Cellulose fibers are promoted for use in various textile applications due their sustainable nature. Cellulose-based fibers vary considerably in their mechanical and flammability properties depending on their chemical composition. The chemical composition of a cellulose-based fiber is further dependent on their source (i.e., seed, leaf, cane, fruit, wood, bast, and grass). Being organic in nature, cellulose fibers, and their products thereof, pose considerable fire risk. In this work we have compared the flammability properties of cellulose fibers obtained from two different sources (i.e., cotton and peat). Compared to cotton cellulose textiles, peat-based cellulose textiles burn longer with a prominent afterglow which can be attributed to the presence of lignin in its structure. A series of phosphoramidates were synthesized and applied on both cellulose textiles. From thermogravimetric and pyrolysis combustion flow analysis of the treated cellulose, we were able to relate the flame retardant efficacy of the synthesized phosphorus compounds to their chemical structure. The phosphoramidates with methyl phosphoester groups exhibited higher condensed phase flame retardant effects on both types of cellulose textiles investigated in this study. In addition, the bis-phosphoramidates exhibited higher flame retardant efficacy compared to the mono-phosphoramidates.
This paper provides a review of recent studies on the weave factor along with the effect of weave parameters and particularly the weave structure on various properties of woven fabric. The weave structure can be considered as one of the prime parameters that contributes to the dominant physical and qualitative properties of the woven fabric. This study analyzed not only the parameters that significantly influence the properties of the woven fabric, but also the weave factors for the estimation of the weave that were proposed by earlier scientists. This review paper highlights the impact of weave structure on the physical and mechanical, thermo-physiological and comfort properties, and some special application properties of woven fabrics. This work seeks to serve as a future reference for related research.
Four types of nonwovens were prepared from different sections of the banana tree e.g., outer bark (OB), middle bark (MB), inner bark (IB) and midrib of leaf (MR) by wet laid web formation. They were reinforced with two different types of matrices e.g., epoxy and polyester, to make eight variants of composites. Treatments including alkali on raw fibers, water repellent on nonwovens and gamma radiation on composites were applied in order to investigate their effects on properties of the composites such as water absorbency, tensile strength (TS), flexural strength (FS) and elongation at break (Eb%). Variations in the morphological structure and chemical composition of both raw banana fibers and fibers reinforced by the treatments were analyzed by Fourier Transform Infrared (FTIR) and Scanning Electron Microscopy (SEM). OB composites exhibited higher water absorbency, TS and FS and lower Eb% compared to other types of composites. Epoxy composites were found to have 16% lower water absorbency, 41.2% higher TS and 39.1% higher FS than polyester composites on an average. Water absorbency of the composites was reduced 32% by the alkali treatment and a further 63% by water repellent treatment. TS and FS of the composites were on average improved 71% and 87% by alkali treatment and a further 30% and 35% by gamma radiation respectively.
Woven jute fabric was used as a reinforcing material for making two types of composite, named Jute/PR and Jute/Epoxy, with two different matrixes of polyester resin and epoxy, respectively, by hand layup techniques. Five different doses of gamma radiation from 100 to 500 krad were used to investigate the effects of the mechanical properties of the composites and the jute fabrics. Though gamma radiation improved the mechanical properties, such as the tensile strength (TS) and Young’s modulus (Y), and decreased the elongation at break % (Eb%) of the composites, it deteriorated all these properties for jute fabrics. The highest values of TS and Y and the lowest value of Eb% were found to be 39.44 Mpa, 1218.33 Mpa, and 7.68% for the Jute/PR; and 48.83 Mpa, 1459.67 Mpa, and 3.68% for the Jute/Epoxy composites, respectively, at a 300 krad gamma radiation dose. A further increase in dose altered all these properties; thus, 300 krad was found to be the optimum dose for both of the composites. Between the two composites, gamma radiation influenced the Jute/PR composite more than the Jute/Epoxy composite.
Jute is a ligno-cellulosic natural fiber that ranks second in terms of the volume of cellulosic fibers and is extensively utilized for technical textile applications. The goal of this study is to determine the flame-retardance (FR) properties of pure Jute and Jute-Cotton fabrics treated with Pyrovatex CP New at concentrations of 90% (owf), M:L: 1:7. Both fabrics exhibited a substantial improvement in flame-retardancy. After the ignition period, the recorded flame spread time in both FR treated fabrics was zero seconds; whereas for untreated Jute and Jute-Cotton fabrics, the flame spread time was measured 21 s and 28 s, respectively, to burn their entire length (15 cm). Within these flame-spread times, the length of the char was 2.1 cm and 2.57 cm in the Jute and Jute-Cotton fabrics, respectively. After FR finishing, on both fabrics in the warp and weft directions, the physico-mechanical properties significantly decreased. The deposition of flame-retardant finishes on the fabric surface was determined by Scanning Electron Microscope (SEM) images. According to Fourier Transform Infra-Red Spectroscopy (FTIR) analysis, the flame-retardant chemical had no effect on the inherent properties of the fibers. Thermogravimetric analysis (TGA) analysis revealed that FR treated fabrics had early degradation, resulting in the formation of more char than in the untreated samples. After FR treatment, both fabrics showed a significant improvement in residual mass (more than 50%). Although the formaldehyde content observed in the FR treated samples was significantly greater, it was still within the permitted limit formaldehyde content in textiles intended for outerwear and not worn next to the skin. The results of this investigation demonstrate the potential use of Pyrovatex CP New in jute-based materials.
The work is devoted to the study of the geometric parameters of a knitted loop. It has been found that the optimal model is a loop model detailed at the yarn level, which considers the change in the cross-sectional shape and sets the properties of the porous material in accordance with the internal porosity of the yarn. A mathematical description of the coordinates of the characteristic points of the loop and an algorithm for calculating the coordinates of the control vertices of the second order spline, which determine the configuration of the yarn axes in the loop, are presented in this work. To create 3D models, Autodesk AutoCAD software and Structura 3D software, developed in the AutoLisp programming language, were used. The simulation of the air flow process was carried out in the Autodesk CFD Simulation environment. For the experimental investigation, plane knits from 44 tex × 3 linear density ultra-high molecular weight polyethylene yarns were produced, and their air permeability was tested according to Standard DSTU ISO 9237:2003. The results obtained during the laboratory experiment and simulation differed by less than 5%.