Xunyang is rich in various metal minerals and is one of the four major metal mining areas in Shaanxi province, China. To explore the effects of soil heavy metals and metalloid pollution on the environment and human health around the mining areas, four places—Donghecun (D), Gongguan (G), Qingtonggou (Q) and Nanshagou (N)—were selected as the sampling sites. Potential ecological risk (PER) and health risk assessment (HRA) models were used to analyze the environmental and health risks around the mining areas. The concentration of heavy metals (Cd, Cr, Pb, Zn, Ni, Cu, Hg) and metalloid (As) in cultivated land in the vicinity of Xunyang mining areas indicated that, except for Cu, the remaining elements detected exceeded the threshold values at some sites. The geo-accumulation index (I_Geo) revealed that soils in G and Q could be identified as being extremely contaminated. PER indicated that there was significantly high risk at G and Q for Hg. In N, Pb recorded the highest $E_r^i$ , which also demonstrates a considerable pre-existing risk. HRA indicated that the hazard index (HI) for both carcinogenic and non-carcinogenic risks was much higher among children than among adults, and the ingestion pathway contributed the greatest risk to human health, followed by the dermal pathway and inhalation. Because the HI values of the metals and metalloid in the study areas were all lower than 1, there was no significant non-carcinogenic risk. However, the carcinogenic risk for Cr is relatively higher, surpassing the tolerable values in G, Q, and N. This study analyzed the ecological risks and human health risks of heavy metals and metalloid in farmland soils near the sampling mining areas, and demonstrated the importance of environmental changes caused by land development in the mining industry.

Despite the immense potential in environmental remediation, the translation of magnetic nanomaterials (MNMs) from laboratory innovations to practical, field-scale applications remains hindered by significant technical and environmental challenges. This is particularly evident in soil environments—which are inherently more complex than aquatic systems and have received comparatively less research attention. Beginning with an outline of the fundamental properties that make iron-based MNMs effective as adsorbents and catalysts for heavy metals and organic pollutants, this review systematically examines their core contaminant removal mechanisms. These include adsorption, catalytic degradation (e.g., via Fenton-like reactions), and magnetic recovery. However, the practical implementation of MNMs is constrained by several key limitations, such as particle agglomeration, oxidative instability, and reduced efficacy in multi-pollutant systems. More critically, major uncertainties persist regarding their long-term environmental fate and biocompatibility. In light of these challenges, we propose that future efforts should prioritize the rational design of stable, selective, and intelligent MNMs through advanced surface engineering and interdisciplinary collaboration.

The ecological environment in Loess Plateau of Northern Shaanxi is fragile, so the soil pollution caused by the exploitation of coal resources cannot be ignored. With Shigetai Coal Mine in Loess Plateau of Northern Shaanxi as the object of study for field survey and sampling, the content of heavy metals in soil is analyzed, the environmental pollution in the research area is evaluated by the single factor pollution index method, comprehensive pollution index method and potential ecological risk index method, and the spatial distribution characteristics of heavy metals are discussed by the geostatistics method. According to the study results, the average contents of heavy metals Hg, Cd, Pb and Cr are 2.03, 1.36, 1.11 and 1.23 times of the soil background values in Shaanxi Province respectively and the average contents of other heavy metals are lower than the soil background values in Shaanxi Province; Hg and Cd show moderate variation while As, Pb, Cr, Zn, Ni and Cu show strong variation; the skewness coefficients and kurtosis coefficient of Cd, As and Cu in the soil within the research area are relatively high, and these elements are accumulated in large amounts. Single factor pollution index (Pi) and potential ecological risk index (E) indicate that heavy metal Hg is the main pollution factor and mainly distributed in the east and north of the research area. The comprehensive index of potential ecological risk (RI) of the research area is 1336.49, showing an extremely high ecological risk, and the distribution characteristics of potential ecological risk are consistent with that of potential ecological risk index (E) of Hg. The results of ecological risk warning show that Hg is in a slight warning status, while Cd, Pb and Cr are in a warning status. The areas with high ecological risk warning values are mainly distributed in the east and north, and the whole research area shows relatively obvious zonal distribution law. The soil is disturbed greatly during the coal mining, so the ecological governance of the mine area shall adapt to the local natural conditions and regional environmental characteristics and follow the principle of “adjusting governance measures based on specific local conditions and classifications”. An environmentally sustainable governance manner shall be adopted to realize the protection of the ecological environment and high-quality development of coal resources.

The study specifically focused on the Hongliulin mining area, where a total of 40 soil samples were meticulously collected and analyzed from within a 1000 m radius extending from the tailings dam. The findings revealed that soil pH within the 0–1000 m range generally leaned towards the alkaline side. In terms of soil nutrient content, encompassing factors such as soil organic matter (SOM), total nitrogen (TN), total phosphorus (TP), total potassium (TK), alkali nitrogen (AK), available phosphorus (AP), and quick-acting potassium (AK), the variations fell within the following ranges: 2.23–13.58 g/kg, 0.12–0.73 g/kg, 0.18–1.15 g/kg, 9.54–35.82 g/kg, 2.89–6.76 mg/kg, 3.45–11.25 mg/kg, and 5.86–130.9 mg/kg. Collectively, these values indicate relatively low levels of soil nutrients. Within the 0–500 m range of soil samples, the average concentrations of Cd, Hg, Pb, and As were 0.778, 0.198, 24.87, and 17.92 mg/kg, respectively. These concentrations exceeded the established soil background values of Shaanxi Province and emerged as the primary pollutants in the study area. Within this same range, the mean values of eight toxic metals (Pi) were ranked in the following descending order: 1.726 (Hg), 1.400 (As), 1.129 (Cr), 1.109 (Pb), 0.623 (Zn), 0.536 (Cd), 0.309 (Cu), and 0.289 (Ni). With the exception of Hg, As, Cr, and Pb, which exhibited slight pollution, the other toxic metals were found to be within acceptable pollution limits for this sampling range, in line with the results obtained using the geo-accumulation index method. The average potential ecological risk index for the eight toxic metals in the study area stood at 185.0, indicating a moderate overall pollution level. When assessing individual elements, the proportions of ecological risk attributed to Hg, As, Pb, and Cd were 34.57%, 27.44%, 25.11%, and 23.11%, respectively. This suggests that the primary potential ecological risk elements in the study area are Hg and As, followed by Cd and Pb. Notably, toxic metals Hg and Pb, as well as As and Pb, exhibited significant positive correlations within the sampling area, suggesting a common source. An analysis of the relationship between soil physicochemical properties and toxic metals indicated that soil pH, SOM, TN, and TP were closely linked to toxic metal concentrations. The toxic metal elements in the research area's soil exhibit moderate variability (0.16 < CV < 0.36) to high variability (CV > 0.36). Within the range of 0–200 m, the CV values for Cd and Hg exceed 1, indicating a high level of variability. The coefficient of variation for SOM, TP, AP, AK and TK is relatively high with the of 2.93, 2.36, 2.36, 21.01, 7.54. The soil in the sampling area has undergone significant disturbances due to human activities, resulting in toxic metal pollution and nutrient deficiencies.

Soil surface electrochemical properties, such as specific surface area and surface charge number, are important indexes to evaluate the agricultural soil quality change. However, there is not enough focus on the effect of different improved materials on the reclaimed soil surface electrochemical characteristics. Therefore, we selected maturing agent (TM), fly ash (TF), organic fertilizer (TO), maturing agent + organic fertilizer (TMO), fly ash + organic fertilizer (TFO), and no modified material (CK) treatment for 5 years of field location experiments to study the effects of different improved materials on the surface electrochemical properties of reclaimed soil from abandoned homestead. The results showed that, compared with CK treatment, the specific surface area, surface charge number, and surface charge density of reclaimed soil increased to 11.36–14.05 m² g⁻¹, 13.49–18.58 cmol kg⁻¹, and 1.14–1.76 C m⁻² after five years of application of different improved materials, respectively, and the number of surface charge under TFO, TMO, and TO treatment increased by 28.9%, 25.2%, and 37.7% compared with CK, respectively. Meanwhile, the specific surface area increased significantly (p < 0.05), showing an order of TFO > TMO > TO > TF > TM > CK. The surface electric field strength can reach the order of 10⁸ V m⁻¹. The statistical analysis results suggest that the contents of soil organic matter (SOM), silt, and clay were positively correlated with the soil surface electrochemical properties, which were the main factors for the changes of reclaimed soil surface electrochemical properties. Our research conclusion shows that in the process of reclamation of abandoned homestead in Loess Plateau, the application of different materials is helpful to improve the soil surface electrochemical properties, among which the organic–inorganic TFO treatment was a suitable improved material treatment for improving the surface electrochemical properties and fertility of reclaimed soil.

The ecological environment of the Loess Plateau in Northern Shaanxi is fragile, and the soil pollution caused by the development of coal resources can not be ignored. in this study, Shigetai Coal Mine in the Loess Plateau of Northern Shaanxi was selected for field investigation and sampling, the content of heavy metals in soil was analyzed, the environmental pollution status in the study area was evaluated by single factor pollution index method, comprehensive pollution index method and potential ecological risk index method, and the spatial distribution characteristics of heavy metals were discussed by geostatistics method. The results show that the average contents of heavy metals Hg, Cd, Pb and Cr are 2.03, 1.36, 1.11 and 1.23 times of the soil background value of Shaanxi Province, respectively. The average contents of other heavy metals are lower than the soil background value of Shaanxi Province. Hg and Cd show medium variation, as, Pb, Cr, Zn, Ni and Cu show strong variation. The skewness coefficient and kurtosis coefficient of soil Cd, as and Cu in the study area are high, In cumulative state. Single factor pollution index (P_i) and potential ecological risk index (E) show that heavy metal Hg is the main pollution factor, mainly concentrated in the East and north of the study area. The comprehensive index of potential ecological risk (RI) in the study area is 1336.49, showing a very high ecological risk, and its distribution characteristics are consistent with the distribution of potential ecological risk index (E) of Hg. The ecological risk early warning results show that Hg is in the light warning situation, Cd, Pb and Cr are in the early warning situation, the high value area of ecological risk early warning in the study area is mainly distributed in the East and North, and the whole study area presents an obvious zonal distribution law. In the process of coal mining, the soil is greatly disturbed. The ecological management of the mining area should be combined with the local natural conditions and regional environmental characteristics, and according to the principle of "adjusting measures to local conditions and implementing measures by classification". Adopt an environmentally sustainable approach to governance to achieve eco-environmental protection and high-quality development of coal resources.