A kinetic model has been developed to simulate reversible gas adsorption in coated wall flow tube reactors (CWFTs). The motivation of this work is to provide the theoretical framework for modelling studies in support of the results obtained from CWFT studies on the adsorption and desorption behaviour of atmospheric trace gases on ice surfaces at temperatures relevant to the upper troposphere/lower stratosphere (190–230 K). The model consists of an axial sequence of individual flow tube sections of equal volumes in which the gas phase is homogeneously mixed and interactions with the coated wall occur by adsoption and desorption exclusively. The adsorption rate is assumed to be kinetically controlled and not to be transport limited. Moreover, chemical reactions are not considered. Simulations have been performed for the temporal behaviour of the gas phase concentration at the exit of the flow tube as a function of laboratory time for typical operation procedures of CWFTs with moveable injectors i.e. (i) instantaneous injection of the gas, (ii) instantaneous termination of the gas flow and (iii) movements of the injector with constant velocities. It is found that the temporal profiles show complex behaviours due to the overlap of adsorption and desorption upon successive exposure of the gas to different length of the ice surface. The validity of the model is demonstrated for the adsorption of acetone on an ice surface at 200 K as a case study.

Detailed atmospheric monitoring data are notoriously difficult to obtain for some geographic regions, while they are of paramount importance in scientific research, forecasting, emergency response, policy making, etc. We describe a continuously updated dataset, METER.AC, consisting of raw measurements of atmospheric pressure, temperature, relative humidity, particulate matter, and background radiation in about 100 locations in Bulgaria, as well as some derived values such as sea-level atmospheric pressure, dew/frost point, and hourly trends. The measurements are performed by low-power maintenance-free nodes with common hardware and software, which are specifically designed and optimized for this purpose. The time resolution of the measurements is 5 min. The short-term aim is to deploy at least one node per 100 km², while uniformly covering altitudes between 0 and 3000 m asl with a special emphasis on remote mountainous areas. A full history of all raw measurements (non-aggregated in time and space) is publicly available, starting from September 2018. We describe the basic technical characteristics of our in-house developed equipment, data organization, and communication protocols as well as present some use case examples. The METER.AC network relies on the paradigm of the Internet of Things (IoT), by collecting data from various gauges. A guiding principle in this work is the provision of findable, accessible, interoperable, and reusable (FAIR) data. The dataset is in the public domain, and it provides resources and tools enabling citizen science development in the context of sustainable development.

The main task of the National Research Program “Smart crop production”, supported by the Ministry of Education and Science of Bulgaria and approved by the Council of Ministers, is the development of a regional data center to facilitate the work of farmers. The regional data center is part of the implementation of a smart crop production environment called ZEMEL which provides personal assistants supporting the work of farmers. The environment provides intelligent services for crop analysis and prevention and assists farmers in performing basic tasks related to crop production. The objective of the proposed article is to present the implementation of the architecture, infrastructure, and data architecture of a regional data center in the Plovdiv region. In order to clearly present the results of this work, which are the architectural and physical implementations of a regional data center and the storage of dynamic data and background knowledge, a methodology consisting of several steps is followed: the system infrastructure of the data center and the data architecture are discussed; one of the local pieces of infrastructure, implemented in the Institute of Plant Genetic Resources (IPGR) in the town of Sadovo in the Plovdiv region, is presented in detail, including the different types of sensors and their connection to the data center in wheat cultivation; the data repositories are discussed where dynamic data and background knowledge are stored. The paper pays special attention to background knowledge developed as ontologies for winter wheat cultivation. The results are summarized by drawing some conclusions and recommendations for the design of the local infrastructure of the center and the stored data to improve its performance.

This article summarizes the results of a research conducted to create an intelligent platform supporting small farmers growing vegetables. In Bulgaria, many farmers use relatively small areas for their production. Considering this situation, the platform is designed for regional use, trying to make maximum use of the specific climatic features of the monitored microdistrict. Consequently, special attention is paid to the possibilities of adapting the platform to the specific environment in which the observed plants grow. Thus, the platform is implemented as an agent-oriented system providing needed flexibility. The core of the platform is a personal assistant, which is responsible for tracking the vegetation cycle of the monitored crop and, upon detection of anomalies, preparing warnings to the farmer. The general architecture of the platform is also presented. In a distributed knowledge base, agriculture-specific knowledge are stored. Furthermore, a standardized interface for receiving data from the sensor networks located in the production areas is briefly described. Currently, the platform is being tested for monitoring four varieties of tomatoes grown on the territory of the national research center for potato breeding. Special attention is paid to the measurements carried out. Conclusions have been drawn that will help improve the platform.