Electrochromic titanium dioxide (TiO2) nanostructured films were grown on gold coated papers using a microwave-assisted hydrothermal method at low temperature (80 °C). Uniform nanostructured films fully covered the paper substrate, while maintaining its flexibility. Three acids, i.e., acetic, hydrochloric and nitric acids, were tested during syntheses, which determined the final structure of the produced films, and consequently their electrochromic behavior. The structural characteristics of nanostructured films were correlated with electrochemical response and reflectance modulation when immersed in 1 M LiClO4-PC (lithium perchlorate with propylene carbonate) electrolyte, nevertheless the material synthesized with nitric acid resulted in highly porous anatase films with enhanced electrochromic performance. The TiO2 films revealed a notable contrast behavior, reaching for the nitric-based film optical modulations of 57%, 9% and 22% between colored and bleached states, at 250, 550 and 850 nm, respectively in reflectance mode. High cycling stability was also obtained performing up to 1500 cycles without significant loss of the electrochromic behavior for the nitric acid material. The approach developed in this work proves the high stability and durability of such devices, together with the use of paper as substrate that aggregates the environmentally friendly, lightweight, flexibility and recyclability characters of the substrate to the microwave synthesis features, i.e., simplicity, celerity and enhanced efficiency/cost balance.
Environmental factors, such as pressure and temperature, are known to contribute to the formation of ulcers that seriously affect bedridden individuals. Researchers have proposed several technologies to achieve the long-term monitoring of those parameters, usually relying on sensing mats, which poses difficulties in correlating the measurements with specific parts of the body. In this work, we aim to develop microsensors to be integrated into patient clothing. They should be highly flexible, thin with a small footprint, and can be achieved by taking advantage of the microfabrication on polyimide (PI) thin-film substrates (total device thicknesses below 30 µm). Both resistive and capacitance transduction mechanisms were explored, targeting operation ranges of 1 to 40 kPa and 24 to 42 °C. The sensors were integrated into textiles using silicone elastomers and electrical connections based on conductive silver yarn. The experimental characterization showed a nominal capacitance of 21 pF, a sensitivity of −8.44 fF/kPa for the pressure sensors, and a 0.0021 Ω/Ω°C sensitivity of the temperature sensor (with resistance of 29 kΩ at 22 °C). The proposed approach can potentially be implemented not only in wearable devices but also in many other applications for health monitoring or human–machine interfaces.
A silicon mechanical-photonic wavelength converter, not based on absorption, has been recently proposed to address the need for all-silicon photodetectors in the infrared spectrum. Its implementation requires high-frequency modulation, from hundreds of kHz to 1 MHz, of a light beam over an area of a few hundred microns. Since the displacement amplitudes of tens of microns at these frequencies are unfeasible, a moving grate is proposed to locally modulate the light. The MEMS actuator, an array of 1 µm-wide 1 µm-spaced beams (100 × 100 µm2 area), achieved displacements of 70 nm at atmospheric pressure and 350 nm under low vacuum, with 10 Vpp actuation at 290 kHz (FOM displacement × frequency2 above previously reported works).