Right from the early days, polymer materials have been discovered as being beneficial for various applications but a poor understanding of these materials greatly handicapped their usage. However, with a change in this trend, polymer materials have gradually displaced other materials in most applications. In recent times, due to improved research and knowledge, polymer-based materials are the first choice materials for several applications and are now replacing other materials rapidly. More advanced materials from polymers are being developed daily as a substitute for other materials even in areas where polymers are considered not to be suitable in the time past. More recently, polymers have replaced metals and ceramics in applications like constructions, aerospace, automobiles, and medical. It is no doubt that this trend will continue due to the inherent properties of polymers and sustainability potential. Today, most of the limitations of polymers are being taken care of in the formulation of composite materials. Besides, the adaptation to positive environmental influence is being handled by scientists and researchers. Hence, this review reveals core areas of application of polymer-based composites and the significance of these materials to the advancement of humanity.

Hard tissue regeneration and regrowth have continued to be a challenge in the field of conventional medicine in this 21^st century. Over the years, the regrowth of broken bones and diseased hard tissue has remained a major concern in medical research. Since the discovery of hydroxyapatite (HA), a bioceramic compound that possesses the ability to activate bone regrowth and bond directly with regenerated bone, it has subsequently become an indispensable biomaterial. Currently, it is being used across the medical fields due to its exceptional biocompatibility. This became plausible because the main mineral phase of mammalian bones is HA. It has found application in various medical fields like medical instruments, drug delivery, bone and tooth fillers, prosthetics, orthotics, and in-vitro implants. As the importance of HA geometrically increases, it is necessary to critically evaluate and propose the most economic process of synthesizing and manufacturing this important bioceramic material. This review, therefore, highlights the different sources of HA and the synthesis/production methods for each source with a strong emphasis on the environment. Thus, the appraisal was carried out based on the properties of the derived HA. Such properties include but are not limited to geometry, particle size, morphology, thermal stability, and stoichiometry to suggest the most economic and environmentally sustainable sources and processing routes.

Scientists and tribologists are currently exploring sustainable and inexhaustible lubricants as a result of increased awareness of environmental and health-related issues. Vegetable oils are being investigated as a potential form of environmentally friendly cutting fluids due to their excellent renewability, biodegradability, and lubricating performance. This report provides an overview of different vegetable oils used as cutting fluids in the machining of engineering materials. The effects of virgin vegetable oils, emulsified vegetable-based oils, and vegetable-oil-based nano-cutting fluids on the cutting force, the surface finish of machined parts, the tool wear, and the temperature of the cutting area were surveyed critically. Compared to mineral-oil-based cutting fluids, studies have demonstrated that vegetable-oil-based cutting fluids meet cleaner manufacturing standards with good or better efficiency.

The additive manufacturing technique of material extrusion has challenge of excessive process defects and not achieving the desired mechanical properties. The industry is trying to develop certification to better control variations in mechanical attributes. The current study is a progress towards understanding the evolution of processing defects and the correlation of mechanical behavior with the process parameters. Modeling of the 3D printing process parameters such as layer thickness, printing speed, and printing temperature is carried out through L27 orthogonal array using Taguchi approach. In addition, CRITIC embedded WASPAS is adopted to optimize the parts' mechanical attributes and overcome the defects. Flexural and tensile poly-lactic acid specimens are printed according to ASTM standards D790 and D638, respectively, and thoroughly analyzed based on the surface morphological analysis to characterize defects. The parametric significance analysis is carried out to explore process science where the layer thickness, print speed, and temperature significantly control the quality and strength of the parts. Mathematical optimization results based on composite desirability show that layer thickness of 0.1 mm, printing speed of 60 mm/s, and printing temperature of 200 °C produce significantly desirable results. The validation experiments yielded the maximum flexural strength of 78.52 MPa, the maximum ultimate tensile strength of 45.52 MPa, and maximum impact strength of 6.21 kJ/m². It is established that multiple fused layers restricted the propagation of cracks with minimum thickness due to enhanced diffusion between the layers.

Stir casting is a common metallurgical route in the casting of aluminum composites. Series of work done in this aspect considered the development of the composites with fixed stir casting parameters without applying an optimization approach. These parameters affect the microstructure and performance of the composites. The study is focused on the optimization of the stir casting parameters in the production of Al 7075 reinforced with TiO₂ microparticles for performance improvement. Three stir casting parameters of stirring temperature, speed, and time were varied and optimized using the central composite design technique of the response surface method. Properties evaluated were ultimate tensile strength, hardness, impact strength, elastic modulus, and compressive strength. ANOVA results showed that the three stir casting parameters had a significant impact on the property responses. Five quadratic models were established for the properties linking them to the factors. The models were confirmed to be statistically significant at a confidence level of 95% and variations were observed to be < 5%. The interaction profile of the parameters as per response surface was analyzed. Contour plots associated with each interaction gave different ranges of stirring parameters in which each property can be maximized. Simultaneous optimization of the properties using Minitab 19 software showcased 779.3 °C, 574.2 rpm, and 22.5 min as the optimal stir casting parameters for temperature, speed and time respectively.

This work was on the comparative evaluation of the property effects obtainable when acetylation is applied to parts of selected agro fibers that are obtainable within common localities. The fibers were subjected to different concentrations of acetylation treatment at ambient temperature for 3 h. The physico-chemical, morphological, and tensile properties of the fibers were examined after the treatment. It was discovered from the results that the procedures variedly influenced the constituents of the fibers, their resulting tensile properties as well as their post-acetylation treatment surface morphology. The proportion of crystalline cellulose in the starting fibers greatly influenced their post treatment composition, behaviour and properties. The results show that plantain fibers had the highest aspect ratios, followed by banana fibers with values of about 1000 and 417, respectively. These fibers exhibited the least density and are thus potential plant fibers for composite development. Banana fiber had the least density of about 1.38 g/cm³ while that of DombeyaBuettneri fiber possessed the highest value of 1.5 g/cm³. There was significant enhancement in the hemicellulose content of Combretum Racemosum, while the lignin content of the plantain fibers was highly reduced. The treatment favoured the enhancement of the tensile properties in Combretum Racemosum fibers, which had enhanced tensile strength and strain at all compositions of the treatment. Optimum tensile strength and strain values of 155 MPa and 0.046, respectively, are achieved at 4% composition. Dombeya Buettneri fibers showed the highest ultimate tensile strength among the plant fibers in the untreated condition, which was gradually decreased as the concentration of the reagents was increased. Overall, 4% acetylation treatment is optimum for tensile properties’ enhancement for most of the natural fibers evaluated.