The purpose of the presented study was to explore the photocatalytic activity of Cu₂O-supported anion exchangers and to explain the mechanism of their action in water purification processes. The functionality of this type of material was studied in the process of As(III) removal from water. As a result of the reactivity of cuprous oxide and functional groups of the polymer, the obtained composite exhibited complex activity towards arsenic(III) species. The adsorption studies were conducted under various conditions: dark, UV-VIS irradiation, VIS irradiation, under aerobic and anoxic conditions. The results from chemical analyses were supported by instrumental analyses - X-ray photoelectron spectroscopy, and FTIR and Raman spectroscopy. These studies showed that the mechanism of As(III) oxidative adsorption is based on the coupling of several reaction pathways: 1) photocatalytic oxidation involving Cu₂O as a photocatalyst, and photogenerated holes and ROS as oxidative agents, 2) chemical oxidation on the surface of CuO (being a result of the ageing process) with a re-oxidation of the produced Cu₂O to CuO by ROS and oxygen present in water, and 3) photochemical oxidation of As(III) in solution under UV light irradiation and subsequent adsorption of arsenates in the functional groups of the polymer.

A major challenge in materials engineering is the development of new materials and methods and/or novel combination of existing ones, all fostering innovation. For that reason, this study aims at the synergy between low-pressure cold spray (LPCS) as a tool for coating deposition and sol-gel technique for fabrication of the feedstock powder. The complementarity of both methods is important for the examined topic. On one side, the LPCS being automized and quick mean provides the solid-state of feedstock material in nondestructive conditions and hence the hydrophobicity imparted on the sol-gel route is preserved. On the other side, the sol-gel synthesis enables the production of oxide materials with enhanced deformability due to amorphous form which supports the anchoring while LPCS spraying. In the paper, several aspects including optimal fluoroalkylsilane (FOTS) concentration or substrate roughness are examined initially for altering the superhydrophobicity of produced coatings. Further, it is shown that the appropriate optimization of feedstock powder, being submicron silica matrices covered with two-layer FOTS sheath, may facilitate the anchoring process, support roughening the substrate or cause enhancement the coating hydrophobicity. All the discussion is supported by the characteristics including surface morphology, wettability and thermal behaviour examined by electron microscopy, water contact angle measurements and thermal analysis (TGA/DSC), respectively. The coatings presented in the paper are characterized by an uneven thickness of up to a few silica particles, but final hydrophobicity is provided uniformly on the surface by the formation of multi-level roughness by a detachment of outer layer from the SiO₂ particles. Thus, the presented approach constitutes a simple and fast solution for the fabrication of functionalized coatings using LPCS including industrial potential and fundamental research character.

This work shows that the titanium dioxide coatings obtained by low-pressure cold gas spraying with the use of the sol–gel amorphous TiO₂ powder are characterized by photocatalytic activity despite their partial amorphous content. Moreover, the research outcome suggests that the decomposition rate of organic pollutants is enhanced after long-term exposure to moisture. The condensation humidity test is not detrimental to the continuity and integrity of the coating, but the phase composition of coatings changes—with the exposure to water vapor, the portion of the amorphous phase crystallizes into brookite. The mechanism responsible for the conversion of amorphous TiO₂ into brookite is attributed to the water-driven dissolution and reprecipitation of TiO₆ octahedra. It has been shown that an additional parameter necessary for the stabilization of the brookite is the oxygen depletion of the amorphous structure of titanium dioxide. Considering the results presented in this paper and the advantages of a portable, low-pressure cold spray system for industrial applications, it is expected that TiO₂ coatings produced from a sol–gel feedstock powder can be further developed and tested as efficient photocatalysts.

Visible-light active photocatalysts in the form of coatings that can be produced using large-scale methods have attracted considerable attention. Here we show a facile approach to deposit coatings using the low pressure cold spray (LPCS) from oxygen-rich amorphous titanium dioxide, which is a structurally-unconventional feedstock powder for LPCS. We synthesized amorphous TiO₂, in which we introduced numerous defects, such as oxide groups (peroxy and superoxy) in volume and hydroxyl groups on the surface. Then we deposited as-prepared powder preserving the presence of active groups, which we demonstrated using Raman spectroscopy. To show the activity of the prepared coatings, we perform methylene blue degradation under visible light. Our research shows that it is worth considering the internal atomic structure and surface chemistry of the powders to be preserved after low pressure cold spraying.