Soil is a non-renewable natural resource. However, the current rates of soil usage and degradation have led to a loss of soil for agriculture, habitats, biodiversity, and to ecosystems problems. Urban and former industrial areas suffer particularly of these problems, and compensation measures to restore environmental quality include the renaturation of dismissed areas, de-sealing of surfaces, or the building of green infrastructures. In this framework, the development of methodologies for the creation of soils designed to mimic natural soil and suitable for vegetation growth, known as constructed soils or technosols, are here reviewed. The possible design choices and the starting materials have been described, using a circular economy approach, i.e., preferring non-contaminated wastes to non-renewable resources. Technosols appear to be a good solution to the problems of land degradation and urban green if using recycled wastes or by-products, as they can be an alternative to the remediation of contaminated sites and to importing fertile agricultural soil. Nevertheless, waste use requires analysis to ensure the salubrity of the starting materials. Moreover, materials produced on site or nearby minimize the cost and the environmental impact of transport, thus the involvement of local stakeholders in the urban land management must be encouraged.

In the last decade, extensive studies have been conducted to quantify the influence of different factors on potentially toxic elements (PTE) bioaccessibility in soil; one of the most important is soil size fraction. However, there is no agreement about the size fraction and the methods to investigate bioaccessibility, as very few review articles are available on soil PTE bioaccessibility and none addressed the influence of particle size on PTE bioaccessibility. This study provides a review of the relations between PTE bioaccessibility and soil particle size fractions. The available research indicates that PTE bioaccessibility distribution across different size fractions varies widely in soil, but a general trend of higher bioaccessibility in finer size fraction was found. The different elements may exhibit different relationships between bioaccessibility and soil size fraction and, in some cases, their bioaccessibility seems to be more related to the source and to the chemico-physical form of PTE in soil. Often, soil pollution and related health risk are assessed based on PTE total concentration rather than their bioaccessible fraction, but from the available studies it appears that consensus must be pursued on the methods to determine PTE bioaccessibility in the fine soil size fractions to achieve a more accurate human health risk assessment.

In February 2017 the “Carbonaceous Aerosol in Rome and Environs (CARE)” experiment was carried out in downtown Rome to address the following specific questions: what is the color, size, composition, and toxicity of the carbonaceous aerosol in the Mediterranean urban background area of Rome? The motivation of this experiment is the lack of understanding of what aerosol types are responsible for the severe risks to human health posed by particulate matter (PM) pollution, and how carbonaceous aerosols influence radiative balance. Physicochemical properties of the carbonaceous aerosol were characterised, and relevant toxicological variables assessed. The aerosol characterisation includes: (i) measurements with high time resolution (min to 1–2 h) at a fixed location of black carbon (eBC), elemental carbon (EC), organic carbon (OC), particle number size distribution (0.008–10 $\mathsf{\mu }$ m), major non refractory PM₁ components, elemental composition, wavelength-dependent optical properties, and atmospheric turbulence; (ii) 24-h measurements of PM₁₀ and PM_2.5 mass concentration, water soluble OC and brown carbon (BrC), and levoglucosan; (iii) mobile measurements of eBC and size distribution around the study area, with computational fluid dynamics modeling; (iv) characterisation of road dust emissions and their EC and OC content. The toxicological assessment includes: (i) preliminary evaluation of the potential impact of ultrafine particles on lung epithelia cells (cultured at the air liquid interface and directly exposed to particles); (ii) assessment of the oxidative stress induced by carbonaceous aerosols; (iii) assessment of particle size dependent number doses deposited in different regions of the human body; (iv) PAHs biomonitoring (from the participants into the mobile measurements). The first experimental results of the CARE experiment are presented in this paper. The objective here is to provide baseline levels of carbonaceous aerosols for Rome, and to address future research directions. First, we found that BC and EC mass concentration in Rome are larger than those measured in similar urban areas across Europe (the urban background mass concentration of eBC in Rome in winter being on average 2.6 ± 2.5 $\mathsf{\mu }$ g · m ${}^{-3}$ , mean eBC at the peak level hour being 5.2 (95% CI = 5.0–5.5) $\mathsf{\mu }$ g · m ${}^{-3}$ ). Then, we discussed significant variations of carbonaceous aerosol properties occurring with time scales of minutes, and questioned on the data averaging period used in current air quality standard for PM ${}_{10}$ (24-h). Third, we showed that the oxidative potential induced by aerosol depends on particle size and composition, the effects of toxicity being higher with lower mass concentrations and smaller particle size. Albeit this is a preliminary analysis, findings reinforce the need for an urgent update of existing air quality standards for PM ${}_{10}$ and PM ${}_{2.5}$ with regard to particle composition and size distribution, and data averaging period. Our results reinforce existing concerns about the toxicity of carbonaceous aerosols, support the existing evidence indicating that particle size distribution and composition may play a role in the generation of this toxicity, and remark the need to consider a shorter averaging period (<1 h) in these new standards.