Per- and polyfluoroalkyl substances (PFAS) have gained significant attention as emerging contaminants due to their persistence, abundance, and adverse health effects. Consequently, the urgent need for ubiquitous and effective sensors capable of detecting and quantifying PFAS in complex environmental samples has become a priority. In this study, we present the development of an ultrasensitive molecularly imprinted polymer (MIP) electrochemical sensor tailored by chemically vapour-deposited boron and nitrogen codoped diamond-rich carbon nanoarchitectures for the selective determination of perfluorooctanesulfonic acid (PFOS). This approach allows for a multiscale reduction of MIP heterogeneities, leading to improved selectivity and sensitivity in PFOS detection. Interestingly, the peculiar carbon nanostructures induce a specific distribution of binding sites in the MIPs that exhibit a strong affinity for PFOS. The designed sensors demonstrated a low limit of detection (1.2 μg L^-1) and exhibited satisfactory selectivity and stability. To gain further insights into the molecular interactions between diamond-rich carbon surfaces, electropolymerised MIP, and the PFOS analyte, a set of density functional theory (DFT) calculations was performed. Validation of the sensor's performance was carried out by successfully determining PFOS concentrations in real complex samples, such as tap water and treated wastewater, with average recovery rates consistent with UHPLC-MS/MS results. These findings demonstrate the potential of MIP-supported diamond-rich carbon nanoarchitectures for water pollution monitoring, specifically targeting emerging contaminants. The proposed sensor design holds promise for the development of in situ PFOS monitoring devices operating under relevant environmental concentrations and conditions.

Innovative and multifunctional mortars for renders and panels were manufactured using white photocatalytic and non-photocatalytic cement as binder. Unconventional aggregates, based on lightweight materials with high specific surface and adsorbent properties, were adopted in order to investigate the possible ability to passively improve indoor air quality. The reference mortar was manufactured with traditional calcareous sand. Results show that even if the mechanical properties of mortars with unconventional aggregates generally decrease, they remain acceptable for application as render. The innovative mortars were able to passively improve indoor air quality in terms of transpirability (70% higher), moisture buffering ability (65% higher) and depolluting capacity (up to 75% higher) compared to traditional ones under the current test conditions.