The surface free energy (SFE) of woods and their wettability are important characteristic for wood painting. No information is available regarding the SFE and wettability of Indonesian tropical woods. The purpose of the study was to determine the SFE and wettability of 10 Indonesian tropical woods. The woods tested in this study were fast-growing species from plantation of teak, sengon, jabon, pine, and species from natural forest of ramin, meranti, mahagony, camphor, keruing, and ebony. Surface roughness was measured by a profilometer, while wettability was determined by sessile drop method. The SFE values were calculated based on the Rabel method. Wettability was characterized by constant contact angle change rate (K) using the Shi and Gardner (S/G) model. The results showed that the mean roughness (Ra) value of fast-growing species from plantation was 13.58 μm and of species from natural forest was 10.73 μm. The SFE of woods varied from 36.00 mJ/m2 in the Meranti to 69.68 mJ/m2 in the Sengon. It was observed that the Meranti wood with the lowest value of SFE provided the lowest value of K (0.01) which indicated the poorest in wettability. The Sengon wood with the highest value of K (0.06) should provide the best wettability for the acrylic paint.
An innovative eco-friendly technology, applied to improve the quality of the short rotation teak, was wood modification by heat treatment. The study was to investigate the effects of heat treatment at 180°C, 200°C, and 220°C on the characteristics of the short rotation teak. The results show that the short rotation teak degraded hemicellulose and increased α-cellulose and lignin after the heat treatment. Anti-swelling efficiency value after heat treatment was improved ranging between 12.9% and 46.7%, indicating an improvement in dimensional stability. The MOE and MOR values decreased after heat treatment. The heat treated sample at 180°C after graveyard test was the lowest in weight loss, which presented good durability against termite (rating 9) and decay (rating 10). The surface roughness and SFE values decreased as the heating temperature increased. The heat treated at 220°C provided the lowest K-values (0.04 for acrylic and 5.04 for alkyd paint) which indicate the poorest wettability.
Short rotation teak (SRT) has a diameter of around 30 cm at the age of 15 years; however, the wood still has low quality, especially in dimensional stability and biological durability. The objective of this study was to improve dimensional stability and biological durability of SRT through modification treatment using non-biocide chemicals, citric acid (CA) and benzophenone tetracarboxylic acid (BPTCA). SRT sapwood was impregnated by 20% and 40% of CA or BPTCA followed by heating in the oven at 150 °C for 2 h. Dimensional stability, strength, surface characteristics and durability against termite attacks of the modified woods were evaluated. Results show that dimensional stability as anti-swelling efficiency (ASE) increased by an average of 46% (CA) and 50% (BPTCA) after treatments. Durability against termites showed that the modified woods were categorized to be class 1 (very durable). Fourier Transform Infrared (FTIR) and X-ray Diffraction observations indicated a possible chemical reaction between the wood components with CA and BPTCA. The water-based acrylic and oil-based alkyd contact angle values of the modified woods were lower than 90°, indicating their high wetting ability against the varnish liquids. The treatment can be applied to improve the quality of SRT for high-quality wood product utilization.
28 June 2023 in Wood Material Science & Engineering