In order to study the deterioration and mechanism of dry–wet cycles and sulfate attack on the performance of concrete in seaside and saline areas, the deterioration of compressive strength of concrete with different water cement ratios under different erosion environments (sodium sulfate soaking at room temperature and coupling of dry–wet cycling and sodium sulfate) was studied here. At the same time, ICT (industrial computed tomography) and NMR (nuclear magnetic resonance) techniques were used to analyze the internal pore structure of concrete under different erosion environments. The results show that the compressive strength under different erosion environments increases first and then decreases, and the dry–wet cycle accelerates the sulfate erosion. With the increase of dry and wet cycles, larger pores are filled with erosion products and developed into small pores in the early stage of erosion; in the later stage of erosion, the proportion of larger pores increases, and cracks occur inside the sample. In the process of sulfate soaking and erosion, the smaller pores in the concrete account for the majority. As the sulfate erosion continues, the T₂ spectrum distribution curve gradually moves right, and the signal intensity of the larger pores increases.

Compressive properties are commonly weak parts in structural application of fiber composites. Matrix modification may provide an effective way to improve compressive performance of the composites. In this work, the compressive property of epoxies (usually as matrices of fiber composites) modified by different types of nanoparticles was firstly investigated for the following study on the compressive property of carbon fiber reinforced epoxy composites. Carbon fiber/epoxy composites were fabricated by vacuum assisted resin infusion molding (VARIM) technique using stitched unidirectional carbon fabrics, with the matrices modified with nanosilica, halloysite, and liquid rubber. Testing results showed that the effect of different particle contents on the compressive property of fiber/epoxy composites was more obvious than that in epoxies. Both the compressive and flexural results showed that rigid nanoparticles (nanosilica and halloysite) have evident strengthening effects on the compression and flexural responses of the carbon fiber composite laminates fabricated from fabrics.

Polyvinyl alcohol (PVA) is a kind of water-soluble polymer, which has been widely used in different industries due to its excellent mechanical and chemical properties. In this paper, the effects of polyvinyl alcohol with different hydrolysis and polymerization degrees on the rheological properties of cement mortar are studied. The results show that the rheological properties of PVA-modified cement mortar can be described by the modified Bingham model. The yield stress of modified cement mortar is less than that of unmodified mortar when the degree of polymerization and the content of PVA are small. With the increase of polyvinyl alcohol content and polymerization degree, the yield stress and plastic viscosity of modified cement mortar increase sharply, which are larger than those of the unmodified cement mortar. However, the effect of hydrolysis degree of PVA on yield stress and plastic viscosity of modified cement mortar is not obvious.

The objective of this manuscript is to study the effects of nano-particle addition on the durability and internal deterioration of concrete subject to freezing and thawing cycles (FTCs). Fifteen nm of SiO₂, 30 nm of SiO₂, and 30 nm of TiO₂ were added to concrete to prepare specimens with different contents. All the specimens were subjected to FTCs from 0 to 75. The mass of each specimen was measured once the FTCs reached 25, 50, and 75. Then the freezing and thawing resistance of the concrete was evaluated by computing the mass loss ratio. The pore fluid size distribution of the concrete was detected using nuclear magnetic resonance (NMR). The deterioration of the concrete subjected to FTCs was detected by industrial computed tomography (CT). The effect of different nano-particle sizes, different contents of nano-particles, and different types of nano-particles on the freezing and thawing resistance, the pore size, distribution, and the deterioration of the concrete were analyzed. The effects of FTCs on the pore size distribution and the internal deterioration of concrete were also studied. Compared to 30 nm-Nono-SiO₂ (NS), 15 nm-NS had a better effect in improving the internal structure for concrete, and 30 nm-Nano-TiO₂ (NT) also had a better effect in preventing pore and crack expansion.

The exposure of recycled concrete (RCA) to a sulphate environment in cold regions makes it crucial to overcome the freeze–thaw cycling effects of recycled concrete. Based on steel and basalt fiber reinforced recycled concrete, the freeze–thaw cycle resistance of recycled concrete was studied by exposure to a sulphate environment. The mass loss, dynamic elastic modulus loss and compressive strength loss of the specimens were studied through freeze–thaw cycle experiments. SEM techniques were used to explore the effect of fiber distribution on the freeze–thaw resistance of recycled concrete. The freeze–thaw mechanism of the basalt fiber and steel fiber recycled concrete exposed to a sulphate environment has also been summarized. The results show that, based on the sulphate environment, the composite fiber recycled concrete has a higher stability in terms of mass loss and relative dynamic modulus of elasticity than single fiber concrete. The compressive strength of S_0.9RC (recycled concrete with 0.9% steel fibers) and BF_5.5RC (recycled concrete containing 5.5 kg/m³ basalt fibers) increased by 8.62% and 13.62%, respectively, compared to normal recycled concrete after 28 days of maintenance; and after 150 freeze–thaw cycles, the compressive strength increased by 41.39% and 47.54%, respectively; compared to ordinary natural aggregate concrete, the compressive strength of S_0.9RC and BF_5.5RC increased by 32.90% and 27.36%, respectively. The compressive strength of the S_1.5BF_7.5RC (recycled concrete with 1.5% steel fibers and 7.5 kg/m³ basalt fibers) composite basalt fiber–steel fiber concrete also increased by 42.82%. SEM techniques indicated that the basalt fiber in the recycled concrete exhibited fracture damage, which inhibited the development of microcracks within the concrete. When the recycled concrete is subjected to coupled sulphate and freeze–thaw cycles, freezing occurs from the outside in, with ice crystals extending along the cracks into the matrix. Prior to freezing, a negative pressure is created by the compression of the air and the contraction of the salt solution, which pulls the external solution inwards. The brine is in a state where ice and water coexist during the continuous cooling process. The salt solution migrates from the inside to the outside during heating and melting.

The metro engineering is in an environment rich in stray current and groundwater, which will accelerate concrete corrosion. In this study, the corrosion of cement-based materials, under stray current, consisting of direct current, was investigated, and the effects of stray current magnitude, water-binder ratio, fly ash, and silica fume on its corrosion were analyzed. The results show that, as the energisation duration of the stray current increases, the mass of the cathode side leachables increases, and the compressive strength of the cement-based materials decreases overall; at 120 d of stray current, the water-binder ratio of 0.50 shows the least reduction in strength, compared to the others; the mass of cathode side leachables decrease significantly with the increase in fly ash content; when fly ash content is 15%, the mass of cathode side leachables is the least, and the decrease in the compressive strength at 120 d of stray current is the smallest. At 10% silica fume content, the mass of the cathode side leachables is the least, and the decrease in the compressive strength of the cement-based materials at 120 d of stray current is the smallest. In general, the corrosion resistance is relatively good at 15% fly ash content and 10% silica fume content under stray current.