The combination of TiO₂ photocatalyst and magnetic oxide nanoparticles enhances the separation and recoverable properties of nanosized TiO₂ photocatalyst. Metal-modified (Me = Pd, Au, Pt, Cu) TiO₂/SiO₂@Fe₃O₄ nanocomposites were prepared by an ultrasonic-assisted sol-gel method. All prepared samples were characterized by X-ray powder diffraction (XRD) analysis, Brunauer-Emmett-Teller (BET) method, X-ray photoelectron spectroscopy (XPS), scanning transmission electron microscopy (STEM), Mott-Schottky analysis and photoluminescence spectroscopy (PL). Phenol oxidation pathways of magnetic photocatalysts modified with Pt, Pd, Cu and Au nanoparticles proceeded by generation of reactive oxygen species, which oxidized phenol to benzoquinone, hydroquinone and catechol. Benzoquinone and maleic acid were products, which were determined in the hydroquinone oxidation pathway. The highest mineralization rate was observed for Pd-TiO₂/SiO₂@Fe₃O₄ and Cu-TiO₂/SiO₂@Fe₃O₄ photocatalysts, which produced the highest concentration of catechol during photocatalytic reaction. For Pt-TiO₂/SiO₂@Fe₃O₄ nanocomposite, a lack of catechol after 60 min of irradiation resulted in low mineralization rate (CO₂ formation). It is proposed that the enhanced photocatalytic activity of palladium and copper-modified photocatalysts is related to an increase in the amount of adsorption sites and efficient charge carrier separation, whereas the keto-enol tautomeric equilibrium retards the rate of phenol photomineralization on Au-TiO₂/SiO₂@Fe₃O₄. The magnetization hysteresis loop indicated that the obtained hybrid photocatalyst showed magnetic properties and therefore could be easily separated after treatment process.

In this paper, the production of CaCO₃ particles via the carbonation route in the reaction of CaCl₂ and CO₂, using NH₃ as a promoter of CO₂ absorption, was studied. The solvents used as the reaction media for CaCO₃ precipitation were aqueous solutions of methanol, isopropanol and dimethyl sulfoxide (DMSO), in a concentration range of 0–20% (v/v). It was found that the presence of an organic additive influenced the precipitation rate, the content of vaterite in the obtained product, the morphology and the size of the precipitated CaCO₃ particles, as well as the rate of its transformation into calcite. The presence of all added organic solvents reduced the vaterite concentration in the produced CaCO₃ both at the end of the reaction and after incubation in the reaction medium for 1 h. However, the transformation of vaterite particles into calcite in the tested solutions was slower when the 4 h and 24 h procedures were compared. The interactions of solvents with calcite and vaterite were compared using HPLC tests. DMSO molecules interacted with vaterite particles the most strongly, while the interaction of isopropanol with this polymorph was the weakest. The opposite effect was observed for interactions with calcite particles, and the affinity decreased in the series: isopropanol, methanol, DMSO.

In this work, thin layers of MoO₃were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation (K⁺) into the MoO₃structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. MoO₃thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering system. The Tauc and Mott–Schottky plots analysis were performed in order to determine the energy bands position of the investigated material. The photointercalation effect of K⁺on photoelectrochemical properties of FTO/MoO₃photoanodes was studied using electrochemical techniques performed under simulated solar light illumination. It was proven that pristine MoO₃layers cannot act as effective photoanodes for water splitting due to the utilization of the photoexcited electrons in the intercalation process. The photochromic phenomenon related to Mo⁶⁺centers reduction, and K⁺intercalation occurs at a potential range in which the photoanode exhibits photoelectrochemical activity towards water photooxidation.