We report the optimization of the length of a D-shaped plastic optical fiber (POF) sensor for refractive index (RI) sensing from a numerical and experimental point of view. The sensing principle is based on total internal reflection (TIR). POFs with 1 mm in diameter were embedded in grooves, realized in planar supports with different lengths, and polished to remove the cladding and part of the core. All D-shaped POF sensors were tested using aqueous medium with different refractive indices (from 1.332 to 1.471) through intensity-based configuration. Results showed two different responses. Considering the refractive index (RI) range (1.33–1.39), the sensitivity and the resolution of the sensor were strongly dependent on the sensing region length. The highest sensitivity (resolution of 6.48 × 10⁻³ refractive index units, RIU) was obtained with 6 cm sensing length. In the RI range (1.41–1.47), the length of the sensing region was not a critical aspect to obtain the best resolution. These results enable the application of this optical platform for chemical and biochemical evanescent field sensing. The sensor production procedure is very simple, fast, and low-cost.

We present a very simple approach for the detection of the Perfluorinated Alkylated Substances (PFAs) in water solution. Perfluorooctanesulfonate (PFOS) and Perfluorooctanoate (PFOA) are the most extensively investigated perfluoroalkyl and polyfluoroalkyl substances in water because human exposition can occur through different pathways, even if the dietary intake seems to be their main route of exposure. The developed sensor is based on a specific Molecularly Imprinted Polymer (MIP) receptor deposited on a simple D-shaped Plastic Optical Fiber (POF) platform. This novel chemical sensor has been characterized using a very simple and low-cost experimental setup based on an LED and two photodetectors. This optical sensor system is an alternative method to monitor the presence of contaminants with an MIP receptor, instead of a surface plasmon resonance (SPR) sensor in D-shaped POFs. For the sake of comparison, the results obtained exploiting the same MIP for PFAs on a classic SPR-POF sensor have been reported. The experimental results have shown that the actual limit of detection of this new configuration was about 0.5 ppb. It is similar to the one obtained by the configuration based on an SPR-POF with the same MIP receptor.

In this study the influence of the surface roughness on the transmission capacities of D-shaped plastic optical fibers (POFs) and sensors performance was investigated. Five D-shaped POF sensors were produced and characterized for refractive index sensing between 1.33 and 1.41. The sensors were characterized using a low-cost optical sensing system based on the variation of the transmitted light though the POF with refractive index changes (RI). Higher surface roughness increases the scattering losses through the POF and influences the sensors’ performance; therefore, a balance must be attained. Generally, the best performance was achieved when the sensing region was polished with P600 sandpaper as a final polishing step. Polishing with sandpapers of lower grit size resulted in lower scattering, higher linearity of the sensor response and generally lower performance for RI sensing. A sensor resolution of 10⁻³–10⁻⁴ RIU, dependent on the value of the external refractive index, was obtained through simple and low-cost manufacturing procedures. The obtained results show the importance of surface roughness in the development of POF sensors which can be used in several applications, such as for water quality assessment.

The detection of perfluorobutanesulfonic acid (PFBS) in water is presented for the first time exploiting a low-cost optical chemical sensing strategy, based on plastic optical fibers and molecularly imprinted polymers (MIPs), able to detect pollutants in water. The sensor’s response measured in this work for the detection of PFBS is similar to the one obtained with Perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA), already investigated. The detection limit of PFBS is considered of interest when compared to those obtained by using different expensive traditional approaches, e.g. high performance liquid chromatography-mass spectrometry (HPLC-MS). Moreover, the use of this sensing approach is a very attractive perspective for fast, in situ, and remote low-cost detection of pollutants in water for smart cities applications.

Glyphosate (N-(phosphonomethyl)glycine) is a popular broad-spectrum systemic herbicide commonly used to kill weeds and grasses that compete with crops. It is one of the most used herbicides worldwide that has been already detected in soils and groundwater. Its toxicity and persistence to humans and environment have been pointed out in literature. The detection and quantification of glyphosate or its degradation product (aminomethyl)phosphonic acid (AMPA), are thus an urgent need. In this work we use molecularly imprinted polymers (MIPs) integrated with different sensing platforms for glyphosate detection. The platforms are based on a piezoelectric quartz crystal and on fibre optics. The assembled piezoelectric quartz crystal system allowed to rapidly characterize MIP binding to glyphosate, with sensitivity of 0.769 and 0.496 Hz/(mg/L) and good selectivity to several tested interferents (selectivity coefficients lower than 0.04 for AMPA and inorganic salts). Optical fibre systems, namely an optical fibre tip and a dip probe fibre bundle, were further developed and combined with a fluorescent MIP selective layer, allowing a proof of concept towards an in situ operational system for glyphosate detection. Fibre tip sensor displayed higher sensitivity to glyphosate compared to dip probe, 0.19 and 0.048 (mg/L) ^-1 , respectively, but with linear behaviour in different concentration ranges, up to 1 mg/L and between 2 – 7 mg/L, respectively. The developed sensing platforms allowed fast measurements directly in the solution, making them promising probes for practical deployment for environmental monitoring.

Molecularly imprinted polymers (MIPs) can be combined with optical fibers (OFs) to create various sensor configurations, yielding low-cost and highly sensitive extrinsic and intrinsic sensors. In this work, an MIP-based extrinsic optical fiber sensor is obtained by two silica OFs connected via an optical waveguide using an MIP as a core of micrometer size (micro OF-MIP-OF sensor). The proposed sensing approach can be used only with MIP receptors and implements an intensity-based sensor configuration. MIPs present several advantages over bio-receptors and can be exploited to realize novel sensing methods. The MIP used in this work is specifically designed for 2-furaldehyde (2-FAL) detection, and the experimental results demonstrate that the micro-probe performs well in terms of sensitivity and selectivity, with capabilities applicable to several application fields. In particular, a nanomolar detection range, from 1.5 nM to 150 nM, has been achieved. Moreover, the results are comparable to or better than those of other previously proposed MIP optical fiber sensors for 2-FAL, which employ more complex sensing principles or fabrication steps.