It is well-documented that large-scale pollution generated by human activity has a dramatic impact on ecosystems. In this context, removing harmful chemicals via photocatalysis has tremendous potential as a depollution method, utilizing freely available solar light and catalytic materials with low or negligible ecotoxicity. The main drawbacks, which aren’t often addressed in the available literature, are the formation of harmful intermediate products, low reaction rates, limited catalyst stability, and difficult catalyst recovery. In most cases, published works assess the efficiency of tested photocatalysts from pollutant degradation studies, whereas identifying and quantifying by-products is not often conducted. This review summarizes the recent advances reported for the photocatalytic removal of some organic (e.g., alcohols, carboxylic acids, volatile organic compounds, phenol) and inorganic (e.g., NO₃⁻) contaminants. The efficiency of various UV- and visible-light active photocatalysts and the reaction degradation pathways were explained, emphasizing the main factors contributing to their mineralization. The reaction mechanisms, the identification and quantification of degradation intermediates, and the implication of reactive active species (ROS) were discussed and analyzed for each category of model target pollutant. Additionally, the actual challenges and future photocatalytic approaches to improve environmental remediation were presented.

Highly defected tubular SiO₂outperforms the photocatalytic activity of TiO₂-P25 and the SiO₂–TiO₂composite.

Well-dispersed Pt–Cu nanoparticles with two average sizes were synthesized: small (≈1.6 nm) and large (≈4.8 nm), respectively. The effects of size and support on the catalytic behavior of the nanoparticles for denitration reaction were analyzed. Both the unsupported and alumina-supported nanoparticles of smaller average size (1.6 nm) were very active, completely converting NO₃ ⁻ and NO₂ ⁻ (an intermediate reaction product) to N₂ and NH₄ ⁺. They were also more selective of N₂ compared to the larger particles. The effects of particle size and alumina support on the denitration rate constants were analyzed in detail. The kinetic investigation indicates that the catalytic behavior is strongly related to the size of Pt–Cu nanoparticles as well as to the metal–support interaction. Generally, the larger nanoparticles proved to be less active, but on the other hand, they are less influenced by the support than the smaller ones. The metal–support interaction for bimetallic nanoparticles with smaller average size proved to be a key factor both for nitrate and nitrite reduction. Consideration of the reaction mechanism is made in light of the experimental results.

This work presents the synthesis of nanostructured TiO₂ modified with noble metal nanoparticles (Au, Ag) and lysozyme and coated on titanium foil. Moreover, the specific structural and functional properties of the resulting inorganic and hybrid materials were explored. The purpose of this study was to identify the key parameters for developing engineered coatings on titanium foil appropriate for efficient dental implants with intrinsic antibacterial activity. TiO₂ nanoparticles obtained using the sol–gel method were deposited on Ti foil and modified with Au/Ag nanoparticles. Morphological and structural investigations (scanning electron and atomic force microscopies, X-ray diffraction, photoluminescence, and UV–Vis spectroscopies) were carried out for the characterization of the resulting inorganic coatings. In order to modify their antibacterial activity, which is essential for safe dental implants, the following aspects were investigated: (a) singlet oxygen (¹O₂) generation by inorganic coatings exposed to visible light irradiation; (b) the antibacterial behavior emphasized by titania-based coatings deposited on titanium foil (TiO₂/Ti foil; Au–TiO₂/Ti foil, Ag–TiO₂/Ti foil); (c) the lysozyme bioactivity on the microbial substrate (Micrococcus lysodeicticus) after its adsorption on inorganic surfaces (Lys/TiO₂/Ti foil; Lys/Au–TiO₂/Ti foil, Lys/Ag–TiO₂/Ti foil); (d) the enzymatic activity of the above-mentioned hybrids materials for the hydrolysis reaction of a synthetic organic substrate usually used for monitoring the lysozyme biocatalytic activity, namely, 4-Methylumbelliferyl β-D-N,N′,N″-triacetylchitotrioside [4-MU-β- (GlcNAc)₃]. This was evaluated by identifying the presence of a fluorescent reaction product, 7-hydroxy-4-metyl coumarin (4-methylumbelliferone).