Copper (Cu)-based composite coatings have been widely applied in all kinds of important industry fields due to their outstanding comprehensive properties. The preparation temperature of a composite coating is the key factor affecting the properties, so the cold spray (CS) technology is characterized by low-temperature solid-state deposition, which ensures its emergence as the most promising technology for preparing the Cu-based composite coatings. In this paper, first, the principle of CS technology and the deposition mechanism of the coatings are introduced. On this basis, the deposition mechanism of Cu-based metal/ceramic composite coatings is further explored. Secondly, the effects of key CS process parameters (particle velocity, particle morphology, and substrate state) on the quality of the Cu-based composite coatings are summarized, and the current research status of cold-sprayed Cu-based composite coatings in the fields of corrosion resistance, wear resistance, self-lubricating properties, and electrical conductivity is reviewed. Moreover, the improvement of the performance of Cu-based composite coatings by various post-process treatments of coatings, such as heat treatment (HT) and friction stir processing (FSP), is elaborated. Finally, the future development of Cu-based composite coatings and CS technology is prospected.
1 January 2014 in Journal of Central South University
CoCrFeNiTiAl high-entropy alloy coatings have been prepared by laser cladding technology based on response surface methodology (RSM). The results show that the effects of laser power, cladding speed, and pulse width on the dilution rate and microhardness of the high-entropy alloy coatings are investigated. Among the single-factor results, the laser power has the most significant effect on the properties of high-entropy alloy coatings, followed by the cladding speed, while the pulse width has no significant effect. In the interaction term analysis, the interaction term of laser power and pulse width has a remarkable effect on both output responses, whereas the interaction term of pulse width and cladding speed only has a considerable effect on microhardness, while the interaction term of laser power and cladding speed has an insignificant effect on both output responses. The optimum parameters for the preparation of high-performance high-entropy alloy coatings are found at laser power P = 676.73 W, cladding speed V = 5 mm/s, and pulse width P0 = 9 ms. The microstructures of the high-entropy alloy coating prepared with optimal process parameters have been characterized, which show that the metallurgical bonding between the cladding layer and the substrate is strong and without obvious defects such as porosity and cracks.
Metal magnetic memory testing (MMMT) is an effective nondestructive technique for fatigue damage monitoring of weldments because of its capacity for stress evaluation. An experimental investigation of the effect of the applied fatigue stress on MMMT signals, including the tangential component Bx and the normal component Bz, during tension–compression fatigue tests in welded joints was carried out systematically. The Bx and Bz signals at different fatigue cycles and fatigue stresses were collected and analyzed, and the results showed that there was a peak of Bx and abnormal peaks of Bz that existed at the welded joint before loading. After loading, the peak of Bx and the abnormal peaks of Bz reversed, and the Bx signals moved upward and the Bz signals rotated anticlockwise dramatically in the first few fatigue cycles. After the fatigue cycle number was larger than 1000, Bx and Bz were stable, with very little fluctuation. In addition, the characteristics of Bx signals, the mean value, and the peak value of the average of Bx had an extremely significant linear relationship with the applied fatigue stress during the stable stage of the fatigue test, which indicates that MMMT is a feasible method for fatigue stress evaluation and even residual fatigue life estimation for weldments in service.
To investigate atomic oxygen effects on tribological properties of Mo/MoS2-Pb-PbS film and further enlarge application range, atomic oxygen exposure tests were carried out for 5 h, 10 h, 15 h, and 20 h by the atomic oxygen simulator with atomic oxygen flux of 2.5 × 1015 atoms/cm2·s. The exposure time in test was equivalent to the atomic oxygen cumulative flux for 159.25 h, 318.5 h, 477.75 h, and 637 h at the height of 400 km in space. Then, the vacuum friction test of Mo/MoS2-Pb-PbS thin film was performed under the 6 N load and 100 r/min. By SEM, TEM, and XPS analysis of the surface of the film after atomic oxygen erosion, it was observed that atomic oxygen could cause serious oxidation on the surface of Mo/MoS2-Pb-PbS film, and the contents of MoS2, PbS, and Pb, which were lubricating components, were significantly reduced, and oxides were generated. From AES analysis and the variation in the main element content, Mo/MoS2-Pb-PbS thin film showed self-protection ability in an atomic oxygen environment. Hard oxide generated after atomic oxygen erosion such as MoO3 and Pb3O4 could cause the friction coefficient slight fluctuations, but the average friction coefficient was in a stable state.
15 May 2024 in Journal of Thermal Spray Technology