Concentrations of chlorophyll-a (Chl-a) and total suspended solids (TSS) are significant parameters used to assess water quality. The objective of this study is to establish a quantitative model for estimating the Chl-a and the TSS concentrations in irrigation ponds in Higashihiroshima, Japan, using field hyperspectral measurements and statistical analysis. Field experiments were conducted in six ponds and spectral readings for Chl-a and TSS were obtained from six field observations in 2014. For statistical approaches, we used two spectral indices, the ratio spectral index (RSI) and the normalized difference spectral index (NDSI), and a partial least squares (PLS) regression. The predictive abilities were compared using the coefficient of determination (R²), the root mean squared error of cross validation (RMSECV) and the residual predictive deviation (RPD). Overall, iterative stepwise elimination based on PLS (ISE–PLS), using the first derivative reflectance (FDR), showed the best predictive accuracy, for both Chl-a (R² = 0.98, RMSECV = 6.15, RPD = 7.44) and TSS (R² = 0.97, RMSECV = 1.91, RPD = 6.64). The important wavebands for estimating Chl-a (16.97% of all wavebands) and TSS (8.38% of all wavebands) were selected by ISE–PLS from all 501 wavebands over the 400–900 nm range. These findings suggest that ISE–PLS based on field hyperspectral measurements can be used to estimate water Chl-a and TSS concentrations in irrigation ponds.

Harmful algal blooms (HABs) occur frequently in the Seto Inland Sea, bringing significant economic and environmental losses for the area, which is well known as one of the world’s most productive fisheries. Our objective was to develop a quantitative model using in situ hyperspectral measurements in the Seto Inland Sea to estimate chlorophyll a (Chl-a) concentration, which is a significant parameter for detecting HABs. We obtained spectra and Chl-a data at six stations from 12 ship-based surveys between December 2015 and September 2017. In this study, we used an iterative stepwise elimination partial least squares (ISE-PLS) regression method along with several empirical and semi-analytical methods such as ocean chlorophyll, three-band model, and two-band model algorithms to retrieve Chl-a. Our results showed that ISE-PLS using both the water-leaving reflectance (R_L) and the first derivative reflectance (FDR) had a better predictive ability with higher coefficient of determination (R²), lower root mean squared error (RMSE), and higher residual predictive deviation (RPD) values (R² = 0.77, RMSE = 1.47 and RPD = 2.1 for R_L; R² = 0.78, RMSE = 1.45 and RPD = 2.13 for FDR). However, in this study the ocean chlorophyll (OC) algorithms had poor predictive ability and the three-band and two-band model algorithms did not perform well in areas with lower Chl-a concentrations. These results support ISE-PLS as a potential coastal water quality assessment method using hyperspectral measurements.

Particle size distribution (PSD), which is an important characteristic of marine suspended particles, plays a role in how light transfers in the ocean and impacts the ocean’s inherent optical properties (IOPs). However, PSD properties and the correlations with IOPs are rarely reported in coastal waters with complex optical properties. This study investigated the PSD variabilities both for the surface water and the water in vertical planes, and the correlations between PSD and the backscattering coefficient (b_bp), scattering coefficient (b_p), and attenuation coefficient (c_p), based on in situ PSD observations (within a size range of 2.05–297 μm) and IOPs in the coastal northern South China Sea. The results show a large variety of PSDs, with a range of 41.06–263.02 μm for the median particle diameter (D_v⁵⁰) and a range of 2.61–3.74 for the PSD slope. In addition, the predominance of small particles is most likely to appear in the nearshore shallow water and estuaries with a large amount of sediment discharge, and vice versa. For the variabilities of IOPs, the particle concentration in a cross-sectional area (AC) is the first driving factor of the variations of b_bp, b_p, and c_p, and the product of the mean particle diameter (D_A) and the apparent density (ρ_a) can explain most variations of the mass-specific b_bp (b_bp/SPM), b_p (b_p/SPM), and c_p (c_p/SPM). In this study, we found that particle size is strongly correlated with volume-specific b_bp (b_bp/VC), b_p (b_p/VC), and c_p (c_p/VC), and the 10th percentile diameter of the accumulated volume concentration (D_v¹⁰) can better explain the variations of b_bp/VC. These findings suggest a potential PSD retrieval method utilizing the b_bp or b_p, which may be determined by remote sensing observations.

As the only natural satellite of the Earth, the Moon provides vital location resources and supportive environment for Earth observations, and the Moon-based Earth observation (MEO) has unparalleled advantages in global climate change and large-scale phenomena. The ocean plays an important role in regulating climate and global water and carbon cycle. With an attempt to explore the feasibility of MEO-based marine environment monitoring, this study aimed to investigate the observing geometry and revisiting frequency of the MEO-based ocean color remote sensing and further to explore its quantitative application potentials. Results showed that MEO-based ocean color remote sensing, capturing the Earth on an hourly basis, could observe most part of the ocean for over five times per day; however, both solar zenith angle and view zenith angle were high at high-latitude regions; atmospheric reflectance accounted for most of sensor-measured signal, especially at high solar and view zenith angle, while surface-reflected glint reflectance was also notable at low solar zenith angle; and the remote sensing reflectance retrieved from MEO-based ocean color remote sensing could be used for chlorophyll retrieval. In further studies, more efforts should be paid on how to accurately retrieve remote sensing reflectance at high solar and view zenith angle, which would improve the application capability of MEO for polar regions. Overall, this study demonstrated the great potentials of MEO-based ocean color remote sensing, and MEO would be a new observing perspective and long-term consistent data source for marine environment monitoring.

The suspended particle size has great impacts on marine biology environments and biogeochemical processes, such as the settling rates of particles and sunlight transmission in marine water. However, the spatial–temporal variations in particle sizes in coastal waters are rarely reported due to the paucity of appropriate observations and the limitations of particle size retrieval methods, especially in areas with complex optical properties. This study proposed a remote sensing-based method for estimating the median particle size D_v⁵⁰ (calculated with a size range of 2.05–297 μm) that correlates D_v⁵⁰ with the inherent optical properties (IOPs) retrieved from in situ remote sensing reflectance above the water’s surface (R_rs(λ)) in the Pearl River estuary (PRE) in China. R_rs(λ) was resampled to simulate the Multispectral Instrument (MSI) onboard Sentinel-2A/B, and the wavebands in 490, 560, and 705 nm were utilized for the retrieval of the IOPs. The results of this method had a statistical performance of 0.86, 18.52, 21.28%, and −1.85 for the R², RMSE, MAPE, and bias values, respectively, in validation, which indicated that D_v⁵⁰ could be estimated by R_rs(λ) with the proposed four-step method. Then, the proposed method was applied to Sentinel-2 MSI imagery, and a clear difference in D_v⁵⁰ distribution which was retrieved from a different time could be seen. The proposed method holds great potential for monitoring the suspended particle size of coastal waters.