This paper presents a procedure for making facetted mirrors to use in linear Fresnel reflectors, considering the design of the transversal geometry, materials, and structure configuration. Four different assemblies of the structure that supports and shapes the mirror are documented and evaluated. An assembly that implies a curved, pleated aluminum rectangular plate with a thin silvered-glass mirror vacuum glued to the plate is defined as the optimal. The geometrical quality of the chosen mirror facet’s configuration is accomplished by photogrammetry.
Linear Fresnel solar collectors are a promising and emerging solution to contribute to renewable heat supply in industrial processes with thermal energy demand in the medium temperature range (<250 °C). An innovative linear Fresnel collector (LFC) prototype has been designed, patented, and built at the Plataforma Solar de Almería (PSA), Spain. This work presents the applied methodology, experimental device, and results obtained in the measurement of the flux density of concentrated solar radiation in the focal plane of the solar collector. The experimental results confirm that an average flux density of (9.8 ± 0.6) kW/m2 was obtained with a direct normal solar irradiance of (870 ± 10) W/m2 in tests performed in May 2002, which is a result similar to that obtained in optical simulations of the system.
Green hydrogen is poised to play a crucial role in the energy-transition process in developed countries over the coming years, particularly in those countries aiming to achieve net-zero emissions. Consequently, the for green hydrogen is expected to rise significantly. This article explores the fundamental methods of producing hydrogen, focusing on the oxidation reaction within a thermochemical solar cycle for the dissociation of steam. Solar thermochemical cycles have been extensively researched, yet they remain in the development stage as research groups strive to identify optimal materials and conditions to enhance process efficiency, especially at high temperatures. The article analyses theoretical foundations drawn from exhaustive scientific studies related to the oxidation of iron in steam, the relationship with the activation energy of the corrosive process, thermodynamic aspects, and the kinetic model of a heterogeneous reaction. Additionally, it presents various mechanisms of high-temperature oxidation, pH effects, reactors, and materials (including fluidized beds). This scientific review suggests that hydrogen production via a thermochemical cycle is more efficient than production via electrochemical processes (such as electrolysis), provided the limitations of the cycle’s reduction stage can be overcome.
Green hydrogen is a fuel that in the coming years will play a very important role in the energy transition process in developed countries, especially those seeking to reach a level of zero emis-sions, for which reason its demand is expected to increase significantly. This article analyzes the fundamentals to produce hydrogen, with a focus on the oxidation reaction of a thermochemical solar cycle for the dissociation of water vapor. Solar thermochemical cycles have been extensively investigated, but it is still in the development stage by groups of researchers who have focused on finding the right materials and conditions to improve the efficiency of the process, especially at high temperatures. The theoretical foundations are analyzed, compiled from exhaustive scientific investigations related to the oxidation of iron in water vapor, the relationship with the activation energy of the corrosive process, thermodynamic aspects and the kinetic model according to a heterogeneous reaction. In addition, some high temperature oxidation mechanisms, pH effects, reactors and materials (fluidized beds) used are presented. The scientific review indicates that the production of hydrogen through a thermochemical cycle is more efficient than electrochemical processes (electrolysis), if the limitations of the reduction stage of the cycle are overcome.