This paper aims at systemizing knowledge related to geodiversity assessment for water resources and its evaluation. The novel aspect connected to geodiversity of this paper is the analysis of the components of hydrological system, both at the superficial and underground level, in the territory of the Sesia Val Grande United Nations educational, scientific, and cultural organization (UNESCO) Global Geopark (Northwest Italy). More specifically, the research establishes a conceptual model and a specific procedure for the evaluation of geodiversity connected to water resources on a regional scale, by means of a qualitative-quantitative geographic information system (GIS) process, renamed here as hydro-geodiversity assessment. For these purposes, a targeted ecosystem approach is applied to consider the assets of the Geopark territory that has been derived from the interaction between water and other components of geodiversity, i.e., the hydro-geosystemic services. The element selection and processing operations led to the identification of areas characterized by greater values of hydrological geodiversity, in which the link between surface and underground hydrodynamics became closer and intense. The single geodiversity factor maps that were obtained from partial data aggregations were added together in map algebra operations, then subjected to weighing to formulate the hydro-geodiversity map of the Sesia Val Grande UNESCO Global Geopark. The results of the present study strengthen the strategic management of geological, geomorphological, and hydrological heritages of the study area by identifying different landscapes and local peculiarities determined by mutual influences between geology and hydrological dynamics.

Rainfall and temperature variability causes changes in groundwater recharge that can also influence groundwater quality by different processes. The aim of this study is the analysis of the hydrogeochemical variations over time due to meteorological variability in two different study areas in Italy: an alluvial aquifer in the Piedmont Po plain and an alluvial-pyroclastic aquifer in the Campanian plain. The examined plains show groundwater with natural quality not satisfying the European drinking water standards, or anthropogenic contamination. The peculiar natural quality is due, in the Campanian plain, to the closeness of volcanic areas, and to the presence of reducing conditions. In Piedmont plain a test site is characterized by a point-source contamination by heavy metals, due to the presence of past industrial activities. In all the examined areas there is a diffuse nitrate contamination. The fluctuations of the ions As, F, Fe, Mn, Cr VI, NO₃, and Cl were analyzed and compared, using statistical methods, with the variations over time in precipitation, temperature, and piezometric levels, sometimes significant. Results highlight the importance of the groundwater and meteorological monitoring and the key role of the recharge variation in the hydrogeochemical processes. The linking degree between rainfall/temperature variability and hydrogeochemistry is variable, in function of the typology of chemical species, their origin, and of the aquifer characteristics. The fluctuation of climate variables determines sudden changes in the geochemistry of shallow unconfined aquifers (e.g., in the Piedmont plain), while semiconfined or confined aquifers (e.g., in the Volturno-Regi Lagni plain) react with a greater delay to these variations. Moreover, natural quality is more affected by climatic variations than anthropogenic contamination, which is the result of multiple environmental and anthropic factors.

Supply of resources, a growing population, and environmental pollution are some of the main challenges facing the contemporary world. The rapid development of mining activities has produced huge amounts of waste. This waste, found in abandoned mine sites, provides the potential opportunity of extracting raw material. The current study, therefore, focuses on testing the validation of a shared methodology to recover extractive waste from abandoned mines, and applies this methodology to a case study in Gorno, northwest Italy. The methods focused on: (1) analyzing the impact of tailings and fine fraction of waste rock (2 mm) of waste rock, by means of dressing methods like wet shaking table and froth flotation. The results indicated that the fine fraction of waste rock and tailings did not have detrimental effects on seed germination; however, there was marked decrease in plant growth. As for the recovery of raw materials, the coarse waste rock samples, crushed to <0.5 mm, produced a recovery of Cd, Ga, and Zn—as much as 66%, 56%, and 64%, respectively—using the wet shaking table. The same samples when crushed to 0.063–0.16 mm and used for froth flotation produced a recovery of Cd, Ga, and Zn of up to 61%, 72%, and 47%, respectively. The flotation experiment on tailings showed a recovery of Cd, Ga and Zn at pH 7 of 33%, 6% and 29% respectively. The present investigation highlights the methodologies used for extracting raw materials from extractive waste.