In this study, we report a novel way to produce carbon-based conductive inks for electronic and sensor technology applications. Carbonized lignin, obtained from the waste products of the Eucalyptus globulus tree paper industry, was used to produce a stable conductive ink. To this end, liquid-phase compositions were tested with different amounts of carbonized lignin powder to obtain an ink with optimal conductivity and rheological properties for different possible uses. The combination that showed the best properties, both regarding electrochemical properties and green compatibility of the materials employed, was cyclohexanone/cellulose acetate/carbonized lignin 5% (w/w), which was used to produce screen-printed electrodes. The electrodes were characterized from a structural and electrochemical point of view, resulting in an electrochemically active area of 0.1813 cm², compared to the electrochemically active area of 0.1420 cm² obtained by employing geometrically similar petroleum-based screen-printed electrodes and, finally, their performance was demonstrated for the quantification of uric acid, with a limit of detection of 0.3 $\mathsf{\mu }$M, and their biocompatibility was assessed by testing it with the laccase enzyme and achieving a limit of detection of 2.01 $\mathsf{\mu }$M for catechol as the substrate. The results suggest that the developed ink could be of great use in both sensor and electronic industries, reducing the overall ecological impact of traditionally used petroleum-based inks.

Industrial wastes have become elective sustainable sources to obtain materials for electronic/electroanalytical purposes; on the other hand, easy and green strategies to include semiconductor 2D graphene-like materials in conductive networks are highly required. In this work, 1D/2D nanocomposites (NCs) based on nanofibrillar biochar (BH) from paper industry waste and transition metal dichalcogenides (TMDs: MoS₂, WS₂, MoSe₂, and WSe₂), were prepared in water via liquid phase exfoliation (LPE) using sodium cholate as bioderived surfactant. The TMD amount in the NCs has been carefully optimized, searching for the best compromise between electron transfer ability and electroanalytical performances. Four different water-dispersed BH-TMD NCs have been selected and comprehensively studied from the electrochemical point of view and morphologically characterized. The BH-TMDs potentiality have been demonstrated in model solutions and real samples towards different analytes of biological and agri-food interest. The most performing NCs have been selected and used for the simultaneous determination of the neurotransmitters dopamine (DP) and serotonin (SR), and the flavonoids quercetin (QR) and rutin (RT), obtaining good linearity (R² ≥ 0.9956) with limits of detection ranging from 10 to 200 nM. Reproducible quantitative recovery values (90-112%, RSD ≤6%, n = 3) were obtained analyzing simultaneously DP and SR in synthetic biological fluid and drugs, and QR and RT in food supplements, proving the usability of the proposed materials for real analyses. This work proves that BH-nanofibers act as a sustainable conductive hosting network for 2D-TMDs, allowing full exploit their electroanalytical potential. The proposed BH-TMD NCs represent a sustainable, affordable, and captivating opportunity for the electrochemical and (bio)sensoristic field.

The significant progress in scientific research and innovation has led to the need for a new paradigm to legitimise the innovation process in society and politics. The European Union, with the Horizon 2020 framework program and Horizon Europe, institutionalises this change by defining the concept of responsible research and innovation (RRI), aiming at greater inclusiveness and sustainability in the research and innovation processes. This paper aimed to present an agent-based model (ABM) to simulate the dynamics between the different actors that cooperate within networks during the innovation process, taking the inclinations toward RRI practices into account. The different types of agent, their characteristics, and the different strategies that they follow have been formulated within the Horizon 2020 project I AM RRI-Webs of Innovation Value Chains (IVCs) of Additive Manufacturing (AM) under consideration of RRI. Besides, some experiments are reported to validate the model, ensuring its rigor and making our model a useful tool for policymakers, assisting them in defining strategic guidelines for disseminating and encouraging RRI best practices and defining the critical factors of the innovative cooperative process.

Additive manufacturing has emerged as a key enabling technology for in-space manufacturing, offering the potential to reduce logistics mass, enhance mission autonomy, and support long-duration exploration. The suppression of gravity-driven phenomena fundamentally alters melt pool dynamics, heat transfer, surface-tension-dominated flow, and defect formation, limiting the direct transferability of terrestrial AM process knowledge to space applications. This paper reviews the current understanding of metallic additive manufacturing process physics under reduced gravity, with emphasis on melt pool behavior, dimensional stability, and in situ monitoring constraints. Approaches for qualification and certification are critically examined, including the applicability of existing AM standards, the role of digital twins and model-based verification, and emerging strategies for space-based validation. Enabling technologies such as autonomous and AI-assisted fabrication, compact hardware architectures, and alternative energy sources are discussed in the context of reliable in-space operation. By synthesizing current developments and identifying key limitations and open challenges, the review provides a roadmap for advancing additive manufacturing toward operational readiness, supporting sustainable exploration, in-space infrastructure development, and long-duration human presence beyond low Earth orbit.

In this work, a set of eight technical lignin samples from various botanical origins and production processes were characterized for their chemical composition, higher heating value, size distribution, dust explosion sensitivity and severity, thermal hazard characteristics and biodegradability, in further support of their sustainable use. More specifically, safety-focused parameters have been assessed in terms of consistency with relating physico-chemical properties determined for the whole set of technical lignins. The results emphasized the heterogeneity and variability of technical lignins and the subsequent need for a comprehensive characterization of new lignin feedstocks arising from novel biorefineries. Indeed, significant differences were revealed between the samples in terms of hazards sensitivity. This first comparative physico-chemical safety profiling of technical lignins could be useful for the hazard analysis and the safe design of the facilities associated with large scale valorisation of biomass residues such as lignins, targeting "zero waste" sustainable conversion of bioresources.

Carbonaceous-based nanomaterials (C-NMs) are the pillar of myriad sensing and catalytic electrochemical applications. In this field, the search for environmentally sustainable C-NMs from renewable sources became a duty in the development of nano-sensors. Herein, water-soluble carbon nanofibers (CF) were produced from eucalyptus scraps-based biochar (BH) through an ultrasound treatment, assisted by sodium cholate used as a stabilizing agent. Noteworthy, thanks to the use of the bio-stabilizing agent, the nanofibers were dispersed in water avoiding the use of organic solvents. The BH-CF was investigated as sensing material onto commercial screen-printed electrodes via drop-casting (BH-SPE) and as thin-film fully integrated into a lab-made flexible electrode. The thin film was produced via BH-CF vacuum filtration followed by the film transferring to a thermo-adhesive plastic substrate through thermal lamination. This approach gave rise to a conductive BH-CF film (BH-Film) easily embodied in a lab-made electrode produced with office-grade instrumentation (i.e., craft-cutter machine, thermal laminator) and materials (i.e., laminating pouches, stencil). The BH-CF amount was optimized and the resulting film morphologically characterized, then, the electrochemical performances were studied. The BH-CF electrochemical features were investigated towards a broad range of analytes containing phenol moieties, discrimination between orto- and mono-phenolic structures were achieved for all the studied compounds. As proof of applicability, the BH-CF-based sensors were challenged for simultaneous determination of mono-phenols and ortho-diphenols in olive oil extracts. LODs ≤ 0.5 μM and ≤ 3.8 μM were obtained for hydroxytyrosol (o-diphenol reference standard) and Tyrosol (m-phenols reference standard), respectively. Moreover, a high inter-sensors precision (RSD calibration-slopes ≤ 7%, n = 3) and quantitative recoveries in sample analysis (recoveries 91–111%, RSD ≤ 6%) were obtained. Here, a solvent-free strategy to obtain water-soluble BH-CF was proposed, and their usability to sensor fabrication and modification proved. This work demonstrated as cost-effective and sustainable renewable sources, rationally used, can lead to obtain useful nanomaterials.