the commercialization of biofuel is also highlighted. Finally, the paper discusses the recent advancements that potentially enable a sustainable energy transition, green economy, and carbon neutrality in the biofuel sector.

Alternative fuels, like biodiesel, are being utilized as a renewable energy source and an effective substitute for the continuously depleting supply of mineral diesel as they have similar combustion characteristics. However, the use of pure biodiesel as a fuel for diesel engines is currently limited due to problems relating to fuel properties and its relatively poor cold flow characteristics. Therefore, the most acceptable option for improving the properties of biodiesel is the use of a fuel additive. In the present study, the properties of palm oil methyl esters with increasing additive content were investigated after addition of ethanol, butanol and diethyl ether. The results revealed varying improvement in acid value, density, viscosity, pour point and cloud point, accompanied by a slight decrease in energy content with an increasing additive ratio. The viscosity reductions at 5% additive were 12%, 7%, 16.5% for ethanol, butanol and diethyl ether, respectively, and the maximum reduction in pour point was 5 °C at 5% diethyl ether blend. Engine test results revealed a noticeable improvement in engine brake power and specific fuel consumption compared to palm oil biodiesel and the best performance was obtained with diethyl ether. All the biodiesel-additive blend samples meet the requirements of ASTM D6751 biodiesel fuel standards for the measured properties.

This study has focused on the PM emissions of diesel engines. Diesel engines are attractive power units that are used widely in many fields and have become one of the larger contributors of total petroleum consumption. However, diesel engines are among the main contributors of emissions into the air, especially particulate matter (PM) and nitrogen oxides (NOx). PM is one of the major pollutants emitted by diesel engines and has adverse effects on human health. Accordingly, many studies have been conducted to find alternative fuels that are clean and efficient. Biodiesel, which produces less PM than diesel fuel, is preferred as an alternative source for diesel engines. Therefore, using palm oil methyl ester (POME) for diesel engines would be a more economical and sustainable solution. This study has focused on the PM emissions of diesel engines fuelled by a diesel and POME blend (B5, B10, B20, and B100). A comparison between diesel and the POME blend has been made which involves PM mass concentration and its components (soluble organic fraction (SOF) and dry soot (DS)). Combustion characteristics, such as in-cylinder pressure and rate of heat release of the engine, as well as gaseous emissions, have also been observed at different operating engine loads (0.05 MPa 20%, 0.4 MPa 40%, and 0.7 MPa 60%). The results show that PM emissions of B100 are lower than those of diesel fuel owing to the oxygen content of POME. With regard to the SOF concentration, B100 has a higher SOF value than diesel fuel at all engine loads. Meanwhile, the DS for B100 is lower than that of diesel fuel. Moreover, as the engine load increased, PM and SOF concentrations increased, while DS concentration decreased. The observation of in-cylinder pressure showed that the increment of pressure with the increasing POME blend, as well as the increasing engine load due to the high cetane number for B100, led to a short ignition delay. The engine brake thermal efficiency between the POME blend and mineral diesel was comparable. Furthermore, B100 fuels showed lower engine power at higher brake-specific fuel consumption compared to other tested fuels. In terms of gaseous emissions, increasing POME blends led to an increase in NOx emissions. Meanwhile, as the engine load increased, NOx also continued to increase. The effect of the POME blend on the PM-NOx trade-off observation showed that B100 simultaneously increased the NOx and decreased the PM emissions. It can be concluded that POME creates a lower PM concentration while giving some negative feedback to NOx.

Poor characterisation of nanoparticle suspensions impedes the development of nanolubricants for use in refrigeration and air-conditioning systems. Chemical treatment techniques, such as surfactants, are inappropriate for enhancing the stability of nanolubricants intended for use in vapour-compression refrigeration (VCR) systems. Prior to incorporating nanolubricants into the system, the stability of TiO₂ and SiO₂ nanoparticles dispersed in PVE was therefore investigated. The nanolubricants were prepared by a two-step method with the aid of an ultrasonication bath homogeniser. Visual observation and ultraviolet–visible (UV–Vis) spectrophotometric analysis were used, and zeta potential analysis was then performed to confirm the nanolubricants’ stability condition. The TiO₂/PVE nanolubricant was observed to be maintained at a 95% concentration ratio for up to 30 days of evaluation. The TiO₂/PVE, SiO_2/PVE, and SiO₂-TiO₂/PVE exhibited zeta potential values of 203.1 mV, 224.2 mV, and 105.3 mV, respectively, after 7 h of sonication. A high absolute value of zeta potential indicates that the electrostatic repulsive forces between nanoparticles are exceptionally strong, indicating an excellent stable suspension. The high values of zeta potentials validated the excellent stability conditions determined by UV–Vis analysis and visual observation. It can be concluded that ultrasonication times of 7 h produced the most stable state for mono- and hybrid nanolubricants.

With its unique qualities, such as infinite supply, high octane number, and capacity to cut greenhouse gas emissions, alcohol is a viable alternative fuel for SI engines. This review article aims to reveal to readers the effects of alcohol on the performance, combustion behavior, and emission characteristics of SI engines by collecting the outcomes from previous research. This article looks at methanol, ethanol, and butanol fuel qualities. The performance of SI engines with butanol, ethanol, and methanol combined with gasoline is investigated in terms of brake torque, brake power, fuel consumption, thermal efficiency, volumetric efficiency, mean effective pressure, and coefficient of variation under various conditions. Second, in-cylinder pressure, mass fraction burnt, ignition delay, pressure increases, and heat release rates are also used to evaluate the combustion characteristic. Finally, the article discusses pollutant emissions such as CO, CO₂, NO_x, UHC, and exhaust gas temperature. Methanol, ethanol, and butanol mixed with gasoline increased fuel consumption and lowered spark-ignition engines’ thermal efficiency. When alcohol was combined with gasoline, most research found that CO, NO_x, and UHC emissions were reduced due to improved combustion.