The purpose of the presented study was to explore the photocatalytic activity of Cu₂O-supported anion exchangers and to explain the mechanism of their action in water purification processes. The functionality of this type of material was studied in the process of As(III) removal from water. As a result of the reactivity of cuprous oxide and functional groups of the polymer, the obtained composite exhibited complex activity towards arsenic(III) species. The adsorption studies were conducted under various conditions: dark, UV-VIS irradiation, VIS irradiation, under aerobic and anoxic conditions. The results from chemical analyses were supported by instrumental analyses - X-ray photoelectron spectroscopy, and FTIR and Raman spectroscopy. These studies showed that the mechanism of As(III) oxidative adsorption is based on the coupling of several reaction pathways: 1) photocatalytic oxidation involving Cu₂O as a photocatalyst, and photogenerated holes and ROS as oxidative agents, 2) chemical oxidation on the surface of CuO (being a result of the ageing process) with a re-oxidation of the produced Cu₂O to CuO by ROS and oxygen present in water, and 3) photochemical oxidation of As(III) in solution under UV light irradiation and subsequent adsorption of arsenates in the functional groups of the polymer.

In this paper, the methodology for design of the system consisting of chromatic confocal displacement sensor integrated with an optical laser head was presented. Furthermore, the results of experimental characterization of optical components of the laser head were also included in the numerical analysis. The designed chromatic confocal displacement sensor was analyzed as an assembly of components widely available on the optical market. Nevertheless, the main goal of the numerical optimization was to determine the influence of individual components of the optical path of the system on its parameters, i.e., measuring range, FWHM of the characteristic spectral peak, and intensity that reaches the detector. The optimized solution was characterized in order to determine the calibration curve, as well as other important application parameters of the system. Moreover, taking into consideration the integration aspect the caustic of the laser beam shaped by the laser head was measured. Finally, the versatility of the system was presented and discussed.

This paper presents an analysis of thermal oxidation kinetics for Aluminium nitride (AlN) epitaxy layers using three methods: dry, wet and mixed. The structures thus obtained were examined by means of scanning electron microscope, energy-dispersive X-ray spectroscopy, spectroscopic ellipsometry and secondary ions mass spectroscopy. On the basis of the investigation results, a model of layer structure after oxidation was proposed, the thickness of the layers was assessed and the refractive indices for particular layers were determined. The modelling results prove that AlN thermal oxidation in dry oxygen follows the logarithmic law, wet oxidation follows the parabolic law, whereas mixed oxidation follows the linear law.

In this paper, the results of experimental characterization of an optical system consisting of a chromatic confocal displacement sensor integrated with an optical laser head are presented. As a result of integration, the part of the optical path of the displacement sensor was combined with the optical path of the laser beam. Consequently, a working distance of 250 mm for the optical system was achieved. The main aim of the characterization was to determine the calibration curve, as well as the application parameters of the system. The methodology for spectral data processing with particular emphasis on the effectiveness of various extraction algorithms is presented. The Lorentzian fitting was considered as the optimal algorithm for the optical system. Consequently, a large measuring range of 10 mm was obtained with perfect linear tendency of the calibration curve. The optical system was characterized by high accuracy equal to ± 0.11 % of the measuring range, as well as 1 µm resolution. Moreover, the functionality of the system was verified on materials commonly used in laser processing and additive manufacturing. Finally, the system was validated through a comparative measurement with a laser profiler.

Three methods of AlN layers oxidation: dry, wet and mixed (wet with oxygen) were compared. Some physical parameters of oxidized thin films of aluminum nitride (AlN) layers grown on silicon Si(1 1 1) were investigated by means Energy-Dispersive X-ray Spectroscopy (EDS) and Spectroscopic Ellipsometry (SE). Three series of the thermal oxidations processes were carried out at 1012 °C in pure nitrogen as carrying gas and various gas ambients: (a) dry oxidation with oxygen, (b) wet oxidation with water steam and (c) mixed atmosphere with various process times. All the research methods have shown that along with the rising of the oxidation time, AlN layer across the aluminum oxide nitride transforms to aluminum oxide. The mixed oxidation was a faster method than the dry or wet ones.