The aim of the present work is to investigate the effect of halloysite nanotubes (HNT) on the mechanical properties of low-density polyethylene composites modified by maleic anhydride-grafted PE (PE-graft-MA). Polyethylene nanocomposites were prepared using an injection molding machine, Arburg Allrounder 320 C 500–170; the HNT content was varied at 0 wt %, 2 wt %, 4 wt % and 6 wt %, and the PE-graft-MA content was varied at 5 wt %. The composites were examined for their ultimate tensile stress, strain at ultimate stress, hardness, impact strength, melt flow rate, heat deflection temperature, Vicat softening temperature, crystallinity degree and phase transition temperature. It was found that the addition of halloysite nanotubes to low-density polyethylene (LDPE) led to an increased heat deflection temperature (HDT, up to 47 °C) and ultimate tensile strength (up to 16.00 MPa) while the Vicat softening temperature, strain at ultimate stress, impact strength and hardness of examined specimens slightly decreased. Processing properties of the materials specified by the melt flow rate (MFR) deteriorated almost twice. The results have demonstrated that the nanoparticles can reinforce enhance LDPE at low filler content without any considerable loss of its ductility, but only when halloysite nanotubes are superbly distributed in the polyethylene matrix.

Additive manufacturing technologies decrease production time and costs in engineering industry but also in other industries. Parts produced with Fused Deposition Modeling (FDM) have typical low surface finish quality. This paper is aimed on research of surface finishing technologies applicable to improve the quality of FDM prototypes surface finish. Pretreated samples were blasted with sodium bicarbonate and glass beads. The values of R_aand R_zwere measured on the samples and compared the impact of selected pre-treatment, blasting medium and blasting conditions on surface finish quality of FDM prototypes.

This paper presents the result of a study evaluating the influence of alternative path generation strategy on structure and some mechanical properties of parts produced by Fused Deposition Modeling (FDM) technology. Several scientific investigations focused on resolving issues in FDM parts by modifying a path generation strategy to optimize its mechanical properties. In this study, an alternative strategy was proposed with the intention of minimizing internal voids and, thus, to improve mechanical properties. Polycarbonate samples made by this alternative path generation strategy were subjected to tensile strength test and metro-tomography structure evaluation. The results reveal that the structure observed on build models differs from a structure expected from path generation predicted by software Insight 9.1. This difference affected the tensile strength of samples.

The synthesis and study of metal-containing hydrogels, particularly those filled with nickel nanoparticles, is currently of interest to many researchers. This paper presents the results of an investigation of the structure and properties of Ni(0)-filled composites on the basis of 2-hydroxyethylmethacrylate copolymers (HEMA) with polyvinylpyrrolidone (PVP) and their hydrogels. The authors of the article are the first who propose the method to produce these materials by combining the processes of polymer matrix synthesis and a reduction of Ni²⁺ ions. Synthesis is carried out in one stage without complicated equipment and is technologically simple. It is determined by thermometric research that the temperature conditions required for the chemical reduction of Ni²⁺ are achieved due to the heat released during the exothermic reaction of HEMA polymerization in the presence of PVP. With the help of Fourier transform infrared analysis, and thermogravimetric and differential-thermal analysis, the formation of a crosslinked graft copolymer based on HEMA and PVP was confirmed, and its structural parameters, including the efficiency of PVP grafting, PVP content in the copolymer, and the molecular weight of the interstitial fragment of the polymer network, were investigated. The results obtained with scanning electron microscopy revealed that the size of the Ni(0) particles is about 500 nm. X-ray structural analysis of the composites obtained confirmed the existence of metal nickel particles. The strength, elastic, sorption, electrical, and magnetic properties of the obtained composites in the solid (dry) and elastic (swollen) physical states, depending on the composition of the copolymer and the content of the metal filler, have been investigated.

This paper presents the research results of the copolymer structure and properties of 2-hydroxyethylmethacrylate (HEMA) with polyvinylpyrrolidone (PVP) and their hydrogels, obtained by block polymerization in the presence of iron sulfate (II). By the methods of chemical analysis, IR spectroscopy, Thermogravimetric (TG) and Differential Thermal Analysis (DTA), the course of grafted copolymerization of HEMA on PVP with the formation of a cross-linked copolymer was confirmed. The results received by scanning electron microscopy showed that due to the copolymerization of HEMA with PVP, macroporous hydrogels with a pore size of 10–30 μm were obtained. The peculiarities of the structure formation of the obtained copolymers depending on the initial composition formulation were established and their structural parameters were investigated: PVP grafting efficiency, PVP content in copolymer, molecular weight of internodal fragment of polymer network, crosslinking degree, and crosslinking density. The interrelation of sorption–diffusion, physical–mechanical and thermophysical properties along with the structure of the obtained materials was proved. It was shown that with the increasing PVP content in the original composition, the efficiency of its grafting and crosslinking density of the polymer network decreased, but the surface hardness, heat resistance, sorption capacity of copolymers in the dry state, as well as ion permeability and elasticity in the swollen state increased, while their tensile strength deteriorated. It is proved that by changing the original composition formulation it is possible to change the structure and hence the properties of the copolymers in the desired direction.

Aluminium alloy sheets cause many problems in sheet metal forming processes owing to their tendency to gall the surface of the tool. The paper presents a method for the determination of the kinematic friction coefficient of friction pairs. The determination of coefficient of friction (COF) in sheet metal forming requires specialised devices that ‘simulate’ friction conditions in specific areas of the formed sheet. In this article, the friction behaviour of aluminium alloy sheets was determined using the strip drawing test. The 1-mm-thick 6082 aluminium alloy sheets in T6 temper were used as test material. Different values for nominal pressures (4.38, 6.53, 8.13, 9.47, 10.63, and 11.69 MPa) and different sliding speeds (10 and 20 mm/min.) were considered. The change of friction conditions was also realised with several typical oils (hydraulic oil LHL 32, machine oil LAN 46 and engine oil SAE 5W-40 C3) commonly used in sheet metal forming operations. Friction tests were conducted at room temperature (24 °C). The main tribological mechanisms accompanying friction (adhesion, flattening, ploughing) were identified using a scanning electron microscope (SEM). The influence of the parameters of the friction process on the value of the COF was determined using artificial neural networks. The lowest value of the COF was recorded when lubricating the sheet metal surface with SAE 5W40 C3 engine oil, which is characterised as the most viscous of all tested lubricants. In dry friction conditions, a decreasing trend of the COF with increasing contact pressure was observed. In the whole range of applied contact pressures (4.38–11.69 MPa), the value of the COF during lubrication with SAE 5W40 C3 engine oil was between 0.14 and 0.17 for a sliding speed of 10 mm/min and between 0.13 and 0.16 for a sliding speed of 20 mm/min. The value of the COF during dry friction was between 0.23 and 0.28 for a sliding speed of 10 mm/min and between 0.22 and 0.26 for a sliding speed of 20 mm/min. SEM micrographs revealed that the main friction mechanism of 6082-T6 aluminium alloys sheet in contact with cold-work tool steel flattens surface asperities. The sensitivity analysis of the input parameters on the value of COF revealed that oil viscosity has the greatest impact on the value of the COF, followed by contact pressure and sliding speed.