In this paper, we report on total electron tetrahydrofuran scattering cross-section measurements for energies in the range from 50 to 5000 eV with experimental errors of about 5%. In addition, integral elastic and inelastic cross sections have been calculated over a broad energy range , with an optical potential method assuming a screening-corrected independent atom representation. Partial and total ionization cross sections have been also obtained by combining simultaneous electron and ion measurements with a time-of-flight analysis of the ionic induced fragmentation. Finally, an average energy distribution of secondary electrons has been derived from these measurements in order to provide data for modeling electron-induced damage in biomolecular systems.
Total electron- scattering cross sections have been measured from 50 to with experimental errors of about 5%. Integral elastic and inelastic cross sections have been calculated over a broad energy range with an optical potential method assuming an independent atom representation. Dipole rotational excitations have also been included in the framework of the first Born approximation. From a detailed evaluation of the present results and their comparison with previous theoretical and experimental data, a set of recommended integral cross sectional data is provided. By combining these data with an average excitation energy derived from the experimental energy loss spectra, the stopping power of electrons in has been obtained from 5 to .
In this paper, an apparatus for measuring electron-scattering cross sections while applying a strong axial magnetic field is described. The first original experiment performed with this setup is the measurement of the total cross sections for pyrimidine (1,3-diazine), which are presented for the incident electron energy range of 8–500 eV. Generally good agreement with earlier theoretical predictions is found after accounting for the angular acceptance (angular resolution for forward scattering) of the apparatus.
A novel experimental setup has been implemented to provide accurate electron scattering cross sections from molecules at low and intermediate impact energies (1-300 eV) by measuring the attenuation of a magnetically confined linear electron beam from a molecular target. High-resolution electron energy is achieved through confinement in a magnetic gas trap where electrons are cooled by successive collisions with N2. Additionally, we developed and present a method to correct systematic errors arising from energy and angular resolution limitations. The accuracy of the entire measurement procedure is validated by comparing the N2 total scattering cross section in the considered energy range with benchmark values available in the literature.
13 August 2018 in Physical Chemistry Chemical Physics
Total electron scattering cross sections, from para-benzoquinone, for impact energies ranging between 1 to 200 eV, have been obtained by measuring the attenuation of a linear electron beam under magnetic confinement conditions. Random uncertainty limits on these values have been found to be within 5%. Systematic errors, due to the axial magnetic beam conditions in combination with the acceptance angle of the detector, have been evaluated by integrating our calculated independent atom model with the screening corrected additivity rule and interference term elastic differential cross sections over that detection acceptance angle. Our previous calculations and measurements on this molecule (Jones et al., J. Chem. Phys., 2018, 148, 124312 and J. Chem. Phys., 2018, 148, 204305), have been compiled and complemented with new elastic and inelastic scattering cross section calculations in order to obtain a comprehensive cross section data base, within the considered energy range, for modelling purposes. The self-consistency of the present data set has been evaluated by simulating the electron transport of 15 eV electrons in para-benzoquinone, and comparing those results with the observed transmitted intensity distribution.