Hydrothermal liquefaction (HTL) was employed to transform biomass into bio-oil. Waste bamboo chopsticks (WBC) were utilized as the raw materials of HTL reaction for resolving excessive WBC problem. Effects of temperatures (TC) from 563 to 653 K and K2CO3 catalyst on the yield (YBOAS) of bio-oil (BOAS) obtained as acetone soluble were assessed. As illustrations, for WBC without catalyst at TC of 593 K with reaction time of 30 min, the yield YBOAS reaches only 3.8 wt% with heating value (HBOAS) of 30.9 MJ kg−1, while the addition of catalyst (catalytic HTL, CHTL) with TC at 563 K can lead to evident enhancement of YBOAS to 21.2 wt% with HBOAS of 31.6 MJ kg−1. The yield (YBOCC) of organic C of BOAS with respect to C of dry-ash-free raw WBC for CHTL corresponding to 21.2 wt% of YBOAS is 33.1 wt%. Higher YBOAS and carbon content of BOAS give higher YBOCC and HBOAS, respectively. The results indicate that K2CO3 is an effective catalyst for HTL of biomass of WBC with significant lignin content of 25.5 wt% in dry-basis. Furthermore, the BOAS shows simulated distillation characteristic close to diesel, while is superior to heavy oil and boat oil

The pulp industry in Taiwan discharges tons of wood waste and pulp sludge (i.e., wastewater-derived secondary sludge) per year. The mixture of these two bio-wastes, denoted as wood waste with pulp sludge (WPS), has been commonly converted to organic fertilizers for agriculture application or to soil conditioners. However, due to energy demand, the WPS can be utilized in a beneficial way to mitigate an energy shortage. This study elucidated the performance of applying torrefaction, a bio-waste to energy method, to transform the WPS into solid bio-fuel. Two batches of the tested WPS (i.e., WPS1 and WPS2) were generated from a virgin pulp factory in eastern Taiwan. The WPS1 and WPS2 samples contained a large amount of organics and had high heating values (HHV) on a dry-basis (H_HD) of 18.30 and 15.72 MJ/kg, respectively, exhibiting a potential for their use as a solid bio-fuel. However, the wet WPS as received bears high water and volatile matter content and required de-watering, drying, and upgrading. After a 20 min torrefaction time (t_T), the H_HD of torrefied WPS1 (WPST1) can be enhanced to 27.49 MJ/kg at a torrefaction temperature (T_T) of 573 K, while that of torrefied WPS2 (WPST2) increased to 19.74 MJ/kg at a T_T of 593 K. The corresponding values of the energy densification ratio of torrefied solid bio-fuels of WPST1 and WPST2 can respectively rise to 1.50 and 1.25 times that of the raw bio-waste. The H_HD of WPST1 of 27.49 MJ/kg is within the range of 24–35 MJ/kg for bituminous coal. In addition, the wet-basis HHV of WPST1 with an equilibrium moisture content of 5.91 wt % is 25.87 MJ/kg, which satisfies the Quality D coal specification of the Taiwan Power Co. requiring a value of above 20.92 MJ/kg.

Combined heat and power production from biogas is now playing an important role in energy and resource utilization as well as pollution control in waste water treatment. This research used biogas from the Bali Sewage Treatment Plant in New Taipei City, Taiwan, as a major source of fuel for the electricity generation. A micro gas turbine electricity generator, Capstone CR-30, which possesses a maximum rated power load (P_WL) of 30 kW, was equipped to convert biogas into electricity. The biogas is mainly composed of CH₄ (56.1 ± 8.0 vol.%), CO₂ (25.5 ± 9.8 vol.%), H₂ (0.5 vol.%), and H₂S (0.99 ± 0.07 ppmv). During the test operation period of the generator, it was found that the thermal efficiency increases from 19.8% to 23.4% kWh_e/kWh_th, while the electricity generation efficiency (η_EB) also rises from 0.93 to 1.09 kWh_e/m³ biogas as the P_WL increases from 10 kW to 30 kW. The results indicated that the generator has a better performance with higher P_WL. At P_WL = 30 kW, the average adjusted concentrations of CO and NOx (adjusted to 15 vol.% O₂) emitted from the generator are 86 ppmv and 17 ppmv, respectively. Both are much lower than the emission standards of stationary sources in Taiwan of 2000 ppmv and 150 ppmv, respectively. Thus, P_WL of 30 kW was selected in cooperation with biogas inflow = 0.412 m³/min and air/fuel ratio (i.e., air/biogas ratio) = 76.0 vol./vol. for the long-term regular operation. At the above setting conditions for long-term operation, the generator continuously consumed the biogas and provided stable electricity generation at a rate of 19.64 kWh_e/h for a 2-year running period. Moreover, the greenhouse gas can be cut off with a rate of 10.78 kg CO₂e/h when using biogas as fuel for electricity generation. Overall, this research proves that the application of a micro gas turbine electricity generator not only has promising performance for using biogas but also gives a significant reduction of greenhouse gas emission, which fits the concepts of the circular economy and environmental protection.

In this study, biomass of rice straw (RS) and wood (WD) and their torrefied biomass (RS_T and WD_T) were used as solid bio-fuel (SBF) for co-firing individually with coal in a commercial continuous chain-grate steam boiler system, which was conducted at fixed input rate of heating value of mixture of SBF and coal and at fixed air flow rate. The effects of key system parameters on the gaseous and particulate pollutions and ash were examined. These include SBF type and blending ratio (R_BL) of biomass (i.e., SBF) in the mixture of coal and biomass based on heating values for co-firing. The results indicated that wood, which possesses high heating value while less amount of ash, is more suitable for co-firing with coal than rice straw. Torrefaction can increase the heating value of biomass and homogenize its property, being beneficial to co-firing. Also, torrefaction can decompose the hydroxyl group of biomass, which makes biomass tending to possess hydrophobicity. This, in turn, helps the storage and transportation of biomass. Generally, adding the RS (with R_BL = 5-10%), WD (2-15%), RS_T (2-10%), and WD_T (2-20%), respectively with coal decreases the emissions of NO_x and SO₂, but increases that of CO (except RS_T). The emission of HCl is little. The addition of biomass also increases the emission of fine particulate matters (PM) especially PM_2.5 in the flue gases, raising PM_2.5/PM₁₀₀ from 34.87 to 78.35 wt.% (Case 50%WD_T). These emissions for the Cases tested satisfy with Taiwanese emission standards of stationary sources which set limitations of NOx, SO₂, CO, and HCl < 350, 300, 2000, and 80 ppmv, while PM < 50 mg/m³, respectively. The results support the use of RS, WD, RS_T, and WD_T for co-firing with coal.