Experiments of gas–liquid flow in a circular pipe for horizontal and inclined positions (upward/downward) are reported. The characteristics of two-phase flow in terms of liquid holdup (ε_(L)) and induced flow patterns are studied using three experimental techniques; time-averaged ε_(L) from permittivity profiles using electrical capacitance tomography (ECT), instantaneous ε_(L) using two fast-closing valves (TFCV), and high-speed camera images (HSCI) to capture/identify the formed flow patterns. Thus, this experimental setup enables the development of more well-defined flow patterns in gas–liquid two-phase flow and allows for multi-technique verification of the results. Taken from experimental measurements, a model is proposed to predict ε_(L) for high and low situations. The correlations are a function of the hydrodynamic dimensionless quantities which provide hydrodynamic similarity. Regarding different pipe orientations, ε_(L) predictions are comparable to ε_(L) from experimental measurements with accepted accuracy: 88% of the predictions are within ±5–15% and 98% are below ±20%. The correlations also were validated by reported results and against correlations available in the literature and show higher prediction accuracy. It is confirmed that the kinematic similarity which is achieved by the gas–liquid velocity ratios and the inertial forces influence the flow pattern and the liquid holdup.

This work proposes a method to distinguish between various flow patterns in a multiphase gas–liquid system. The complete discrimination between different flow patterns can be achieved by mapping the corresponding frequency and statistical parameters. These parameters are usually obtained from further analysis conducted on the signal data of the utilized sensor. The proposed technique is based on establishing interrelationships between these parameters, namely the mean (m), the standard deviation ( $\overline{\sigma }$ ), power spectral density (PSD), the width of the characteristic frequency peaks (Δƒ), the skewness ( ${\gamma }_1$ ) and the kurtosis ( ${\gamma }_2$ ). Therefore, a relatively simple electrical capacitance sensor with two electrodes was designed and implemented on a two-phase flow apparatus with a circular pipe. The experimental operating conditions comprised of different combinations of air–water superficial velocities at three inclinations (i.e., horizontal, upward 15° and upward 30°). This research discusses in specific the analysis underlying flow patterns identification method and the rationale for selecting the proposed approach. The results showed that some parameters found to be more valuable than others such as m, $\overline{\sigma }$ and Δƒ. Besides, combining two sets of these statistical graphs which are (a) $\overline{\sigma }$ vs. Δƒ with Δƒ vs. m (or Δƒ vs. total power), (b) Δƒ vs. total power with ${\gamma }_1$ vs. $\overline{\sigma }$ (or ${\gamma }_2$ vs. $\overline{\sigma }$ ), and (c) $\overline{\sigma }$ vs. m with Δƒ vs. m (or Δƒ vs. total power), allowed all flow patterns field to be identified clearly at all inclinations. It is therefore concluded that for any gas–liquid multiphase flow system, the reported approach can be used reliably to discriminate between different generated flow patterns.

COx-free H₂, along with uniform carbon nanotubes, can be achieved together in high yield by CH₄ decomposition. It only needs a proper catalyst and reaction condition. Herein, Fe-based catalyst dispersed over titania-incorporated-alumina (Fe/Ti-Al), with the promotional addition of lanthanides, like CeO₂ and La₂O₃, over it, is investigated for a methane decomposition reaction at 800 °C with GHSV 6 L/(g·h) in a fixed-bed reactor. The catalysts are characterized by temperature-programmed reduction (TPR), powder X-ray diffraction (XRD), Raman spectroscopy, and transmission electron microscopy (TEM). The promoted catalysts are facilitated with higher surface area and enhanced dispersion and concentration of active sites, resulting in higher H₂ and carbon yields than unpromoted catalysts. Ceria-promoted 20Fe/Ti-Al catalyst had the highest concentration of active sites and always attained the highest activity in the initial hours. The 20Fe-2.5Ce/Ti-Al catalyst attains >90% CH₄ conversion, >80% H₂-yield, and 92% carbon yield up to 480 min time on stream. The carbon nanotube over this catalyst is highly uniform, consistent, and has the highest degree of crystallinity. The supremacy of ceria-promoted catalyst attained >90% CH₄ conversion even after the second cycle of regeneration studies (against 87% in lanthanum-promoted catalyst), up to 240 min time on stream. This study plots the path of achieving catalytic and carbon excellence over Fe-based catalysts through CH₄ decomposition.