Very thin Au layers were deposited on SiC hexagonal and $\mathrm{Si}{\mathrm{O}}_2$ substrates by sputtering. The Au surface diffusion, clustering, and self-organization of Au nanoclusters on these substrates, induced by thermal processes, were investigated by Rutherford backscattering spectrometry, atomic force microscopy, scanning electron microscopy, and transmission electron microscopy. On both types of substrates, clustering is shown to be a ripening process of three-dimensional structures controlled by surface diffusion and the application of the ripening theory allowed us to derive the surface diffusion coefficient and all other parameters necessary to describe the entire process. The system Au nanoclusters/SiC and Au nanoclusters/$\mathrm{Si}{\mathrm{O}}_2$ are proposed as nanostructured materials for nanoelectronic and nanotechnology applications.

The authors experimentally demonstrate strong light confinement and enhancement of emission at $1.54\mu \mathrm{m}$ in planar silicon-on-insulator waveguides containing a thin layer (slot) of $\mathrm{Si}{\mathrm{O}}_2$ with ${\mathrm{Er}}^{3+}$ doped Si nanoclusters. Angle-resolved attenuated total reflectance is used to excite the slab guided modes, giving a direct evidence of the strong confinement of the electric field in the low-index active material for the fundamental transverse-magnetic mode. By measuring the guided photoluminescence from the cleaved-edge of the sample, the authors observe a more than fivefold enhancement of emission for the transverse-magnetic mode over the transverse-electric one. These results show that Si-based slot waveguides could be important as starting templates for the realization of Si-compatible active optical devices.

Very thin Au layer was deposited on Si(100) using the sputtering technique. By annealing at 873 K Au/Si nanodroplets were formed and their self-organization was induced changing the annealing time. The evolution of droplet size distribution, center-to-center distance distribution, and droplet density as a function of the annealing time at 873 K was investigated by Rutherford backscattering spectrometry, atomic force microscopy (AFM), and scanning electron microscopy. As a consequence of such study, the droplet clustering is shown to be a ripening process of hemispherical three-dimensional structures limited by the Au surface diffusion. The application of the ripening theory allowed us to calculate the surface diffusion coefficient and all other parameters needed to describe the entire process. Furthermore, the AFM measurements allowed us to study the roughness evolution of the sputtered Au thin film and compare the experimental data with the dynamic scaling theories of growing interfaces.

Heteroepitaxial cubic silicon carbide (3C-SiC) is an extremely promising material for micro- and nano-electromechanical systems due to its large Young’s modulus. Unfortunately, the heteroepitaxy of 3C-SiC on Si substrate is affected by the high mismatch in the lattice parameters and the thermal expansion coefficients between the two dissimilar materials that generate a high number of defects in the material. In this work, through the measurement of natural resonant frequencies and Raman shift analysis, a strong relationship between the mechanical proprieties of the material (Young’s modulus) and the film crystal quality (defect density) was observed.

The degradation trend of photovoltaic modules depends on the technology, manufacturing techniques and climatic conditions of the site where they are installed. Longer useful life of the PV modules means that they will be able to produce much more energy than was used to build them; thus, extending the useful life of the modules is beneficial for the environment and increases the cost effectiveness of PVs. The problem of land use has prompted the development of agrivoltaic systems to exploit the same land both for the production of energy and for agriculture, and on water surfaces such as lakes and dams (floating PV). The exploitation of floating PV systems in onshore and offshore areas is currently under study. This constitutes an opportunity for which many factors must be taken into account; a fundamental aspect is the environmental impact, on which some recent studies have focused. Another aspect is the impact of the marine environment on PV system reliability and durability, due to the stress on operating conditions. The aim of this preliminary study is to evaluate the influence of the marine environment on the degradation trend of photovoltaic modules, based on existing models whose inputs are meteorological data from offshore locations. The results obtained from the application of a cumulative exposure model unexpectedly showed a lower degradation value in the offshore environment than on the mainland: −0.95% and −3% values of power decay, respectively. The absolute value of power decay in the onshore case is higher than the typical values because the used model has to be revised, as the empirical coefficients of the model have to be calculated according to the installation environment. The empirical coefficients used in the model were obtained in environmental conditions different from those under study. In the offshore case, the degradation estimated by the model does not take into account some environmental factors typical of the marine environment. Model adaptations calibrated with datasets of plants in environmental conditions similar to those analyzed would allow for greater accuracy in the results.