To achieve durable high-performance fiber-reinforced concrete that meets economic requirements, this paper introduces a hybrid intelligent framework based on the Latin hypercube experimental design, response surface methodology (RSM), and the NSGA-III algorithm for optimizing the mix design of high-performance fiber-reinforced concrete. The developed framework allows for the prediction of concrete performance and obtains a series of Pareto optimal solutions through multi-objective optimization, ultimately identifying the best mix proportion. The decision variables in this optimization are the proportions of various materials in the concrete mix, with concrete’s frost resistance, chloride ion permeability resistance, and cost as the objectives. The feasibility of this framework was subsequently validated. The results indicate the following: (1) The RSM model exhibits a high level of predictive accuracy, with coefficient of determination (R-squared) values of 0.9657 for concrete frost resistance and 0.9803 for chloride ion permeability resistance. The RSM model can be employed to construct the fitness function for the optimization algorithm, enhancing the efficiency of multi-objective optimization. (2) The NSGA-III algorithm effectively balances durability and cost considerations to determine the optimal mix proportion for the concrete. After multi-objective optimization, the chloride ion permeability resistance and frost resistance of the high-performance fiber-reinforced concrete improved by 38.1% and 6.45%, respectively, compared to the experimental averages, while the cost decreased by 2.53%. The multi-objective optimization method proposed in this paper can be applied to mix design for practical engineering projects, improving the efficiency of concrete mix design.

The combined action of freeze–thaw cycles and chloride-induced corrosion are generally recognized as one of the main causes of the degradation of the mechanical properties and seismic performance of reinforced concrete (RC) structures in the northern frozen coastal regions. To investigate the degradation mechanisms of the seismic performance of RC columns subjected to the combined action of freeze–thaw cycles and chloride-induced corrosion, the impact of freeze–thaw cycles on the chloride diffusion coefficient of concrete was studied through concrete deterioration tests and theoretical analysis. This paper proposed a time-dependent deterioration model for RC columns, which is suitable to consider the combined action of freeze–thaw cycles and chloride-induced deterioration. The proposed deterioration model could be applied to the investigations of time-dependent seismic performance and the seismic fragility of RC columns. Based on the established deterioration model, this paper proposed a time-dependent seismic fragility analysis framework for the aging RC columns, considering the combined action of freeze–thaw cycles and chloride-induced corrosion. In addition, a representative three-span RC continuous T-shaped girder bridge that is located in the high-latitude northern frozen coastal regions of China was taken as the case study, and the time-dependent seismic fragility analysis of RC columns was conducted considering the involved uncertainties in geometric parameters, the deterioration mechanisms of the materials, and ground motions. The time-dependent seismic fragility curves of RC columns were obtained at different service time points. The results indicated that the combined action of freeze–thaw cycles and chloride-induced deterioration had a significant influence on the time-dependent seismic responses of the deteriorating RC columns. Under the combined action of freeze–thaw cycles and chloride-induced corrosion, when the RC bridge was in service for 75 years, the stirrup strength decreased by 3.88% and the cross-sectional area decreased by 30.03%. The peak stress of the confined concrete decreased by 52.1% and its peak strain increased by 12.2 times, respectively. Moreover, the time-dependent seismic fragilities of the aging RC columns under different damage states exhibited a nonlinear increase as the service life increased.

The morphology, nanostructures, and crystallinity of hydroxyapatite (HA) materials have significant effects on their physicochemical properties and biomedical applications. However, the controllable synthesis of HA nanomaterials with various size and morphology using the same synthesis system, though desirable, has remained a challenge. In this work, we successfully synthesized HA nanomaterials with different morphologies via a one-step solvothermal route in the same reaction system. By using (NaPO₃)₃, Na₃PO₄·12H₂O and NaH₂PO₄·2H₂O as phosphorus sources, the growth of HA crystals was regulated, resulting in the transformation of HA nanomaterials morphology from nanorods to nanowires. Different concentrations of PO₄³⁻ and OH⁻ ions in the reaction environments regulated by different phosphates lead to different nanostructures of HA crystals. Our work provides an instructive way to controllably fabricate HA nanomaterials with various morphologies and will widen the biomedical applications of HA materials.

Well-defined carbonated hydroxyapatite microspheres assembled from nanosheets were synthesized by a Na₂EDTA-assisted hydrothermal homogeneous precipitation route.

Freeze–thaw damage is one of the primary causes deteriorating the seismic resistance of reinforced concrete (RC) structures. This paper proposed a freeze–thaw damage deterioration model for C30 concrete, and it can be employed to study the time-varying seismic performance of aging RC columns. Next, this study developed a seismic fragility analysis framework for deteriorating RC columns considering the effect of freeze–thaw damage. Considering the geometric parameters of the case-study bridge, the deterioration characteristics of material, and the uncertainties involved in structural modeling and ground motions, a probabilistic seismic fragility analysis on aging RC columns was conducted. The results indicate that the influence of freeze–thaw damage cannot be ignored in studying the seismic performance of aging RC structures. The seismic fragilities of deteriorating RC columns shown a nonlinear increase trend as the increased of freeze–thaw cycles and severity of the damage state. In the early stage of freeze–thaw cycles, the seismic fragilities of RC columns increased slowly. However, the closer to the later stage of freeze–thaw cycles, the more significant of the increase in the seismic fragilities of the columns.

High-speed railways are built in deep soft-soil foundations interlayered with hard materials. However, the hard layers cannot be penetrated by conventional foundation treatment. Moreover, the project cost is sometimes prohibitive, which is an issue for post-construction subsidence control. The bag grouting pile is a special grouting-pile-reinforcement technique for treating soft-soil foundations interlayered with hard materials. This paper conducted tests on the Ningbo-Taizhou-Wenzhou ballast track passenger railway, combining a conventional mixing-pile-foundation (not through hard layer) processing station and the bag-grouting-pile-processing subgrade line. Using field tests combined with numerical calculation, the lateral displacement, settlement and pile–soil stress were tested to obtain the working properties of the grouting-pile-composite foundation. The variation in the law of lateral displacement, settlement, and pile–soil stress of the foundation was studied. The results showed that the post-construction subsidence of bag-grouting-pile- and conventional mixing-pile-foundation control was less than 15 cm and 30 cm, respectively, which met the design requirements. The results also showed that the design scheme was reasonable (load-sharing ratio of bag-pile-foundation pile soil-based test was reasonable). The numerical calculation showed a change in pile diameter. It also showed that pile spacing could not improve subsidence-control properties, bag grouting pile can promote pore-pressure dissipation and accelerate consolidation, and pile spacing can be increased to cut project costs incurred by the pile-bearing capacity.