The aim of this study was to determine selected energy parameters, leachability of heavy metals and phytotoxicity of biomass ash for different types of plant biomass (wheat straw, miscanthus straw, bark and sawdust) and poultry manure, as well as biochars produced from them. Based on data from proximate and ultimate analysis of the investigated materials, fuel value index (FVI) was calculated to determine their suitability for energy production. The ashes were analyzed for both chemical composition and leaching behavior. The phytotoxicity test of aqueous ash extracts was performed for Lepidium sativum L. It was found that the calorific value of biochars was higher on average by 36% than the value determined for feedstocks used in the pyrolysis process. The pyrolysis of organic materials resulted in the reduction of the volatile matter content. The gross calorific value was determined in biochars formed from miscanthus straw and sawdust which were 26.6 and 23.4 MJ kg⁻¹, respectively. Leachability of heavy metals of biomass ash was highly diverse and depended on the analyzed element and the material type. The phytotoxicity analysis showed that, in general, each of the ash extracts tested had a positive effect on the growth of Lepidium sativum L. compared to the control. The use of ash, fertilizer, or sorbents can be an interesting alternative for materials with high ash content. In all these cases, biochars seem to be very attractive materials that can be used not only in energy production. Given the high carbon content of biochar obtained in the pyrolysis process, it has a high-energy potential and can be used as a biofuel.

Increasing production of waste has compelled the development of modern technologies for waste management. Certain fractions of municipal solid wastes are not suitable for recycling and must be utilised in other ways. Materials such as refuse-derived fuel (RDF) fractions are used as fuel in cement or CHP (combined heat and power) plants. The low bulk density leads to many problems pertaining to transportation and storage. In the case of biomass, these problems cause reduction in pelletisation. This paper therefore presents a comprehensive study on RDF pellet production, which is divided into three major areas. The first describes laboratory-scale tests and provides information on key factors that affect pellet quality (e.g., density and durability). Based on this, the second part presents a design of modified RDF dies to form RDF pellets, which are then tested via a semi-professional line test. The results show that RDF fraction can be compacted to form pellets using conventional devices. Given that temperature plays a key role, a special die must be used, and this ensures that the produced pellets exhibit high durability and bulk density, similar to biomass pellets.

The article discusses an innovative system used for aerobic biostabilisation and biological drying of solid municipal waste. A mechanical–biological process (MBT) of municipal solid waste (MSW) treatment were carried out and monitored in 5 bioreactors. A two-stage biological treatment process has been used in the investigation. In the first step an undersize fraction was subjected to the biological stabilisation for a period of 14 days as a result of which there was a decrease of loss on ignition, but not sufficient to fulfill the requirements of MBT technology. In the second stage of a biological treatment has been applied 7-days intensive bio-drying of MSW using sustained high temperatures in bioreactor. The article presents the results of the chemical composition analysis of the undersize fraction and waste after biological drying, and also the results of temperature changes, pH ratio, loss on ignition, moisture content, combustible and volatile matter content, heat of combustion and calorific value of wastes. The mass balance of the MBT of MSW with using the innovative aeration system showed that only 14.5% of waste need to be landfilled, 61.5% could be used for thermal treatment, and nearly 19% being lost in the process as CO₂ and H₂O.

Biogas production is an important component of sustainable energy management. In addition to energy-rich biogas, this process also generates solid waste in the form of digestate. The management of this stream has been problematic for many years. One promising method of utilizing this fraction seems to be incineration under controlled conditions. This paper presents an analysis of mixtures of different digestates to assess their suitability for incineration. Four digestates based on corn silage CS and apple pomace AP were used as test fuel. The ultimate and proximate analysis showed that this fuel deviates from the standards accepted for pure biomass, but was found in other fuels, especially those treated as waste. This materials can be a valuable source of energy, but combustion needs be undertaken in special units. Moisture content of investigated digestate-type ranges from 11.9–12.2% and ash content ranges from 8.2% to 11.6%. This could lead to ash sintering and slugging problems, which are problematic, especially because it is not designed for such types of fuel boilers. The study showed correlations between the elemental composition and the course of basic combustion processes. The ultimate analysis of all mixtures shows that the shares of major elements looks similar. These results are connected with the thermogravimetric analysis TGA, which shows similar thermal decomposition for all four mixtures. It is valuable information because, in this special case, when we have mixtures of corn silage and apple pomace originated digestates, the changes in the ratio CS:AP will not affect combustion significantly.