In this article, the fabrication, characterization, tribological performance, and micromechanical properties of nanostructured smart coatings (NSC) based on the multilayered alternating carbonitride/nitride bilayer {TiMe-CN/TiAlSi-N}n system are discussed. The symbol “Me” denotes refractory metals Hf or Nb, and the index “n” shows the number of superlattice periods. The NSC samples were deposited onto bearing steel (100Cr6) substrates using a reactive high-power physical vapor deposition (PVD) technique that can be scaled up for industrial use. The deposited multilayered NSC contained crystalline nanometer-scale TiMe-CN/TiAlSi-N nanoparticles strengthened by Hf or Nb additives, which increased surface microhardness up to 3000 HV. The measured steady-state friction coefficient (CoF) was within the 0.2–0.4 range, and a specific wear rate lower than 2 × 10⁻⁶ mm³/Nm was observed in the dry friction regime. The impact of NSC substrate hardness and NSC coating thickness on microhardness measurement values was investigated. A thicker coating provided a higher integrated (coating + substrate) microhardness value at a lower indentation test force (<0.3 N). As the indentation test force increased, the obtained microhardness values decreased faster for the coatings deposited on a softer substrate. The surface roughness impact on wear properties for specific NSC coatings was observed.

This article discusses the micromechanical properties and true microhardness determination of nanostructured tribological coatings (NTCs) based on a multilayered alternating nitride/carbonitride bilayer substructure for transition metals. The constituent nitride/carbonitride bilayers in the superlattice structure of the NTC were alloyed with refractory metals, denoted as Me = Me₁ or Me₂= Cr, Hf, Nb, W, and Zr. The resulting NTC coatings were deposited onto 100Cr6 steel substrates using an advanced physical vapor deposition (PVD) technique, referred to here as high-power ion-plasma magnetron sputtering (HiPIPMS). The comprising crystalline nanometer-scale TiAlSiMe₁-N/TiMe₂-CN nanoparticles strengthened by Me additives significantly increased the NTC microhardness to over 3200 HV. The primary focus of this research was to determine the true microhardness of the NTC film samples. The apparent microhardness (H_a) of the film/substrate system for various NTC samples was measured during microindentation testing using the Vickers method. Nine NTC samples were tested, each generating a corresponding microindentation dataset containing between 430 and 640 imprints, depending on the specific NTC sample. These datasets were analyzed using three distinct empirical approaches: (i) the inverse power-law model (IPL-Model), (ii) the sigmoid-like decay model (SLD-Model), and (iii) the error function model (ERF-Model). The observed solid correlation between the proposed models and experiments suggests that the true microhardness estimates (H_f) obtained through the empirical mathematical modeling approach are reliable.

This study investigates the nanomechanical and tribological behavior of multilayered nitride/carbonitride nanostructured superlattice type coatings (NTCs) composed of alternating TiAlSiNb-N and TiCr-CN sublayers, deposited via high-power ion-plasma magnetron sputtering (HiPIPMS) technique. Reinforced with refractory elements Cr and Nb, the NTC samples exhibit high nanohardness (39–59 GPa), low friction, and excellent wear resistance. A novel analytical approach was introduced to extract stress–strain field (SSF) gradients and divergences from nanoindentation data, revealing alternating strain-hardening and strain-softening cycles beneath the incrementally loaded indenter. The discovered oscillatory behavior, consistent across all samples under the investigation, suggests a general deformation mechanism in thin films under incremental loading. Fourier analysis of the SSF gradient oscillatory pattern revealed a variety of characteristic dominant wavelengths within the length-scale interval (0.84–8.10) nm, indicating multi-scale nanomechanical responses. Additionally, the NTC samples display an anisotropic coating morphology exhibited as unidirectional undulating surface roughness waves, potentially attributed to atomic shadowing, strain-induced instabilities, and limited adatom diffusion. These findings deepen our understanding of nanoscale deformation in advanced PVD coatings and underscore the utility of SSF analysis for probing thin-film mechanics.

This study investigates the fabrication, nanomechanical behavior, and tribological performance of nanostructured superlattice coatings (NSCs) composed of alternating TiAlSiNb-N/TiCr-CN bilayers. Deposited via High-Power Ion-Plasma Magnetron Sputtering (HiPIPMS) onto 100Cr6 steel substrates, the coatings achieved nanohardness values of ~25 GPa and elastic moduli up to ~415 GPa. A novel empirical method was applied to extract stress–strain field (SSF) gradient and divergence profiles from nanoindentation load–displacement data. These profiles revealed complex, depth-dependent oscillations attributed to alternating strain-hardening and strain-softening mechanisms. Fourier analysis identified dominant spatial wavelengths, DWL, ranging from 4.3 to 42.7 nm. Characteristic wavelengths WL1 and WL2, representing fine and coarse oscillatory modes, were 8.2–9.2 nm and 16.8–22.1 nm, respectively, aligning with the superlattice period and grain-scale features. The hyperfine structure exhibited non-stationary behavior, with dominant wavelengths decreasing from ~5 nm to ~1.5 nm as the indentation depth increased. We attribute the SSF gradient and divergence spatial oscillations to alternating strain-hardening and strain-softening deformation mechanisms within the near-surface layer during progressive loading. This cyclic hardening–softening behavior was consistently observed across all NSC samples, suggesting it represents a general phenomenon in thin film/substrate systems under incremental nanoindentation loading. The proposed SSF gradient–divergence framework enhances nanoindentation analytical capabilities, offering a tool for characterizing thin-film coatings and guiding advanced tribological material design.