The manuscript is focused on corrosion behavior of a Cr coating under CANada Deuterium Uranium(CANDU) primary circuit conditions. The Cr coating is obtained via the thermionic vacuum arc procedure on Zircaloy -4 cladding. The surface coating characterization was performed using metallographic analysis and scanning electron microscopy (SEM) with an energy dispersive spectra detector (EDS), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) investigations. The thickness of the Cr coating determined from SEM images is around 500 nm layers After the autoclaving period, the thickness of the samples increased in time slowly. The kinetic of oxidation established a logarithmic oxidation law. The corrosion tests for various autoclaving periods of time include electrochemical impedance spectroscopy (EIS) and potentiodynamic tests, permitting computing porosity and efficiency of protection. All surface investigations sustain electrochemical results and promote the Cr coating on Zircaloy-4 alloy autoclaved for 3024 h as the best corrosion resistance based on decrease in corrosion current density values simultaneously with the increase of the time spent in autoclave. A slow increase of Vickers micro hardness was observed as a function of the autoclaved period as well. The value reached for 3024 h being 219 Kgf/mm² compared with 210 Kgf/mm² value before autoclaving.

The paper’s aim is the assessment of corrosion behaviour of a CrN_x-coated 310 H stainless steel under simulated supercritical water conditions (550 °C and 25 MPa) for up to 2160 h. The CrN_x coating was obtained by the thermionic vacuum arc (TVA) method. The oxides grown on this coating were characterized using metallographic and gravimetric analysis, SEM with EDS, and grazing incidence X-ray diffraction (GIXRD). A diffusion mechanism drives oxidation kinetics because it follows a parabolic law. By XRD analysis, the presence of Cr₂O₃ and Fe₃O₄ on the surface of the autoclaved CrN_x-coated 310 H samples were highlighted. Corrosion susceptibility assessment was performed by electrochemical impedance spectroscopy (EIS) and linear potentiodynamic polarization. EIS impedance spectra show the presence of two capacitive semicircles in the Nyquist diagram, highlighting both the presence of the CrN_x coating and the oxide film formed during autoclaving on the 310 H stainless steel. Very low corrosion rates, with values up to 11 nm × year⁻¹, obtained in the case of autoclaved for 2160 h, CrN_x-coated samples indicated that the oxides formed on these samples are protective and provide better corrosion resistance. The determination of micro hardness Vickers completed the above investigation.

The paper presents the investigation of a series of silver-incorporated diamond-like carbon (Ag-DLC) coatings with increasing Ag content on Ti50Zr and deposited using high voltage anodic plasma (HVAP). The coatings surface properties were analyzed with scanning electron microscope (SEM), atomic force microscope (AFM), and contact angle determinations. Electrochemical tests were performed in Afnor artificial saliva and evaluated by potentiodynamic polarization and electrochemical impedance spectroscopy. Based on these properties, comparisons of coatings performance were linked with the amount of deposited Ag. Increasing the Ag content led to the increase of the corrosion resistance and to the decrease of the forces exhibited on the surface. The hydrophobic character of the coating with the highest Ag amount could prevent thrombosis, thus suggesting its possible use for medical implants.

Carbon–metal composite NiCrFeC coatings, prepared with and without controlled oxygen addition, were investigated to evaluate the influence of oxygen on the structure, mechanical response, and tribological performance. X-ray diffraction revealed that oxygen-containing films (NiCrFeC + O₂) exhibit a mixed metallic–oxide microstructure with CrNi, CrO, and NiO phases, whereas oxygen-free coatings show only CrNi crystalline peaks. The incorporation of oxygen led to a substantial increase in nano-hardness, from 0.84 GPa for NiCrFeC to 1.59 GPa for NiCrFeC + O₂. Scratch testing up to 100 N indicated improved adhesion and higher critical loads for the oxygen-rich coatings. Tribological measurements performed under dry sliding conditions using a sapphire ball showed a significant reduction in friction: NiCrFeC + O₂ stabilized at ~0.20, while NiCrFeC exhibited values between 0.25 and 0.35 at 0.5 N and 0.4–0.5 at 1 N, accompanied by non-uniform sliding due to coating failure. Wear-track analysis confirmed shallower penetration depths and narrower wear scars for NiCrFeC + O₂, despite similar initial roughness (~35 nm). These findings demonstrate that oxygen incorporation enhances hardness, adhesion, and wear resistance while substantially lowering friction, making NiCrFeC + O₂ coatings promising for low-friction dry-sliding applications.

(1) Background: The high-voltage anodic-plasma (HVAP) coating technique has a series of specificities that are not simultaneously met in other deposition methods. This paper aimed at assessing the potential of HVAP to synthesize quality multilayers for X-ray optics. (2) Methods: Nanolayers of W, Ta, B, and Si were deposited as mono-, bi-, and multilayers onto very smooth glass substrates by HVAP, and their thickness and density were analyzed by X-ray reflectometry. The minimal film thickness needed to obtain continuous nanolayers was also investigated. (3) Results: Nanolayer roughness did not increase with layer thickness, and could be lowered via deposition rate, with values as low as 0.6 for the W nanolayer. Minimal film thickness for continuous films for the studied metals was 4 nm (W), 6 nm (Ta), 2.5 nm (B), and 6 nm (Si). (4) Conclusions: The investigation revealed the range of parameters to be used for obtaining quality nanolayers and multilayers by HVAP. Advantages and possible improvements are discussed. This deposition technique can be tailored for demanding applications such as X-ray mirrors.

NiCr composite coatings on stainless steel were obtained by the simultaneous deposition of Cr and Ni, using thermionic vacuum arc (TVA) technology. The main aim of this paper is to study the influence of graphite and oxygen incorporation on the structural, mechanical, and tribological properties of the resulting coatings. The deposition geometry was designed to maintain a relative constant Cr/Ni ratio while inducing a controlled compositional gradient in carbon content. An additional batch of samples was synthesized under reactive conditions by introducing a controlled O₂ flow while maintaining the same plasma parameters during deposition. The coatings were deposited on both Si wafers and AISI 304 stainless steel substrates. The elemental composition and phase structure were analyzed by scanning electron microscopy- energy dispersive spectroscopy (SEM-EDS) and grazing-incidence X-ray diffraction (GIXRD), revealing the formation of mixed CrNi intermetallic phases, nickel carbide (Ni₃C), and, under reactive conditions, chromium and nickel oxides. Increasing the oxygen content led to a progressive structural transition from metallic–carbide mixtures to predominantly crystalline oxide phases. Tribological performance was evaluated using a ball-on-disk tribometer, and the results demonstrated a significant reduction and stabilization of the friction coefficient for oxygen-containing coatings, together with enhanced wear resistance. SEM and EDS analyses of the wear tracks confirmed the formation of protective oxide layers that effectively reduced coating removal during sliding. Nanoindentation measurements revealed a substantial increase in hardness from ~4 GPa for binary Cr–Ni coatings to ~9 GPa for ternary Cr–Ni–C films, with the highest hardness values obtained for oxygen-enriched coatings. The results highlight the synergistic role of carbon and oxygen in tailoring the microstructure and enhancing the mechanical and tribological performance of Cr–Ni-based composite coatings deposited by TVA, demonstrating their potential for protective applications under demanding operating conditions. This work demonstrates that controlled oxygen incorporation during TVA deposition can be used as an effective tool to tailor simultaneously the phase composition, surface chemistry, mechanical response, and tribological behavior of Cr–Ni–C coatings without compromising coating integrity.