In the recent past, significant research effort has been dedicated to examining the usage of nanomaterials hybridized with lignocellulosic fibers as reinforcement in the fabrication of polymer nanocomposites. The introduction of nanoparticles like montmorillonite (MMT) nanoclay was found to increase the strength, modulus of elasticity and stiffness of composites and provide thermal stability. The resulting composite materials has figured prominently in research and development efforts devoted to nanocomposites and are often used as strengthening agents, especially for structural applications. The distinct properties of MMT, namely its hydrophilicity, as well as high strength, high aspect ratio and high modulus, aids in the dispersion of this inorganic crystalline layer in water-soluble polymers. The ability of MMT nanoclay to intercalate into the interlayer space of monomers and polymers is used, followed by the exfoliation of filler particles into monolayers of nanoscale particles. The present review article intends to provide a general overview of the features of the structure, chemical composition, and properties of MMT nanoclay and lignocellulosic fibers. Some of the techniques used for obtaining polymer nanocomposites based on lignocellulosic fibers and MMT nanoclay are described: (i) conventional, (ii) intercalation, (iii) melt intercalation, and (iv) in situ polymerization methods. This review also comprehensively discusses the mechanical, thermal, and flame retardancy properties of MMT-based polymer nanocomposites. The valuable properties of MMT nanoclay and lignocellulose fibers allow us to expand the possibilities of using polymer nanocomposites in various advanced industrial applications.
This work aims to describe the coffee silverskin effect as a lignocellulosic waste filler for high-density polyethylene (HDPE) composites development. The main task was to determine various modification effects resulting from the complex chemical composition of coffee silverskin containing compounds with potential antioxidative properties, including caffeine, polyphenols, tannins, or melanoidins. The processing, thermal, physicochemical, and thermomechanical properties of the HDPE-based composites with different filler content (1–20 wt%) were evaluated. Comprehensively realized thermomechanical analysis revealed the filler’s reinforcing effects on the HDPE matrix while defining problems with obtaining adequate adhesion in the interfacial area. At the same time, studies have shown a very beneficial effect of the silverskin addition on the thermal properties of composites, that even the smallest addition allows for a significant increase in the thermooxidative resistance of HDPE composites assessed using the oxidation induction time from 20 min for HDPE up to 140 min for the composites with 20 wt% of the filler. The obtained research results allow classifying the coffee silverskin waste filler, not only as a filler intended for the production of composites with a high degree of filling but also as an additive that significantly changes the properties of polyethylene in the case of using low concentrations. This can have a very beneficial impact on the development of novel wood polymer (WPC) and natural fiber composites (NFC).
The present paper describes the application of two types of food-industry by-products, brewers’ spent grain (BSG), and coffee silverskin (ŁK) as promising alternatives for the conventional beech wood flour (WF) for wood–polymer composites. The main goal was to investigate the impact of partial and complete WF substitution by BSG and ŁK on the processing, structure, physicochemical, mechanical, and thermal properties of resulting composites. Such modifications enabled significant enhancement of the melt flowability, which could noticeably increase the processing throughput. Replacement of WF with BSG and ŁK improved the ductility of composites, which affected their strength however. Such an effect was attributed to the differences in chemical composition of fillers, particularly the presence of proteins and lipids, which acted as plasticizers. Composites containing food-industry by-products were also characterized by the lower thermal stability compared to conventional WF. Nevertheless, the onset of decomposition exceeding 215 °C guarantees a safe processing window for polyethylene-based materials.
1 February 2021 in IOP Conference Series: Materials Science and Engineering
One of the main indicators characterizing the quality of modern products are reliability indicators. The detection and development of effective measures to combat corrosion of aviation materials and structures is one of the most important areas of ensuring safety, high operational reliability and efficiency of modern aviation technology. It is one of the modern trends in the development of aviation at this stage of development of aircraft construction. This article discusses the technological aspects of the development of the use of composite materials in aircraft construction at the present stage of society development. The aircraft industry is one of the high-tech industries where modern polymer and composite materials play a decisive role. In this regard, the development of composite and polymer materials is the future of all the world aviation.
20 April 2023 in Advances in Materials Science and Engineering
Generally, solar dryer cabinets are made up of sheet metals that are heavy, costly, tend to rust over time, and possess the high heat rate to the outer atmosphere. In order to overcome these drawbacks, this research urges to develop a natural fiber reinforced polymer-based cabinet dryer, specially designed and fabricated for the purpose of solar drying. Nylon is used as the matrix material and Prosopis juliflora in particulate form is used as the natural fiber reinforcement. The dryer cabinet was designed at industrial scale to dry 5kg of ginger at a single setting. This work also studies the efficiency of the polymer composite cabinet integrated with a flat plate solar collector system that is coated with copper and black chrome attached to corrugated fins in between the absorber plate and storage medium. The FRP chamber was compartmented in its interior with aluminium perforated sheets and experimentation was performed to determine the efficiency of the composite cabinet based on reduction of heat loss from the system. The performance of the coating, storage medium materials, and overall storage efficiency were also studied. The FRP cabinet resulted in a moisture level less than 8.5 within 47days. Exergy studies showed 75 efficiency and energy studies gave 25.5kJ/kg peak readings of drying efficiency for a period ranging between 11 and 12hours. This was a 75 increment in energy efficiency. Thermal degradation of the FRP material was found to be stable up to 300C. The overall weight of the constructed polymer cabinet was 25 lesser than the conventional systems.
This study investigates the potential of incorporating alternative waste materials—limestone (LS) powder and construction and demolition waste (CDW)—in sustainable brick production under real-time curing conditions. Cement was partially replaced with LS powder in the range of 0–20% by weight, while natural aggregates were substituted with CDW at 0–100%. Experimental evaluations were conducted to assess the mechanical properties of the fabricated bricks. The results demonstrated a notable enhancement in performance compared to conventional bricks, with a maximum compressive strength of 14.99 N/mm2 observed at 2% LS and 10% CDW replacement levels. Additionally, a significant reduction in water absorption was recorded. Machine learning models, including Random Forest and Gradient Boosting, were employed to predict mechanical behavior. The findings underscore the feasibility of producing eco-efficient bricks by valorizing industrial waste within a circular construction framework.