The global flux of sulfur dioxide (SO₂) emitted by passive volcanic degassing is a key parameter that constrains the fluxes of other volcanic gases (including carbon dioxide, CO₂) and toxic trace metals (e.g., mercury). It is also a required input for atmospheric chemistry and climate models, since it impacts the tropospheric burden of sulfate aerosol, a major climate-forcing species. Despite its significance, an inventory of passive volcanic degassing is very difficult to produce, due largely to the patchy spatial and temporal coverage of ground-based SO₂ measurements. We report here the first volcanic SO₂ emissions inventory derived from global, coincident satellite measurements, made by the Ozone Monitoring Instrument (OMI) on NASA’s Aura satellite in 2005–2015. The OMI measurements permit estimation of SO₂ emissions from over 90 volcanoes, including new constraints on fluxes from Indonesia, Papua New Guinea, the Aleutian Islands, the Kuril Islands and Kamchatka. On average over the past decade, the volcanic SO₂ sources consistently detected from space have discharged a total of ~63 kt/day SO₂ during passive degassing, or ~23 ± 2 Tg/yr. We find that ~30% of the sources show significant decadal trends in SO₂ emissions, with positive trends observed at multiple volcanoes in some regions including Vanuatu, southern Japan, Peru and Chile.

This overview paper highlights the successes of the Ozone Monitoring Instrument (OMI) on board the Aura satellite spanning a period of nearly 14 years. Data from OMI has been used in a wide range of applications and research resulting in many new findings. Due to its unprecedented spatial resolution, in combination with daily global coverage, OMI plays a unique role in measuring trace gases important for the ozone layer, air quality, and climate change. With the operational very fast delivery (VFD; direct readout) and near real-time (NRT) availability of the data, OMI also plays an important role in the development of operational services in the atmospheric chemistry domain.

Severe haze is a major public health concern in China and India. Both countries rely heavily on coal for energy, and sulfur dioxide (SO₂) emitted from coal-fired power plants and industry is a major pollutant contributing to their air quality problems. Timely, accurate information on SO₂ sources is a required input to air quality models for pollution prediction and mitigation. However, such information has been difficult to obtain for these two countries, as fast-paced changes in economy and environmental regulations have often led to unforeseen emission changes. Here we use satellite observations to show that China and India are on opposite trajectories for sulfurous pollution. Since 2007, emissions in China have declined by 75% while those in India have increased by 50%. With these changes, India is now surpassing China as the world’s largest emitter of anthropogenic SO₂. This finding, not predicted by emission scenarios, suggests effective SO₂ control in China and lack thereof in India. Despite this, haze remains severe in China, indicating the importance of reducing emissions of other pollutants. In India, ~33 million people now live in areas with substantial SO₂ pollution. Continued growth in emissions will adversely affect more people and further exacerbate morbidity and mortality.

Sulfur dioxide (SO₂) measurements from the Ozone Monitoring Instrument (OMI) satellite sensor processed with the new principal component analysis (PCA) algorithm were used to detect large point emission sources or clusters of sources. The total of 491 continuously emitting point sources releasing from about 30 kt yr⁻¹ to more than 4000 kt yr⁻¹ of SO₂ per year have been identified and grouped by country and by primary source origin: volcanoes (76 sources); power plants (297); smelters (53); and sources related to the oil and gas industry (65). The sources were identified using different methods, including through OMI measurements themselves applied to a new emission detection algorithm, and their evolution during the 2005–2014 period was traced by estimating annual emissions from each source. For volcanic sources, the study focused on continuous degassing, and emissions from explosive eruptions were excluded. Emissions from degassing volcanic sources were measured, many for the first time, and collectively they account for about 30 % of total SO₂ emissions estimated from OMI measurements, but that fraction has increased in recent years given that cumulative global emissions from power plants and smelters are declining while emissions from oil and gas industry remained nearly constant. Anthropogenic emissions from the USA declined by 80 % over the 2005–2014 period as did emissions from western and central Europe, whereas emissions from India nearly doubled, and emissions from other large SO₂-emitting regions (South Africa, Russia, Mexico, and the Middle East) remained fairly constant. In total, OMI-based estimates account for about a half of total reported anthropogenic SO₂ emissions; the remaining half is likely related to sources emitting less than 30 kt yr⁻¹ and not detected by OMI.

INTRODUCTION: Although the carbon budget is often presented in terms of global-scale fluxes, many of the contributing processes occur through localized point sources, which have been challenging to measure from space. Persistent anthropogenic carbon dioxide (CO ₂ ) emissions have altered the natural balance of Earth’s carbon sources and sinks. These emissions are driven by a multitude of individual mobile and stationary point sources that combust fossil fuels, with urban areas accounting for more than 70% of anthropogenic emissions to the atmosphere. Natural point-source emissions are dominated by wildfires and persistent volcanic degassing. RATIONALE: Comprehensive global measurements from space could help to more completely characterize anthropogenic and natural point-source emissions. In global carbon cycle models, anthropogenic point-source information comes from bottom-up emission inventories, whereas natural point-source information comes from a sparse in situ measurement network. Whereas clusters of urban CO ₂ point-source plumes merge together, isolated point sources (e.g., remote power plants, cement production plants, and persistently degassing volcanoes) create localized plumes. Because turbulent mixing and diffusion cause rapid downwind dilution, they are challenging to detect and analyze. Point-source detection from space is complicated by signal dilution: The observed values of Δ X CO 2 (enhancement of the column-averaged dry-air CO ₂ mole fraction) correspond to in situ CO ₂ enhancements of 10-fold or higher. Space-based sensors that detect and quantify CO ₂ in plumes from individual point sources would enable validation of reported inventory fluxes for power plants. These sensors would also advance the detectability of volcanic eruption precursors and improve volcanic CO ₂ emission inventories. RESULTS: Spaceborne measurements of atmospheric CO ₂ using kilometer-scale data from NASA’s Orbiting Carbon Observatory-2 (OCO-2) reveal distinct structures caused by known anthropogenic and natural point sources, including megacities and volcanoes. Continuous along-track sampling across Los Angeles (USA) by OCO-2 at its ~2.25-km spatial resolution exposes intra-urban spatial variability in the atmospheric X CO 2 distribution that corresponds to the structure of the urban dome, which is detectable under favorable wind conditions. Los Angeles X CO 2 peaks over the urban core and decreases through suburban areas to rural background values more than ~100 km away. Enhancements of X CO 2 in the Los Angeles urban CO ₂ dome observed by OCO-2 vary seasonally from 4.4 to 6.1 parts per million (ppm). We also detected isolated CO ₂ plumes from the persistently degassing Yasur, Ambrym, and Aoba volcanoes (Vanuatu), corroborated by near-simultaneous sulfur dioxide plume detections by NASA’s Ozone Mapping and Profiler Suite. An OCO-2 transect passing directly downwind of Yasur volcano yielded a narrow filament of enhanced X CO 2 ( Δ X CO 2 ≈ 3.4 ppm), consistent with plume modeling of a CO ₂ point source emitting 41.6 ± 19.7 kilotons per day (15.2 ± 7.2 megatons per year). These highest continuous volcanic CO ₂ emissions are collectively dwarfed by about 70 fossil fuel–burning power plants on Earth, which each emit more than 15 megatons per year of CO ₂ . CONCLUSION: OCO-2’s sampling strategy was designed to characterize CO ₂ sources and sinks on regional to continental and ocean-basin scales, but the unprecedented kilometer-scale resolution and high sensitivity enables detection of CO ₂ from natural and anthropogenic localized emission sources. OCO-2 captures seasonal, intra-urban, and isolated plume signals. Capitalizing on OCO-2’s sensitivity, a much higher temporal resolution would capture anthropogenic emission signal variations from diurnal, weekly, climatic, and economic effects, and, for volcanoes, precursory emission variability. Future sampling strategies will benefit from a continuous mapping approach with the sensitivity of OCO-2 to systematically and repeatedly capture these smaller, urban to individual plume scales of CO ₂ point sources. OCO-2 detects urban CO ₂ signals with unprecedented detail over Los Angeles.: Individual “footprints” of OCO-2 X CO 2 data from early fall 2014 and summer 2015 over the city of Los Angeles strongly contrast with values over the distant, rural Antelope Valley. X CO 2 is the averaged dry-air molar CO ₂ concentration between the spacecraft and Earth’s surface.

Volcanoes are the main pathway to the surface for volatiles that are stored within the Earth. Carbon dioxide (CO₂) is of particular interest because of its potential for climate forcing. Understanding the balance of CO₂ that is transferred from the Earth’s surface to the Earth’s interior, hinges on accurate quantification of the long-term emissions of volcanic CO₂ to the atmosphere. Here we present an updated evaluation of the world’s volcanic CO₂ emissions that takes advantage of recent improvements in satellite-based monitoring of sulfur dioxide, the establishment of ground-based networks for semi-continuous CO₂-SO₂ gas sensing and a new approach to estimate key volcanic gas parameters based on magma compositions. Our results reveal a global volcanic CO₂ flux of 51.3 ± 5.7 Tg CO₂/y (11.7 × 10¹¹ mol CO₂/y) for non-eruptive degassing and 1.8 ± 0.9 Tg/y for eruptive degassing during the period from 2005 to 2015. While lower than recent estimates, this global volcanic flux implies that a significant proportion of the surface-derived CO₂ subducted into the Earth’s mantle is either stored below the arc crust, is efficiently consumed by microbial activity before entering the deeper parts of the subduction system, or becomes recycled into the deep mantle to potentially form diamonds.