This paper explores the historical development of conventional plastics, tracing their evolution from early forms to their pervasive use in modern society. Its observations include the rise of mass plastic production during World War II and the post-war development, showcasing plastics’ economic and societal impact. The environmental repercussions of plastic pollution have led to increased global awareness and calls for sustainable alternatives. The emergence of bioplastics is investigated, including their classification, properties, applications, and challenges in scaling. This paper emphasises the urgency of adopting bioplastics for a sustainable future and discusses efforts towards homogenisation and standardisation across global markets.

Environmentally friendly packaging is becoming more popular as the number of companies implementing more sustainable solutions continues to increase, and consumers become more aware and choose more environmentally friendly options. However, not all environmentally friendly packaging meets all desirable properties, as some are only partially made of renewable raw materials or degrade over a long period of time. Bioplastics constructed from blends of gelatine and starch are solely made from renewable raw materials. Combined with relatively short degradation times, these materials have the potential to replace currently used, non-biodegradable film and single-use plastics. However, despite these advantages, further research is required to identify the best combination of raw materials, selectively and collectively, and to then optimise the appropriate physicochemical properties of the resultant bioplastics. In this study, gelatine from different sources (piscine, porcine, bovine) combined with potato starch was used to generate home-compostable bioplastics. These bioplastics were assessed in terms of water solubility, water content, opacity, surface roughness, and key mechanical properties such as tensile strength. Significant differences were found, particularly for piscine gelatine blends. It was concluded that piscine gelatine is a promising protein with highly relevant properties for the bioplastics industry.

To combat the release of petroleum-derived plastics into the environment the European Commission has adopted the EU plastics strategy, which aims for a complete ban on single-use plastics by 2030. Environmentally friendly and sustainable packaging like bioplastic is being up taken at significant levels by companies and consumers. In this study, the environmental impact of novel gelatine–starch blend bioplastics is investigated. The assessments included ecotoxicology with different species that can be found in marine and soil environments to simulate natural conditions. Microalgae, plant, and nematode species were chosen as these are representative of their habitats and are known for their sensitivity to pollutants. Degradation rates of these novel bioplastics were assessed as well as microbiome analysis of the soil before and after bioplastic degradation. The main findings of this study are that (i) the bioplastic generated can be fully biodegraded in soil environments at moderate conditions (20 °C) leaving no physical traces; (ii) bioplastic did not exhibit significantly adverse effects on any organisms assessed in this study; (iii) microbiome analysis of the soil after biodegradation showed a decrease in alpha diversity and a significant increase of Actinobacteria and Firmicutes phyla, which were dominative in the soil.

The valorisation of food by-products is an important step towards sustainability in food production. Tomatoes constitute one of the most processed crops in the world (160 million tonnes of tomatoes are processed every year), of which 4% is waste. This translates to 6.4 million tonnes of tomato skins and seeds. Currently, this waste is composted or is used in the production of low-value animal feed; higher value can be achieved if this waste stream is re-appropriated for more advanced purposes. Plant cuticle is a membrane structure found on leaves and fruit, including tomatoes, and is mainly composed of cutin. The main function of plant cuticle is to limit water loss from the internal tissue of the plant. Cutin, which can be recovered from the tomato skins by pH shift extraction, has hydrophobic (water repellent) properties and is therefore an ideal raw material for the development of a novel water-resistant coating. In this study, biomass-based bioplastics were developed. Unfortunately, although these bioplastics have good mechanical properties, their hydrophilic nature results in poor water barrier properties. To mitigate this, a very effective water-resistant coating was formulated using the cutin extracted from tomato peels. The water vapour permeability rates of the bioplastics improved by 74% and the percentage swelling of the bioplastic improved by 84% when treated with the cutin coating. With physicochemical properties that can compete with petroleum-based plastics, these bioplastics have the potential to address the growing market demand for sustainable alternatives for food packaging. Using ingredients generated from by-products of the food processing industries (circular economy), the development of these bioplastics also addresses the UN’s Sustainable Development Goal (SDG) 12, Sustainable Consumption and Production (SCP).