Proton Exchange Membrane Fuel Cell (PEMFC) fuel cells is a technology successfully used in the production of energy from hydrogen, allowing the use of hydrogen as an energy vector. It is scalable for stationary and mobile applications. However, the technology demands more research. An important research topic is fault diagnosis and condition monitoring to improve the life and the efficiency and to reduce the operation costs of PEMFC devices. Consequently, there is a need of physical models that allow deep analysis. These models must be accurate enough to represent the PEMFC behavior and to allow the identification of different internal signals of a PEM fuel cell. This work presents a PEM fuel cell model that uses the output temperature in a closed loop, so it can represent the thermal and the electrical behavior. The model is used to represent a Nexa Ballard 1.2 kW fuel cell; therefore, it is necessary to fit the coefficients to represent the real behavior. Five optimization algorithms were tested to fit the model, three of them taken from literature and two proposed in this work. Finally, the model with the identified parameters was validated with real data.
Applications of renewable electricity in cities are mostly limited to photovoltaics, and they need other renewable sources, batteries, and the grid to guarantee reliability. This paper proposes a hybrid system, combining biomass and photovoltaics, to supply electricity to educational buildings. This system is reliable and provides at least 50% of electricity based on renewable sources. Buildings with small (70%) implies high electricity costs.
21 May 2025 in International Journal of Hydrogen Energy
In this work, we report the preparation of Nafion membranes containing two different nanocomposite MF-4SC membranes, modified with polyaniline (PANI) by the casting method through two different polyaniline infiltration procedures. These membranes were evaluated as a polymer electrolyte membrane for water electrolysis. Operating conditions were optimized in terms of current density, stability, and methanol concentration. A study was made on the effects on the cell performance of various parameters, such as methanol concentration, water, and cell voltage. The energy required for pure water electrolysis was analyzed at different temperatures for the different membranes. Our experiments showed that PEM electrolyzers provide hydrogen production of 30 mL/min, working at 160 mA/cm2. Our composite PANI membranes showed an improved behavior over pristine perfluorinated sulfocationic membranes (around 20% reduction in specific energy). Methanol–water electrolysis required considerably less (around 65%) electrical power than water electrolysis. The results provided the main characteristics of aqueous methanol electrolysis, in which the power consumption is 2.34 kW h/kg of hydrogen at current densities higher than 0.5 A/cm2. This value is ~20-fold times lower than the electrical energy required to produce 1 kg of hydrogen by water electrolysis.
15 October 2018 in Proceedings of the Institution of Mechanical Engineers, Part H: Journal of Engineering in Medicine
Using enteroscopes with therapeutic capacity to explore the small intestine entails certain limitations, including long exploration times, patient discomfort, the need for sedation, a high percentage of incomplete explorations and a long learning curve. This article describes the advances and setbacks encountered in designing the new Endoworm enteroscopy system, a semi-autonomous device consisting of a control unit and three cavities that inflate and deflate in such a way that the bowel retracts over the endoscope. The system can be adapted to any commercial enteroscope. Endoworm was tested in different intestine models: a polymethyl methacrylate rigid tube, an in vitro polyester urethane model, an ex vivo pig model and an in vivo animal model. The general behavior of the prototype was evaluated by experienced medical personnel. The mean distance covered through the lumen was measured in each cycle. The system was found to have excellent performance in the rigid tube and in the in vitro model. The ex vivo tests showed that the behavior depended largely on the mechanical properties of the lumen, while the in vivo experiments suggest that the device will require further modifications to improve its performance.
A study of energy supply alternatives was carried out based on a cogeneration fuel cell system fed from the natural gas network of compact Mediterranean cities. As a case study it was applied to the residential energy demands of the L’Illa Perduda neighbourhood, located in the east of the city of Valencia and consisting of 4194 residential cells. In total, eight different alternatives were studied according to the load curve, the power of the system, the mode of operation and the distribution of the fuel cells. In this way, the advantages and disadvantages of each configuration were found. This information, together with the previous study of the energy characteristics of the neighbourhood, enabled selection of the most promising configuration and to decide whether or not to recommend investment. The chosen configuration was a centralised system of phosphoric acid fuel cells in cogeneration, with approximately 4 MW of thermal power and an operating mode that varied according to the outside temperature. In this way, when heating is required, the plant adjusts its production to the thermal demand, and when cooling is required, the plant follows the electrical demand. This configuration presented the best energy results, as it achieved good coverage of thermal (62.5%) and electrical (88.1%) demands with good primary energy savings (28.36 GWh/year). However, due to the high power of the system and low maturity (i.e., high costs) of this technology, would be necessary to make a large initial economic investment of 15.2 M€.