The production of novel materials and value-added chemicals from lignin has received considerable attention in recent years. Due to its abundant occurrence in nature, there is a growing interest in utilizing lignin as a feedstock for functional materials production, for example aerogels. Much like in the synthesis of phenol-based resins, the vacant ortho positions of the aromatic rings in lignin can crosslink with formaldehyde and form polymeric gels. After drying the hydrogels with supercritical CO2, highly porous aerogels are obtained. Current study focuses on the preparation and thorough parametrization of organosolv lignins from different types of lignocellulosic biomass (aspen, pine, and barley straw) as well as their utilization for the preparation of lignin-5-methylresorcinol-formaldehyde aerogels. The thorough structural characterization of the obtained aerogels was carried out by gas adsorption, IR spectroscopy, and scanning electron microscopy. The obtained lignin-based monolithic mesoporous aerogels had specific surface areas and total pore volumes in the upward ranges of 450 m2/g and 1.4 cm3/g, respectively.
31 December 2014 in International Journal of Architectural Heritage
This article analyzes the indoor climate that creates risk of damages in naturally ventilated churches in the cold climate of Estonia. Indoor temperature and humidity were measured over a one-year period and the results were analyzed on the basis of damage functions: mold growth, risk of cracking and fracturing of wooden objects, and delamination of the gesso layer of panel paintings. In unheated churches, one of the most dominant problems was very high relative humidity throughout the year, creating a high risk for mold and algae growth. Churches may need background heating to avoid freezing during a long cold winter that causes low surface temperatures of massive walls during the spring–summer period. It was found that mold risk was significantly lower in heated churches than in unheated or intermittently heated churches. The risk of mold growth was not decreased by the use of intermittent heating. In heated churches, overheating (room temperature >+10ºC) causes a RH below 50% during cold periods, and the favorable period for irreversible response of panel paintings was significantly longer, so there is a higher risk that the gesso may crack or delaminate. From the point of view of the cracking and fracturing of wood, indoor climate conditions are in the safe range for most of the year.
28 April 2016 in Journal of Thermal Analysis and Calorimetry
Article A Comparative Investigation of the Ultrastructure of Steam Exploded Wood With Light, Scanning and Transmission Electron Microscopy was published on January 1, 1995 in the journal Holzforschung (volume 49, issue 2).