An activity lift for platinum: Platinum is an excellent but expensive catalyst for the oxygen reduction reaction (ORR), which is critical for fuel cells. Alloying platinum with other metals can create shells of platinum on cores of less expensive metals, which increases its surface exposure, and compressive strain in the layer can also boost its activity (see the Perspective by Stephens et al. ). Bu et al. produced nanoplates—platinum-lead cores covered with platinum shells—that were in tensile strain. These nanoplates had high and stable ORR activity, which theory suggests arises from the strain optimizing the platinum-oxygen bond strength. Li et al. optimized both the amount of surface-exposed platinum and the specific activity. They made nanowires with a nickel oxide core and a platinum shell, annealed them to the metal alloy, and then leached out the nickel to form a rough surface. The mass activity was about double the best reported values from previous studies. Science , this issue p. 1410 , p. 1414 ; see also p. 1378
As with donuts, the holes matter: Improving the density of stored charge and increasing the speed at which it can move through a material are usually opposing objectives. Sun et al. developed a Nb 2 O 5 /holey graphene framework composite with tailored porosity. The three-dimensional, hierarchically porous holey graphene acted as a conductive scaffold to support Nb 2 O 5 . A high mass loading and improved power capability were reached by tailoring the porosity in the holey graphene backbone with higher charge transport in the composite architecture. The interconnected graphene network provided excellent electron transport, and the hierarchical porous structure in the graphene sheets facilitated rapid ion transport and mitigated diffusion limitations. Science , this issue p. 599